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1.
Wireless Personal Communications - In the present scenario, there is a boom in the demand of the users to achieve increased capacity, high data, low latency, and high-performance rates. 5G New... 相似文献
2.
3.
Some substituted coumarins have been synthesized by von-Pechmann condensation using SnCl2 · 2H2O (10 mol %) as catalyst in ethanolic medium. The reactions are simple, easy in handling and environmentally benign. 相似文献
4.
Arjunan Arulchakkaravarthi Rakesh Kumar Parthasarathy Santhanaraghavan Sivaramakrishnan Muralithar Rengasamy Gopalakrishanan Perumalsamy Ramasamy 《Materials Research Innovations》2002,6(5-6):273-276
Organic molecular scintillating crystals are noted for their good timing and particle discrimination process. Trans-stilbene
is one such candidate noted for its good particle detection characteristics for the past five decades. Progressive strengthening
of detection characteristics of trans-stilbene has been attempted by improving crystal perfection. A series of timing resolution
studies have been carried out for the Bridgman grown trans-stilbene crystals under different experimental conditions. The
results were compared with the previously reported values. Pulse shape discrimination process has been carried out for 241Am and 252Cf sources and good discrimination has been obtained for gamma-alpha and gamma-neutron sources from the grown organic phosphor
crystal.
Electronic Publication 相似文献
5.
Shamsher S. Kanwar Ghansham S. Chauhan Swapandeep S. Chimni Sandeep Chauhan Gajendra S. Rawat Rajeev K. Kaushal 《应用聚合物科学杂志》2006,100(2):1420-1426
An alkaline thermotolerant bacterial lipase of Bacillus coagulans MTCC‐6375 was purified and immobilized on a methacrylic acid and dodecyl methacrylate (MAc‐DMA) hydrogel. The lipase was optimally bound to the matrix after 20 min of incubation at 55°C and pH 9 under shaking conditions. The matrix‐bound lipase retained approximately 50% of its initial activity at 70–80°C after 3 h of incubation. The immobilized lipase was highly active on medium chain length p‐nitrophenyl acyl ester (C: 8, p‐nitrophenyl caprylate) than other p‐nitrophenyl acyl esters. The presence of Fe3+, NH4+, K+, and Zn2+ ions at 1 mM concentration in the reaction mixture resulted in a profound increase in the activity of immobilized lipase. Most of the detergents partially reduced the activity of the immobilized lipase. The immobilized lipase performed ~62% conversion in 12 h at temperature 55°C. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1420–1426, 2006 相似文献
6.
Rakesh?Kumar?MahajanEmail author Inderpreet?Kaur Mandeep?Singh?Bakshi 《Journal of surfactants and detergents》2004,7(2):131-134
Poly(vinyl chloride) (PVC) membrane electrodes to determine monomer concentrations of tetradecyltrimethylammonium ion (TTA+) and hexadecylpyridinium ion (HPy+) based on neutral ion-pair carrier complexes of tetradecyltrimethylammonium dodecyl sulfate (TTA+-DS−) and hexadecylpyridinium dodecyl sulfate (HPy+-DS−), respectively, are reported here. The electrodes exhibit a Nernstian slope of 59 mV per decade for TTA+ and a sub-Nernstian slope of 34.5 mV per decade for HPy+ ions. The TTA+ ion-selective electrode (ISE) and the HPy+-ISE can determine the monomer units down to concentrations as low as 4.0×10−4M and 1.66×10−5 M, respectively. The effect of various additives, such as the anionic polyelectrolyte sodium dextran sulfate and macrocyclic
β-cyclodextrin, on the surface activity exhibited by the cationic surfactants TTA+-DS− and HPy+-DS−, in the presence of background concentrations of NaCl was also examined with surfactant-selective sensors. The Gibbs free
energy of micelle formation (ΔG
m
) of both surfactants in the presence of various additives was calculated and found to be less favorable with respect to an
increase in the amount of additives due to less availability of cationic surfactant monomer units. The ion-pair complexes
TTA+-DS− and HPy+-DS− were found to behave as selective carrier compounds in PVC membranes in determining the concentration of monomer units of
both TTA+ and HPy+, respectively. The proposed sensors worked well at a fairly acidic pH of 1–6.5 with response time of 60 s. The sensors responded
well to the surfactant ions even in the presence of additives at lower concentration. The lifetime of the sensors is 3 mon. 相似文献
7.
Different rubber formulations were designed using nitrile rubber and a mixed crosslinking system consisting of sulfur/accelerator and electron beam radiation. Based on the experimental results, an artificial neural network (ANN) was constructed to simulate the mechanical properties and volume fraction of rubber. The ANN could predict accurately the above properties for a series of nitrile rubber compounds. However, the number of training data played a key role in the ANN predictive quality. In addition, the more complex the nonlinear relation between input and output was, the larger was the number of training dataset required. The predicted results were further validated using another mathematical model. The constructed ANN was verified with a completely different styrene butadiene rubber system. The prediction was found to be extremely good. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 2227–2237, 2006 相似文献
8.
Shamsher Singh Kanwar Rajeev Kumar Kaushal Amit Aggarwal Sandeep Chauhan Swapandeep Singh Chimni Ghansham Singh Chauhan 《应用聚合物科学杂志》2007,105(3):1437-1443
A purified alkaline thermotolerant bacterial lipase of Bacillus coagulans MTCC‐6375 was efficiently immobilized onto poly(N‐AEAAm‐co‐AAc‐cl‐MBAm)‐hydrogel at pH 8.5 and at temperature 55°C in 16 h. The hydrogel‐bound matrix possessed 1.04 U/g (matrix) lipase activity with a specific activity of 1.8 U/mg of protein. The immobilized lipase resulted in formation of 52.5 mM of ethyl propionate (52% conversion) at 55°C in 9 h in n‐nonane. Ethanol and propionic acid when used in a ratio of 300 : 100 mM, respectively, in n‐nonane along with 10 mg of hydrogel‐bound lipase resulted in optimal synthesis of ethyl propionate (82.5 mM). Addition of molecular sieves (3 Å, 0.7 g/reaction volume) further enhanced the conversion rate to 82.4% resulting in 83.5 mM of ethyl propionate. Incubation temperature below or above 55°C had a marked effect on the synthesis of ethyl propionate. However, esterification performed in n‐heptane at 65°C resulted in 87.5 mM of ethyl propionate with a conversation rate of 89.3%. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
9.
For complex reactions, the choice of reactor type is important for attaining optimum product yields. Strategies for specifying reactor types have beenIn this paper, product yield in a Van de Vusse reaction scheme has been studied for a wide range of the rate constants, in a reactor system consisting 相似文献
10.
Castor oil was hydrogenated to evaluate the effect of agitation during hydrogenation. The turbine and propeller impellers
were evaluated during hydrogenation of castor oil at various temperatures, pressures, and catalyst concentrations. The effect
of impeller position in the agitator at definite oil depth was also evaluated. Hydrogenation of castor oil at 130°C, 2.0 kg/cm2 hydrogen gas pressure with 0.5% Ni catalyst for 6 h while using two turbine impellers fitted in an agitator, one close to
the reactor bottom and another at a height just below the top oil layer, revolving at 350 rpm, resulted in a product of a
iodine value of 4.1, hydroxyl value of 156.4, and slip point of 84°C. 相似文献