Synthesis and characterization of zeolite NaY from rice husk silica

Rice husk silica (RHS) in amorphous phase with 98% purity was prepared from a waste rice husk from rice milling by leaching with hydrochloric acid and calcination. The RHS was used effectively as a silica source for the synthesis of zeolite Y in sodium form (NaY). The zeolite in pure phase was obtained from a two-step synthetic route in which the starting gels were mixed, aged for 24 h at room temperature and crystallized for 24 h at 90 °C. The diameter of single crystal particles from a scanning electron microscope was approximately 1.0 μm, whereas the average particle diameter from laser diffraction particle size analyzer was approximately 10 μm because of the agglomeration of small crystals. Longer crystallization time in this route resulted in a mixed phase containing NaY and zeolite P in sodium form (NaP). In addition, a one-step synthetic route (no aging) was studied and the product was also a mixed phase zeolite.     

Shape effect on weakly nonlinear elliptical composites

The electric field responses of two types of weakly nonlinear dielectric composites consisting of elliptic cylindrical inclusions, one with identical shape and the another with distributed shapes, randomly embedded in the linear host media in the dilute limit are investigated. The dielectric property of the inclusions is that the relation between the displacement (D) and electric (E) fields obey the form D = ?E + χ∣E∣^βE where β is a nonlinear integer exponent and ? ? χ∣E∣^β. By using the decoupling approximation, the effective nonlinear susceptibility (χ_e) is determined and analyzed for varying the aspect ratios and the shape distribution parameters for the composites with identical and distributed inclusion shapes, respectively. In addition, the exact analytic result of χ_e for the elliptical composites with distributed inclusion shapes for the case of β = 2 is derived in this article.     

Visible light-irradiated degradation of alachlor on Fe-TiO<Subscript>2</Subscript> with assistance of H<Subscript>2</Subscript>O<Subscript>2</Subscript>

0.1 Fe/Ti mole ratio of Fe-TiO₂ catalysts were synthesized via solvothermal method and calcined at various temperatures: 300, 400, and 500 °C. The calcined catalysts were characterized by XRD, N₂-adsorption-desorption, UV-DRS, XRF, and Zeta potential and tested for photocatalytic degradation of alachlor under visible light. The calcined catalysts consisted only of anatase phase. The BET specific surface area decreased with the calcination temperatures. The doping Fe ion induced a red shift of absorption capacity from UV to the visible region. The Fe-TiO₂ calcined at 400 °C showed the highest photocatalytic activity on degradation of alachlor with assistance of 30 mM H₂O₂ at pH 3 under visible light irradiation. The degradation fitted well with Langmuir-Hinshelwood model that gave adsorption coefficient and the reaction rate constant of 0.683 L mg⁻¹ and 0.136 mg/L·min, respectively.     

Experimental investigation of evaporation heat transfer coefficient and pressure drop of R-410A in a multiport mini-channel

The evaporation heat transfer coefficient and pressure drop of R-410A flowing through a horizontal aluminium rectangular multiport mini-channel having 3.48 mm hydraulic diameter are experimentally investigated. The test runs are performed at mass flux ranging between 200 and 400 kg/m² s. The heat fluxes are between 5 and 14.25 kW/m² and the saturation temperatures range between 10 and 30 °C. The pressure drop across the test section is directly measured by a differential pressure transducer. The effects of the imposed wall heat flux, mass flux, vapour quality, and saturation temperature on the evaporation heat transfer and pressure drop are also discussed. The results from the present experiment are compared with those obtained from the existing correlation. New correlations for the evaporation heat transfer coefficient and pressure drop of R-410A flowing through a multiport mini-channel are proposed for practical applications.     

Utilization of mesoporous molecular sieves synthesized from natural source rice husk silica to Chlorinated Volatile Organic Compounds (CVOCs) adsorption

The adsorption of trichloroethylene (TCE), tetrachloroethylene (PCE), and carbon tetrachloride was studied over our synthesized mesoporous material, MCM-41, from rice husk silica source, abbreviated as RH-MCM-41. More than 99% silica for RH-MCM-41 synthesis was extracted from rice husk under refluxing in HBr solution and then calcined at 873 K for 4 hours. RH-MCM-41 possessed surface area around 750-1,100 m²/g with a uniform pore size with an average diameter of 2.95 nm, narrow range of pore distribution and somewhat hexagonal structure, similar to properties of parent MCM-41. The adsorption of CC1₄ to RH-MCM-41 was stronger than that of TCE and PCE. The adsorption capacity of RH-MCM-41 for CVOCs (chlorinated volatile organic compounds) was higher than commercial mordenite and activated carbons.     

Adsorption behavior of NO and CO and their reaction over cobalt on zeolite beta

Adsorption behavior of NO and CO as well as their reaction was investigated on cobalt supported zeolite beta (Co/BEA) prepared by solid-state ion exchange (SSIE) and by impregnation (IMP). By temperature programmed desorption (TPD), two NO desorption peaks at 100 and 260‡C were observed over both SSIE and IMP catalysts with complete desorption after 450‡C. CO desorbed from SSIE catalyst between 50 and 200‡C. In the same temperature interval negligible CO₂ desorption was observed, most likely due to reaction of CO with trace of cobalt oxides. Over IMP catalysts, desorption of CO₂ was found mainly at 500‡C. By comparing CO TPD profiles from physical mixtures of cobalt oxides and HBEA, SSIE catalysts most likely contained cobalt cations in zeolite exchange position while IMP catalysts had cobalt in oxidic forms. The SSIE catalysts were active for NO reduction at 400 and 500‡C with a maximum conversion at 500‡C. However, the activity in the presence of water and oxygen was low. Water might inhibit the reaction by blocking active sites for NO and CO, while oxygen reacted with CO to form carbon dioxide. The activity of SSIE was better than IMP catalyst.     

A Visual Study of Two-Phase Flow Patterns of HFC-134a and Lubricant Oil Mixtures

The two-phase flow patterns of HFC-134a with lubricant oil mixtures inside a smooth horizontal tube were experimentally elucidated. Tests were performed in an inside diameter of 7.8 mm having a lubricating oil concentration of 5%. Tests were made of mass fluxes ranging between 150 and 590 kg/m 2 s. The most obvious difference from oil-free cases reported is the presence of froth flow pattern. Apparently, this flow pattern is related to the increase of surface tension and viscosity. With the presence of lubricant oil, the onset of transition from stratified flow region to annular flow regime shifted to a lower value of superficial gas velocity. In addition, the tearing phenomenon of the refrigerant-oil mixtures may be related to its relevant properties such as wettability and surface tension.     

The Effect of the Electrohydrodynamic on the Two-Phase Flow Pressure Drop of R-134a during Evaporation inside Horizontal Smooth and Micro-Fin Tubes

This article concerns the pressure drop caused by using the electrohydrodynamic (EHD) technique during evaporation of pure R-134a inside smooth and micro-fin tubes. The test section is a counter-flow concentric tube-in-tube heat exchanger where R-134a flows inside the inner tube and hot water flows in the annulus. A smooth tube and micro-fin tube having an inner diameter of 8.12 mm and 8.92 mm, respectively, are used as an inner tube. The length of the inner tube is 2.50 m. The outer tube is a smooth copper tube having an inner diameter of 21.2 mm. The electrode, which is a cylindrical stainless steel wire having diameter of 1.47 mm, is placed in the center of the inner tube. The electrical field is established by connecting a DC high voltage power supply of 2.5 kV to the electrode while the inner tube is grounded. Experiments are conducted at saturation temperatures of 10–20°C, mass fluxes of 200–600 kg/m²s, and heat fluxes of 10–20 kW/m². The experimental results indicate that the application of EHD introduces a small pressure drop penalty. New correlations for the pressure drop are proposed for practical applications.