Hole transporting materials play a vital role in improving the performance of perovskite solar cells (PSCs). In this work, different concentrations of poly[bis(4-phenyl)(2, 4, 6-trimethylphenyl)amine] (PTAA) are used to modify the surface of sputtered nickel oxide (NiOx) as hole transport layer (HTL) in inverted PSCs. After the introduction of PTAA, the roughness of the sputtered NiOx films decreases, while the crystallinity of the perovskite layer increases. The carrier transport across the interface between the sputtered NiOx film and the perovskite layer is significantly improved. A power conversion efficiency of 18.5% is achieved based on PTAA-modified sputtered NiOx, exhibiting a 15.2% improvement compared to its pristine counterpart.
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