全文获取类型
收费全文 | 17240篇 |
免费 | 1553篇 |
国内免费 | 683篇 |
专业分类
电工技术 | 998篇 |
技术理论 | 1篇 |
综合类 | 1164篇 |
化学工业 | 2974篇 |
金属工艺 | 1240篇 |
机械仪表 | 1155篇 |
建筑科学 | 1343篇 |
矿业工程 | 661篇 |
能源动力 | 488篇 |
轻工业 | 1004篇 |
水利工程 | 275篇 |
石油天然气 | 1197篇 |
武器工业 | 173篇 |
无线电 | 1623篇 |
一般工业技术 | 2015篇 |
冶金工业 | 960篇 |
原子能技术 | 155篇 |
自动化技术 | 2050篇 |
出版年
2024年 | 110篇 |
2023年 | 386篇 |
2022年 | 591篇 |
2021年 | 868篇 |
2020年 | 636篇 |
2019年 | 478篇 |
2018年 | 567篇 |
2017年 | 624篇 |
2016年 | 527篇 |
2015年 | 729篇 |
2014年 | 854篇 |
2013年 | 997篇 |
2012年 | 1082篇 |
2011年 | 1195篇 |
2010年 | 960篇 |
2009年 | 894篇 |
2008年 | 901篇 |
2007年 | 835篇 |
2006年 | 875篇 |
2005年 | 788篇 |
2004年 | 521篇 |
2003年 | 495篇 |
2002年 | 528篇 |
2001年 | 455篇 |
2000年 | 386篇 |
1999年 | 422篇 |
1998年 | 332篇 |
1997年 | 273篇 |
1996年 | 245篇 |
1995年 | 224篇 |
1994年 | 157篇 |
1993年 | 101篇 |
1992年 | 100篇 |
1991年 | 64篇 |
1990年 | 59篇 |
1989年 | 54篇 |
1988年 | 43篇 |
1987年 | 25篇 |
1986年 | 12篇 |
1985年 | 16篇 |
1984年 | 20篇 |
1983年 | 2篇 |
1982年 | 17篇 |
1981年 | 9篇 |
1980年 | 10篇 |
1979年 | 4篇 |
1977年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Junwei Fu Zhengbiao Zhang Zhenping Cheng Jian Zhu Wei Zhang Xiulin Zhu 《Polymer Bulletin》2008,61(3):287-297
A novel reversible addition-fragmentation chain transfer (RAFT) reagent bearing triphenylamine (TPA)
group, 4-diphenylamino-dithiobenzoic acid benzyl ester (DDABE), was designed and synthesized. It was used
in the RAFT polymerizations of styrene (St) and methyl acrylate (MA) to prepare end-functionalized polymers.
The results of the polymerization showed that the RAFT polymerizations could be well controlled using DDABE
as the RAFT agent. Number-average molecular weight (Mn,GPC) increased linearly
with monomer conversion, and molecular weight distributions were relatively narrow (PDI<
1.50). The results of chain-extension reaction, 1H NMR spectra and UV/Vis
spectra confirmed that most of the polymers chains were end-capped by the functional triphenylamine
(TPA) groups. The effect of feed molar ratios of St/DDABE/AIBN on polymerization was investigated. 相似文献
2.
一种实验炼钢渣不同炉次样品的室温透射穆斯堡尔谱由两组裂距较大的四极分裂双峰和一组裂距较小的双峰组成,它们分别相应于具有不同微观环境的Fe^2+和Fe^3+。参照文献中已知FexO的穆斯堡尔谱数据,可确定该渣中的主要含铁相为FexO。X射线衍射相分析给出相同的结果。按亚谱的面积比计算出Fe^2+和Fe^3+的相对含量分别为85%和15%左右。进一步选取与样品晶体结构相联系的原子簇模型。用MS-Xa方 相似文献
3.
In this paper, we study a manufacturing system consisting of two machines separated by two intermediate buffers, and capable of producing two different products. Each product requires a constant processing time on each of the machines. Each machine requires a constant non-negligible setup change time from one product to the other. The demand rate for each product is considered to be piecewise constant. Each machine undergoes failure and repair. The time-to-failure and time-to-repair are exponentially distributed random variables. The setup change and processing operations are resumable. We model our system as a continuous time, continuous flow process. An optimal control problem is formulated for the system to minimize the total expected discounted cost over an infinite horizon. To determine the optimal control policy structure, a discrete version of the problem is solved numerically using a dynamic programming formulation with a piecewise linear penalty function. A real-time control algorithm is then developed with the objective of maintaining low work-in-process inventory and keeping the production close to the demand. The algorithm uses a hierarchical control structure to generate the loading times for each product on each machine in real time and to respond to random disruptions in the system. The system is simulated using this algorithm to study its performance. The performance of the algorithm is also compared to alternative policies. 相似文献
4.
A new type of polysiloxane modified polyurethane–acrylic hybrid emulsion was synthesized by solvent-free method and the polysiloxane was introduced into the soft segment of polyurethane chains using dihydroxybutyl-terminated polydimethylsiloxane (PDMS). The formed film from the hybrid emulsion could provide obviously higher water-resistance property. The preparation technologies such as the content of carboxy group and acrylic monomer, the rate and the time of emulsification were discussed systematically. The chain structure and the particle size were confirmed by the analysis of Fourier transform infrared spectroscopy and transmission electron microscopy, respectively. The effect of PDMS content on the water resistance and the mechanical property were investigated by absorbed water ratio, water contact angle and dynamic mechanical measurement. 相似文献
5.
本文分析了离心复合铸造轧辊生产过程中离心机停机温度和时间对轧辊质量的影响 ,提出了用先进的红外测温技术来预报停机温度和时间 ,以实现微机监控适时停机 ,保证轧辊内外层熔合良好 ;同时指出了红外测温技术在离心复合铸造轧辊生产上的应用前景 相似文献
6.
塑料在包装领域有着广泛的应用,其中聚酯(PET)性能优良,应用领域不断扩大。介绍了塑料包装不断通现的新技术,以及塑料包装环保问题的几点思路。 相似文献
7.
Jinpeng Zhang Hongfeng Gao Nini Yuan Qiang Wang Yuhua Wu Yanli Sun Hongcun Bai 《中国化学工程学报》1982,28(11):2771-2777
Understanding and modulating the interaction between various reactive molecules and oxygen carriers are the key issue to achieve process intensification of chemical looping technology. C1 chemical molecules play an important role in many reactions involved with chemical looping processes. However, up to now, there is still a lack of systematic and in-depth understanding of the adsorption mechanism of C1 molecules on the surface of oxygen carriers (OCs). In this work, the intrinsic interaction between a series of C1 molecules composed of CH4, CO, CO2, CH3OH, HCHO and HCOOH and surface of NiO OCs in the chemical looping process have been studied using density functional theory calculations. Various adsorption configurations of C1 molecules and also different adsorption sites of NiO have been considered. The structural features of stable configuration of C1 molecules on the surface of NiO OCs have been obtained. Further, the interacted sites, types and strengths of C1 molecules on the surface of NiO have been directly pictured by the independent gradient model methods. Also, the nature of the interaction between C1 molecule and NiO surface has been investigated with the aid of energy decomposition analysis from a quantitative view. 相似文献
8.
Sodium-ion battery (SIB) is an ideal device that could replace lithium-ion battery (LIB) in grid-scale energy storage system for power because of the low cost and rich reserve of raw material. The key challenge lies in developing electrode materials enabling reversible Na+ insertion/desertion and fast reaction kinetics. Herein, a core-shell structure, FeS2 nanoparticles encapsulated in biphase TiO2 shell (FeS2@TiO2), is developed towards the improvement of sodium storage. The diphase TiO2 coating supplies abundant anatase/rutile interface and oxygen vacancies which will enhance the charge transfer, and avoid severe volume variation of FeS2 caused by the Na+ insertion. The FeS2 core will deliver high theoretical capacity through its conversion reaction mechanism. Consequently, the FeS2@TiO2 nanorods display notable performance as anode for SIBs including long-term cycling performance (637.8 mA·h·g-1 at 0.2 A·g-1 after 300 cycles, 374.9 mA·h·g-1 at 5.0 A·g-1 after 600 cycles) and outstanding rate capability (222.2 mA·h·g-1 at 10 A·g-1). Furthermore, the synthesized FeS2@TiO2 demonstrates significant pseudocapacitive behavior which accounts for 90.7% of the Na+ storage, and efficiently boosts the rate capability. This work provides a new pathway to fabricate anode material with an optimized structure and crystal phase for SIBs. 相似文献
9.
Yiming Zeng Zhigang Wang Lijun Wan Yanqiao Shi Guanwen Chen Chunli Bai 《应用聚合物科学杂志》2003,88(5):1328-1335
By the use of atomic force microscopy (AFM), formation mechanism of nodular structure in cellulose acetate membranes was systematically investigated. Elementary factors affecting the nodule formation were delineated on the basis of both kinetic and thermodynamic considerations. It was shown that (1) the exact nature of nodular structure is thermodynamic equilibrium glassy state; nodular structure will vanish in the rubbery state; (2) the thermodynamic factor affecting nodule formation is the membrane formation temperature; with the membrane formation temperature decreasing, more chain segments are able to form nodular structures; (3) nodule formation is dependent on the segment rearrangement; variation of the solvent environment is the major kinetic factor affecting the segment rearrangement and nodule formation. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 1328–1335, 2003 相似文献
10.