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1.
    
Hexagonal-phase NaYF(4):Yb(3+),Er(3+) up-conversion nanocrystals (UCNCs) are synthesized by a combination of refluxing and hydrothermal treatment. This strategy leads to only a slight increase in particle size, from 4.5 to ca. 10 nm, during the cubic-to-hexagonal phase transition. The hexagonal UCNCs can be internalized by HeLa cells and exhibit visible emission in the cells under near-infrared excitation.  相似文献   
2.
Design of dual-polarized L-probe patch antenna arrays with high isolation   总被引:4,自引:0,他引:4  
An experimental study of a dual-polarized L-probe patch antenna is presented. The antenna is designed to operate at around 1.8 GHz. A "dual-feed" technique is introduced to achieve high isolation between two input ports. The proposed antenna has an impedance bandwidth of 23.8% (SWR/spl les/2), 15% (SWR/spl les/1.5) and an isolation over 30 dB. In array designs, techniques for improving the isolation between two adjacent elements of an antenna array are also investigated. A two-element array with more than 30 dB isolation is designed and tested.  相似文献   
3.
    
Zou  Rui  Huang  Junjian  Shi  Junpeng  Huang  Lin  Zhang  Xuejie  Wong  Ka-Leung  Zhang  Hongwu  Jin  Dayong  Wang  Jing  Su  Qiang 《Nano Research》2017,10(6):2070-2082
Near-infrared (NIR) persistent-luminescence nanoparticles have emerged as a new class of background-free contrast agents that are promising for in vivo imaging.The next key roadblock is to establish a robust and controllable method for synthesizing monodisperse nanoparticles with high luminescence brightness and long persistent duration.Herein,we report a synthesis strategy involving the coating/etching of the SiO2 shell to obtain a new class of small NIR highly persistent luminescent ZnGa2O4∶Cr3+,Sn4+ (ZGOCS) nanoparticles.The optimized ZGOCS nanoparticles have an excellent size distribution of ~15 nm without any agglomeration and an NIR persistent luminescence that is enhanced by a factor of 13.5,owing to the key role of the SiO2 shell in preventing nanoparticle agglomeration after annealing.The ZGOCS nanoparticles have a signal-to-noise ratio ~3 times higher than that of previously reported ZnGa2O4∶Cr3+ (ZGC-1) nanoparticles as an NIR persistent-luminescence probe for in vivo bioimaging.Moreover,the persistent-luminescence signal from the ZGOCS nanoparticles can be repeatedly re-charged in situ with external excitation by a white lightemitting diode;thus,the nanoparticles are suitable for long-term in vivo imaging applications.Our study suggests an improved strategy for fabricating novel high-performance optical nanoparticles with good biocompatibility.  相似文献   
4.
The synthesis of YAlO3 is described from commercially-available yttria and alumina preformed sols which have nanometer particle-size ranges. The products have been characterized by X-ray diffraction (XRD), diffuse reflectance infrared Fourier transform (DRIFT) spectra, thermogravimetry—derivative thermogravimetry—differential thermal analysis (TG-DTG-DTA), scanning electron microscopy (SEM) as well as CHN-analysis, and are similar to those prepared by the alkoxide, nitrate and citrate routes. The proposed method is a simple, cheap and rapid synthetic route.  相似文献   
5.
In literature, the reaction kinetic of pyrolysis process is often determined and modelled under constant heating rates. In reality, the heating rate of an industrial pyrolysis process is difficult or often not necessary to be kept constant. The variation of heating rate at different reaction stages, termed “dynamic heating”, governs the pyrolysis performance such as production rate, energy consumption, product quality, etc. In this work, pyrolysis progress with dynamic heating is being studied. The rate and reaction heat of tyre pyrolysis at different heating rates are obtained experimentally. A transient model considering the effect of dynamic heating was then developed and compared with the conventional static heating model. Results show that a higher heating rate favours the production of volatiles and shifts the overall pyrolysis heat flow to more endothermic. The significance of the dynamic heating model was observed for processes with large feed size and/or with high heating rate.  相似文献   
6.
    
Examples of trinuclear lanthanide (Ln) complexes using bridging sulfato and hydroxo ligands for Ln = Eu and Tb are reported. Structural data demonstrate that three nine-coordinate Ln3+ ions are caged in a monomeric structure in [Ln3(phen)3(OH)(SO4)4(DMF)3] · DMF · H2O, with Ln?Ln distances slightly greater than 4 Å. The luminescence and excitation spectra have been recorded and interpreted.  相似文献   
7.
Mechanoluminescence(ML) is the emission of light consecutive to a mechanical force or stress imposed to a crystalline material. Many inorganic and organic compounds present this phenomenon that is known for over 400 years. Lanthanide and uranyl salts were among the first substances investigated for this property. Mechanoluminescence, also referred to as tribo luminescence, is often considered as being a badly understood phenomenon. In fact it is because of two main reasons. Firstly, a variety of different mechanical stresses, from simple rubbing, to applied pressure, crushing, impact of a weight, ultrasound,laser-generated shock wave, crystallization, dissolution of crystals, or even wind can trigger it. Secondly,ML is very sensitive to the purity and morphology of the sample: in inorganic compounds, generation of traps by doping "impurities"(e.g. lanthanide ions) is responsible for light emission so that the exact composition of the sample has to be known to a very detailed level; for chelates, the crystallization conditions are crucial since they often generate extended networks of weak interactions that are instrumental in triggering ML when they are broken. In fact mechanisms of ML are relatively well known and theories and models often reproduce very well the experiments. Additionally, practical applications are at hand,for example stress,crack,and impact sensors based on SrAl_2 O_4:Eu~Ⅱ or Et_3 NH[Eu(dbm)_4] are used to test structures and materials as diverse as road bridges, reinforced concrete elements, pressurized containers or airplane wings and to image the propagation of cracks or stress distribution. Military and security applications involve detecting the passage of vehicle or soldiers and producing counterfeiting inks while more joyful applications are luminous balls, wrapping papers and adhesive tapes. Not only bulk materials, but micro-and nanoparticles feature mechanoluminescent properties and single particle manipulation under an AFM allows one to produce light sources that could be useful to several photonic applications, including bio-applications.The review starts with a short historical background of ML, discussing definitions, and providing some theoretical bases. It then presents instrumental setups before covering all aspects of lanthanide mechanoluminescence, starting with simple salts, then doped inorganic compounds(irradiated and nonirradiated) and finally chelates. Mechanoluminescent sensors are described with various actual and potential applications. Literature is covered until April 2017. The wealth of information gathered during the past 20 years in the field and the broad understanding of the phenomenon attained show that the field is presently ready for a quantitative leap forward. Many subjects are waiting to be developed,including NIR mechanoluminescence or bio-applications based on single mechanoluminescent particle light sources; in addition, designing new types of mechanoluminescent materials with techniques paralleling the developments in other aspects of lanthanide photonics could prove extremely rewarding.  相似文献   
8.
    
The need to reduce the harmful consequences of environmental damage is fueling the development of environmentally friendly products. However, many people believe that being fashionable and being environmentally conscious are in direct conflict, and they question whether these two concepts can coexist. The results of a questionnaire survey of 327 consumers from South Korea show that consumers’ involvement in fashion is not necessarily linked to their intention to buy and consume sustainable fashion. This finding motivated us to investigate whether there are any barriers that restrict the popularization of sustainable fashion and, if so, how we can solve such a problem. From this perspective, an in-depth interview study was conducted to consolidate the views of five fashion professionals to reveal the major barriers to popularization. The ultimate goal is to explore solutions to bridge the gap between the supply and demand for sustainable fashion. The findings of this study extend our understanding of consumers’ attitude toward two conflicting values – fashionism and environmentalism, as well as the popularization barriers of sustainable fashion. This understanding is imperative to the promotion of the green movement in the fashion industry, particularly in Asian countries.  相似文献   
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10.
    
The host interactome of influenza viral proteins is ever-expanding. In this work, we report the identification of host heterogeneous nuclear ribonucleoprotein C (hnRNP-C) as an interacting partner of influenza A virus nucleoprotein (NP). We confirmed that this interaction exists across different influenza A subtypes and strains. Using biochemical methods, we determined that hnRNP-C interacts with NP via its C-terminal auxiliary domain. Further, we determined that the hnRNP-C is a negative regulator of influenza viral growth. Its interaction with NP is implicated in the promotion of host cell apoptosis during viral infection. It is the first time that the interaction between influenza nucleoprotein and host heterogeneous nuclear ribonucleoprotein C is characterized in detail. Overall, these findings not only characterize the interaction between NP and its host interacting partner hnRNP-C but also clarify the functional significance of this interaction. This work may lead to a new therapeutic target for the development of anti-influenza drugs.  相似文献   
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