Sodium silicate as a coke inhibitor during naphtha pyrolysis

Rates of coke formation during steam pyrolysis of naphtha have been investigated in a jet-stirred reactor both for sodium silicate coated and uncoated Inconel 600 surfaces in the temperature range of 1078–1108 K. Coke formation rates were significantly reduced on sodium silicate coated plates due to the passivation of the metal surface. However, the coking rates gradually increased with successive decokings of the coated surface.     

Impact of communication time delays on combined LFC and AVR of a multi-area hybrid system with IPFC-RFBs coordinated control strategy

In this paper, the impact of communication time delays (CTDs) on combined load frequency control (LFC) and automatic voltage regulation (AVR) of a multi-area system with hybrid generation units is addressed. Investigation reveals that CTDs have significant effect on system performance. A classical PID controller is employed as a secondary regulator and its parametric gains are optimized with a differential evolution - artificial electric field algorithm (DE-AEFA). The superior performance of the presented algorithm is established by comparing with various optimization algorithms reported in the literature. The investigation is further extended to integration of redox flow batteries (RFBs) and interline power flow controller (IPFC) with tie-lines. Analysis reveals that IPFC and RFBs coordinated control enhances system dynamic performance. Finally, the robustness of the proposed control methodology is validated by sensitivity analysis during wide variations of system parameters and load.     

Nitrogen incorporated diamond-like carbon films by microwave surface wave plasma CVD

Nitrogen incorporated diamond like carbon films have been deposited by microwave surface wave plasma chemical vapor deposition (MW-SWP-CVD), using methane (CH₄) as the source of carbon and with different nitrogen flow rates (N₂ / CH₄ flow ratios between 0 and 3). The influence of the nitrogen incorporation on the optical, structural properties and surface morphology of the carbon films were investigated using different spectroscopic techniques. The nitrogen has been incorporated into DLC:N films which was confirmed by the X-ray photoelectron spectroscopy (XPS) measurement. Moreover, the nitrogen incorporation was accompanied by a variation in the optical gap, which was attributed to the removal or creation of band tail states.     

Evaluation of Concurrent Flaw Populations in Silicon Carbide in Terms of a Modified Weibull Distribution Function

Concurrent surface- and edge-flaw populations are often observed in strength testing of ceramics The overall strength distribution in such ceramic samples has been analyzed in terms of a modified Weibull distribution function. The junction provides an upper and lower strength limit and is characterized by two shape and location parameters. To evaluate the parameters of the distribution function, the type of flaw that causes failure need not be identified. The applicability of the function has been evaluated in terms of experimental results on SiC specimens. The analysis also shows that the relative values of shape parameters determine which flaw type dominates.     

Diamond-like carbon thin films by microwave surface-wave plasma CVD aimed for the application of photovoltaic solar cells

The nitrogen doped diamond-like carbon (DLC) thin films were deposited on quartz and silicon substrates by a newly developed microwave surface-wave plasma chemical vapor deposition, aiming the application of the films for photovoltaic solar cells. For film deposition, we used argon as carrier gas, nitrogen as dopant and hydrocarbon source gases, such as camphor (C₁₀H₁₆O) dissolved with ethyl alcohol (C₂H₅OH), methane (CH₄), ethylene (C₂H₄) and acetylene (C₂H₂). The optical and electrical properties of the films were studied using X-ray photoelectron spectroscopy, Nanopics 2100/NPX200 surface profiler, UV/VIS/NIR spectroscopy, atomic force microscope, electrical conductivity and solar simulator measurements. The optical band gap of the films has been lowered from 3.1 to 2.4 eV by nitrogen doping, and from 2.65 to 1.9 eV by experimenting with different hydrocarbon source gases. The nitrogen doped (flow rate: 5 sccm; atomic fraction: 5.16%) film shows semiconducting properties in dark (i.e. 8.1 × 10^{− 4} Ω^{− 1} cm^{− 1}) and under the light illumination (i.e. 9.9 × 10^{− 4} Ω^{− 1} cm^{− 1}). The surface morphology of the both undoped and nitrogen doped films are found to be very smooth (RMS roughness ≤ 0.5 nm). The preliminary investigation on photovoltaic properties of DLC (nitrogen doped)/p-Si structure show that open-circuit voltage of 223 mV and short-circuit current density of 8.3 × 10^{− 3} mA/cm². The power conversion efficiency and fill factor of this structure were found to be 3.6 × 10^{− 4}% and 17.9%, respectively. The use of DLC in photovoltaic solar cells is still in its infancy due to the complicated microstructure of carbon bondings, high defect density, low photoconductivity and difficulties in controlling conduction type. Our research work is in progress to realize cheap, reasonably high efficiency and environmental friendly DLC-based photovoltaic solar cells in the future.     

Synthesis of nitrogen incorporated diamond-like carbon thin films using microwave surface-wave plasma CVD

Nitrogenated diamond-like (DLC:N) carbon thin films have been deposited by microwave surface wave plasma chemical vapor deposition on silicon and quartz substrates, using argon gas, camphor dissolved in ethyl alcohol composition and nitrogen as plasma source. The deposited DLC:N films were characterized for their chemical, optical, structural and electrical properties through X-ray photoelectron spectroscopy, UV/VIS/NIR spectroscopy, Raman spectroscopy, atomic force microscope and current–voltage characteristics. Optical band gap decreased (2.7 to 2.4 eV) with increasing Ar gas flow rate. The photovoltaic measurements of DLC:N / p-Si structure show that the open-circuit voltage (V_oc) of 168.8 mV and a short-circuit current density (J_sc) of 8.4 μA/cm² under light illumination (AM 1.5 100 mW/cm²). The energy conversion efficiency and fill factor were found to be 3.4 × 10^{− 4}% and 0.238 respectively.     

An Architectural Framework for Accurate Characterization of Network Traffic

In networks carrying large volume of traffic, accurate traffic characterization is necessary for understanding the dynamics and patterns of network resource usage. Previous approaches to flow characterization are based on random sampling of the packets (e.g., Cisco's NetFlow) or inferring characteristics solely based on long lived flows (LLFs) or on lossy data structures (e.g., bloom filters, hash tables). However, none of these approaches takes into account the heavy-tailed nature of the Internet traffic and separates the estimation algorithm from the flow measurement architecture.In this paper, we propose an alternate approach to traffic characterization by closely linking the flow measurement architecture with the estimation algorithm. Our measurement framework stores complete information related to short lived flows (SLFs) while collecting partial information related to LLFs. For real-time separation of LLFs and SLFs, we propose a novel algorithm based on typical sequences from Information theory. The distribution (pdf) and sample space of the underlying traffic is estimated using the non-parametric Parzen window technique and likelihood function defined over the Coupon collector problem. We validate the accuracy and performance of our estimation technique using traffic traces from the internal LAN in our laboratory and from National Library for Applied Network Research (NLANR).     

Appearance Harmonization for Single Image Shadow Removal

Shadow removal is a challenging problem and previous approaches often produce de‐shadowed regions that are visually inconsistent with the rest of the image. We propose an automatic shadow region harmonization approach that makes the appearance of a de‐shadowed region (produced using any previous technique) compatible with the rest of the image. We use a shadow‐guided patch‐based image synthesis approach that reconstructs the shadow region using patches sampled from non‐shadowed regions. This result is then refined based on the reconstruction confidence to handle unique textures. Qualitative comparisons over a wide range of images, and a quantitative evaluation on a benchmark dataset show that our technique significantly improves upon the state‐of‐the‐art.     

Dynamic Modeling and Simulation of Impact in Tether Net/Gripper systems

The objective of this paper is to study the dynamic modeling andsimulation of a tether-net/gripper system during an impact, while it isbeing deployed or retrieved by a winch on a satellite orbiting aroundearth. We stick to Tether-Net system but the analysis is applicable toTether-Gripper systems too. We assume that the net is deployed from thesatellite in orbit and the motion is restricted to the orbital plane.This net captures a second satellite and tows it. The motion of atether-net system can be broken down into the following phases: (i)Phase 1: Net is shot out from the satellite with the tether completelyslack, (ii) Phase 2: Net comes to a location where the tether is tautwhile the drum on the orbiter is locked, (iii) Phase 3: Drum is unlockedand the net moves with the tether, (iv) Phase 4: Net captures a body.The continua (tether) is modeled using mode functions and coordinates.The theory of impulse and momentum can be used to model Phases 1, 2, and4 of motion of the tether-net system. The dynamics of the motion of thesystem in phase 3 is characterized by differential and algebraicequations (DAEs). Matlab ODE solvers were used to solve these DAEs.     

Note: Compact high voltage pulse transformer made using a capacitor bank assembled in the shape of primary

The experimental results of an air-core pulse transformer are presented, which is very compact (<10 Kg in weight) and is primed by a capacitor bank that is fabricated in such a way that the capacitor bank with its switch takes the shape of single-turn rectangular shaped primary of the transformer. A high voltage capacitor assembly (pulse-forming-line capacitor, PFL) of 5.1 nF is connected with the secondary of transformer. The transformer output voltage is 160 kV in its second peak appearing in less than 2 μS from the beginning of the capacitor discharge. The primary capacitor bank can be charged up to a maximum of 18 kV, with the voltage delivery of 360 kV in similar capacitive loads.