Iron pyrite films prepared by sulfur vapor transport

Iron films deposited via thermal evaporation, with a thickness between 100 and 250 nm, were converted into FeS₂ by open sulfur transport using nitrogen as a gas vector. The films thus obtained constituted a single pyrite phase and were optically highly absorbing. The sulfurization process was optimized. As a result, sample temperature and conversion time were found to be the major determining parameters. The films were characterized using several methods. The crystallinity and phase identification were determined by X-ray diffractometry. Scanning electron microscopy showed a homogeneous surface of both iron and pyrite layers. Optical transmission measurements confirmed the highly absorbing character of FeS₂ and allowed the determination of direct (1.35 eV) and indirect (0.82 eV) transitions.     

Solar cookers for outdoors and indoors

The solar cooking process has been investigated to develop safe, simple, portable, and reliable solar cookers. The concept of insulated and vapor-tight pots has been introduced and applied to oven, point-focus and heat-pipe cookers. A new, flat-plate cooker with heat pipes has been developed. It requires no tracking and allows cooking to be done in the shade or indoors. Also, a novel-portable cooker, the Mina Oven, featuring a vapor-tight pot and an integral collector with reflector flaps, has been constructed and tested. A second portable cooker that has been developed is the Arafa Cooker, which comprises a parabolic dish focused at a glazed and insulated receiver. Experiments indicated that all cookers yielded satisfactory performance, with cooking times of 25–45 min per kg of food per m² of solar collection area while operating from 10 a.m. to 4 p.m.     

Investigations on mode-division multiplexed free-space optical transmission for inter-satellite communication link

Wireless Networks - Inter-satellite data transmission links are very crucial for providing global inter-connectivity. We report designing and investigations on high date rate inter-satellite...     

Evaluation of rutting potential for asphalt concrete mixes containing copper slag

Copper slag (CS) is a by-product of the copper extraction process, which can be used as coarse and/or fine aggregate in hot mix asphalt (HMA) pavements. This study used CS as a replacement of the fine aggregate with a percentage of up to 40% by total aggregate weight. The objective of this study was to evaluate the effect of CS on the rutting potential of the asphalt concrete mix using two methods. One method is based on the Dynamic modulus |E*| testing result. Actual pavement temperature data from a test section were used with the developed |E*| master curves. EverStressFE finite element program was used to perform a linear elastic load-deformation analysis for a pavement section and to determine the vertical resilient strain in a 40-mm HMA surface layer. The M-E PDG permanent deformation model was used with and Excel Visual Basic for Applications code to predict the accumulated rutting for different CS mixes for 10 million ESALs. The other method used the data from the flow number (FN) test. Based on the |E*| approach, the results indicated that adding 5% CS in the mix increased the predicted rutting from 0.59 to 0.98 mm at 10 million ESALs (increase by 68%). When 40% CS was used, rutting increased by more than 700% compared with the control mix. After analysing the FN results with the Francken model, the results indicated a decrease in FN as CS content is increased, indicating higher rutting potential. The decrease in FN ranged from 9% for 5% CS to 95% for 40% CS. The mixes containing up to 10% CS satisfied the minimum FN criteria for rutting. A calibration process for the M-E PDG distress prediction models that allows the use of waste and by-product materials such as CS should be considered in the future.     

Inter-plant hydrogen integration with regeneration placement and multi-period consideration

Inter-plant hydrogen integration (IPHI) is getting more attention in recent years, as a result of the increasing demand for hydrogen in refinery processes, such as hydrotreating and hydrocracking. In this work, IPHI with regeneration scheme is analyzed. Indirect integration scheme is adopted, where hydrogen sources from different hydrogen networks are integrated via a centralized purifier, such as pressure swing adsorption (PSA) or membrane separation. The introduced model is able to select the optimum interception unit, which minimizes the total annualized cost. Besides, multi-period consideration is included in the analysis to address the effect of changes in operating conditions of the IPHI network on total hydrogen consumption. Two case studies are presented to demonstrate the applicability and usefulness of the proposed model.     

A human-assisted knowledge extraction method for machining operations

This paper deals with a human-assisted knowledge extraction method to extract “if…then…” rules from a small set of machining data. The presented method utilizes both probabilistic reasoning and fuzzy logical reasoning to benefit from the machining data and from the judgment and preference of a machinist. Using the extracted rules, one can determine the values of operational parameters (feed, cutting velocity, etc.) to ensure the desired machining performance (keep surface roughness within the stipulated range (e.g., moderate)). Applying the presented method in a real-life machining knowledge extraction situation and comparing it with the inductive learning based knowledge extraction method (i.e., ID3), the usefulness of the method is demonstrated. As the concept of manufacturing automation is shifting toward “how to support humans by computers”, the presented method provides some valuable hints to the developers of futuristic computer integrated manufacturing systems.     

PERIODIC VARIATIONS OF LANTHANIDES YKERGIC EXTRACTION BY THENOYLTRI-FLUOROACETONE AND TRIPHENYLPHOSPHINE OXIDE MIXTURE∗

Abstract

The synergic extraction of the different lanthani-des, except Pm and Lu, by thenoyltrifluoroacetone (HTTA) and triphenylphosphine oxide (TPPO) mixture in benzene from an aqueous perchlorate medium of constant ionic strength of 0·2 was investigated. It was found that the main adduct extracted contains the lanthanide chelates together with two TPPO molecules. The different extraction and formation constants for the lanthanides investigated have been determined. The variations of the logarithmic values of the chelate extraction constant and the adduct formation constant with the different lanthanides was discussed in the light of the tetrad and the inclined-W effects. The experimental results showed that the nature of coordination by adduct formation for the Yb-Sm group is different than that of the Pr-La group.     

Comment on ‘Discussion on Barkhausen and Nyquist stability criteria’

This comment is related to the recently published article entitled “On ‘Discussion on Barkhausen and Nyquist stability criteria’, Analog Integrated circuits and signal processing, Vol. 70, pp. 443–449, 2012. In this article the authors considered one of the possible four alternatives of the Wien-bridge oscillator that was previously considered in the article entitled “Discussion on Barkhausen and Nyquist stability criteria”, Analog Integrated Circuits and Signal Processing, Vol. 62, pp. 327–332, 2010, which depicts the failure of Barkhausen criterion concerning the determination of the condition of oscillation startup of sinusoidal oscillation. In the above mentioned articles the operational amplifier used is assumed ideal. In this comment it will be shown that the Wien-bridge oscillator circuit used in the above mentioned articles can behave as a sinusoidal oscillator only at relatively high frequencies when the operational amplifier can be considered non-ideal. At relatively low frequencies; when the operational amplifier can be considered ideal, the same circuit behaves as a relaxation oscillator with a square wave output rather than a sinusoidal output.