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Dielectric spectroscopy of Nano BaTiO/sub 3/ confined in MCM-41 mesoporous molecular sieve materials
Kinka M. Banys J. Bohlmann W. Bierwirth E. Hartmann M. Michel D. Volkel G. Poppl A. 《IEEE transactions on ultrasonics, ferroelectrics, and frequency control》2006,53(12):2305-2308
Dielectric properties of barium titanate (BaTiO3) particles, synthesized directly in the pores of MCM-41 materials, have been investigated in the frequency range from 20 Hz to 1 MHz for temperature intervals from 100 K to 500 K. The dielectric spectra of BaTiO3 confined in these molecular sieves were compared with the results obtained from the investigation of pure MCM-41 materials. Obtained results confirmed successful incorporation of BaTiO3 into porous matrix, but no phase transition from paraelectric to ferroelectric phase was observed due to the particle size being smaller than the critical size. Also, the overall dielectric response of investigated materials is strongly influenced by adsorbed water molecules 相似文献
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Martynas Kinka Juras Banys Winfried B?hlmann Eicke Bierwirth Martin Hartmann Dieter Michel Georg V?lkel Andreas P?ppl 《IEEE transactions on ultrasonics, ferroelectrics, and frequency control》2006,53(12):2305-2308
Dielectric properties of barium titanate (BaTiO3) particles, synthesized directly in the pores of MCM-41 materials, have been investigated in the frequency range from 20 Hz to 1 MHz for temperature intervals from 100 K to 500 K. The dielectric spectra of BaTiO3 confined in these molecular sieves were compared with the results obtained from the investigation of pure MCM-41 materials. Obtained results confirmed successful incorporation of BaTiO3 into porous matrix, but no phase transition from paraelectric to ferroelectric phase was observed due to the particle size being smaller than the critical size. Also, the overall dielectric response of investigated materials is strongly influenced by adsorbed water molecules. 相似文献
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