Measurements and correlation of effect of cosolvents on the solubilities of complex molecules in supercritical carbon dioxide

A new transparent microscale circulation-type high pressure equilibrium cell with on-line sampling was devised. With this apparatus, experimental solubility of molecularly complex species such as steroids (cholesterol, stigmasterol and ergosterol) and fatty acids (palmitic acid and stearic acid) in supercritical carbon dioxide(sc-C0₂) were measured. Also, to find an appropriate substance for enhancing both the polarity and the solubility power of the SC-CO₂ solvent, we arbitrarily selected three polar substances such as acetone, methanol and water and the effect of these cosolvents on the solubility of solutes in SC-CO₂ are examined. The supercritical phase equilibrium data of solute-cosolvent-sc-CO₂ systems were quantitatively correlated using a new equation of state based on the lattice fluid theory incorporated with the concept of multibody interaction. We found that the addition of tracer amount of acetone or methanol to SC-CO₂ enhances the solubility of all solutes about thirty to sixty times when compared with the case of pure sc-CO₂ However, for the case of cosolvent water, no further enhancement of the solubility of solutes was realized. Also, the versatile fittability of the equation of state proposed in this work was demonstrated with the newly measured ternary supercritical equilibrium data.     

Bandwidth Adaptation Algorithms for Adaptive Multimedia Services in Mobile Cellular Networks

The fluctuation of available link bandwidth in mobilecellular networks motivates the study of adaptive multimediaservices, where the bandwidth of an ongoing multimedia call can bedynamically adjusted. We analyze the diverse objectives of theadaptive multimedia framework and propose two bandwidth adaptationalgorithms (BAAs) that can satisfy these objectives. The firstalgorithm, BAA-RA, takes into consideration revenue and``anti-adaptation' where anti-adaptation means that a user feelsuncomfortable whenever the bandwidth of the user's call ischanged. This algorithm achieves near-optimal total revenue withmuch less complexity compared to an optimal BAA. The secondalgorithm, BAA-RF, considers revenue and fairness, and aims at themaximum revenue generation while satisfying the fairnessconstraint defined herein. Comprehensive simulation experimentsshow that the difference of the total revenue of BAA-RA and thatof an optimal BAA is negligible. Also, numerical results revealthat there is a conflicting relationship between anti-adaptationand fairness.     

Mobility management for VoIP service: Mobile IP vs. SIP

Wireless Internet access has gained significant attention as wireless/mobile communications and networking become widespread. The voice over IP service is likely to play a key role in the convergence of IP-based Internet and mobile cellular networks. We explore different mobility management schemes from the perspective of VoIP services, with a focus on Mobile IP and session initiation protocol. After illustrating the signaling message flows in these two protocols for diverse cases of mobility management, we propose a shadow registration concept to reduce the interdomain handoff (macro-mobility) delay in the VoIP service in mobile environments. We also analytically compute and compare the delay and disruption time for exchanging signaling messages associated with the Mobile IP and SIP-based solutions.     

Nondestructive evaluation of the characteristics of degraded materials using backward radiated ultrasound

The frequency dependency of Rayleigh surface wave is investigated indirectly by measuring the angular dependency of the backward radiation of the incident ultrasonic wave in two kinds of degraded specimens by scuffing or corrosion. Then, the frequency dependency is compared with the residual stress distribution or the corrosion-fatigue characteristics for the scuffed or corroded specimens, respectively. The width of the backward radiation profile increases with the increase of the variation in residual stress distribution for the scuffed specimens. In the corroded specimens, the profile width decreases with the increase of the effective aging layer thickness and is inversely proportional to the exponent, m, in the Paris’ law that can predict the crack size increase due to fatigue. The result observed in this study demonstrates high potential of backward radiated ultrasound as a tool for nondestructive evaluation of subsurface gradient of material degradation generated by scuffing or corrosion.     

W-band divide-by-3 frequency divider using 0.1 /spl mu/m InAlAs/InGaAs metamorphic HEMT technology

A W-band divide-by-3 frequency divider with wide bandwidth and low power dissipation is presented using harmonic injection-locking technique. A cascode FET is employed for a self-oscillating second-harmonic mixer which is injection-locked by third-harmonic input to obtain the division order of three. The fabricated frequency divider using 0.1 /spl mu/m GaAs metamorphic HEMT technology shows superior performance such as large bandwidth of 6.1 GHz around 83.1 GHz (7.3%) under small DC power consumption of 12 mW.     

Instability of solid–liquid interface in transitional metal–carbide systems

The instability of solid–liquid interface (ISLI) during the liquid-phase sintering was studied using carbide–Ni composites. Of the various transitional metal carbides TiC of 4th period is the only carbide that exhibits a strong ISLI with negative curvatures in molten Ni. No ISLI was observed for other carbides in the 5th and 6th periods. The origin of ISLI is strain developed at the interface between the carbides and the newly formed solid solutions. The difference in the size of the atoms involved can be used to predict the formation of a carbide–Ni solid solution when the Hume-Rothery rules are applied. Aside from the size factor, other factors in the rules are not effective in predicting this phenomenon.     

Kernel Spectral Matched Filter for Hyperspectral Imagery

In this paper a kernel-based nonlinear spectral matched filter is introduced for target detection in hyperspectral imagery, which is implemented by using the ideas in kernel-based learning theory. A spectral matched filter is defined in a feature space of high dimensionality, which is implicitly generated by a nonlinear mapping associated with a kernel function. A kernel version of the matched filter is derived by expressing the spectral matched filter in terms of the vector dot products form and replacing each dot product with a kernel function using the so called kernel trick property of the Mercer kernels. The proposed kernel spectral matched filter is equivalent to a nonlinear matched filter in the original input space, which is capable of generating nonlinear decision boundaries. The kernel version of the linear spectral matched filter is implemented and simulation results on hyperspectral imagery show that the kernel spectral matched filter outperforms the conventional linear matched filter.