珠钢不锈钢冶炼技术探讨

本文阐述了不锈钢冶炼的关键技术，为生产准备提供帮助。     

Effects of Heat Treatment on the Transformation Temperature and the Microstructure of Ni-Ti-Nb Shape Memory Alloy

The effects of heat treatment on the phase transformation temperature and the microstructure of Ni-Ti-Nb alloy have been investigated by means of R-T method, TEM and EPMA. With the increase of annealing temperature, cooling rate and ageing temperature, the Ms temperature increases. TEM observations show no new precipitated phase was found in the B2 parent phase after heat treatment, but EPMA shows the content of Ni (or Ni/Ti ratio) in the B2 matrix changed. The main reason for the change of transformation temperature lies in the change of the matrix composition (or Ni/Ti ratio) with the variation of heat treatment procedure.     

pH传感器温度补偿模型研究

水质pH值在线监测对提高水产品健康养殖至关重要,本文将无线传感器网络与pH值传感器相集成,设计了pH值监测的无线传感器网络系统。为克服pH值测量过程中温度对测量结果的影响,提出了一种pH传感器温度补偿模型,该模型通过pH传感器和PT100铂电阻温度传感器分别测量溶液的pH值和温度,利用最小二乘法对pH值和电压进行线性分析,建立pH传感器的温度补偿模型。实验结果表明,该补偿模型测量精度高,能够实现较精确的pH值在线监测。     

2004年起中国将启用新的金属废料分类目录及报关方法

在交流条件硅酸钠溶液中利用微等离子体氧化技术合成了陶瓷涂层。通过XRD，EPMA分析了所得陶瓷涂层在不同层面上的相组成、微观结构及元素分布。由陶瓷涂层截面的背散射图看出陶瓷涂层较致密、与基体结合强度高。XRD分析结果显示，陶瓷涂层的最外层由莫来石及γ-Al2O3相组成，随着向陶瓷涂层内部的移动，莫来石的含量逐渐减少，α-Al2O3，γ-A12O3相的含量逐渐提高，而且陶瓷涂层的颜色由白色逐渐变为黑色。硅元素在陶瓷涂层的外侧及陶瓷涂层与基体的交界处陶瓷涂层一侧含量较多，在陶瓷涂层中间含量少。而陶瓷涂层的硬度变化也出现了中间高，两侧低的分布情况。     

Preparation and electrochemical properties of LiMn1.95M0.05O4 （M=Cr, Ni）

The preparation process and electrochemical properties of LiMn2O4 and LiMnl.95M0.05O4 （M = Cr, Ni） were studied. The results show that the decomposition temperature range of xerogel prepared with lithium acetate and manganese acetate as raw rnaterials is large and the decomposition speed is slow. Oxygen consumed is apt to get a prompt supplement during the preparation of LiMn2O4, and carbonization of the organic matter can be reduced or avoided, which is favorable to the combination of lithium and manganese. Using lithium acetate, manganese acetate, chromium nitrate, and nickel nitrate as raw materials and adopting the citric acid complexing method, it has been found that the prepared powders have high purity, high quality stability, and even doping characters. With the increase of sintering temperature, the particle size and crystal lattice constant of LiMn1.95M0.05O4 （M = Cr, Ni） enhance. However, the purity of the product is relatively high and has no obvious change, which is advantageous to the control of the quality of LiMn1.95M0.0504 （M = Cr, Ni）. Doping with a small amount of Cr3. and Ni^2＋ can stabilize the spinel structure of LiMn2O4, suppress the Jahn-Teller effect, and improve the cycling properties but reduce the initial capacity.     

挤压后硼酸铝晶须增强铝复合材料表面的腐蚀特征

利用原于力显微镜观察了挤压态Al18B4O33 w／pure Al复合材料早期腐蚀过程中表面形貌的变化特征．研究了沿与挤压方向成不同角度截取的Al18B4O33 w／pure Al复合材料在3．5％NaCl溶液中的腐蚀规律．结果表明：晶须与基体的界面是腐蚀易于发生的地方．点蚀首先在晶须的端部产生，随后沿着晶须与基体的界面扩展．挤压后沿与挤压方向成不同角度截取的Al18B4O33 w／pure Al复合材料表面腐蚀坑的深度存在差别．     

INFLUENCE OF MARTENSITE MORPHOLOGY AND CRYSTAL STRUCTURE ON THE PSEUDOELASTICITY IN A Cu-Al-Zn-Mn-Ni ALLOY

本文研究了Cu-Al-Zn-Mn-Ni合金的伪弹性变形行为,并用金相和X射线衍射法观察分析了变形及时效前后马氏体组织结构的变化。结果表明,合金在母相状态时的伪弹性与其原始马氏体组织结构密切相关;通过改善原始马氏体组织结构的自协作性和适当的时效处理可以显著提高合金的伪弹性。     

磁控溅射PtSi／p-Si纳米薄膜组织结构的研究

采用磁控溅射方法在p-Si(111)衬底上淀积5nmPt膜，分别在350℃-600℃退火。原子力显微镜(AFM)观察和x射线光电子谱(XPS)分析表明，随退火温度的增加，平坦的薄膜表面变得粗糙，其相分布由Pt-Pt2Si-Ptsi变为Pt Pt2Si PtSi-Ptsi。     

PRECIPITATION IN A Cu-BASED SMA

ＰＲＥＣＩＰＩＴＡＴＩＯＮＩＮＡＣｕ－ＢＡＳＥＤＳＭＡＣｈａｎｇ；ＦｅｎｇｌｉａｎＷａｎｇ；ＳｈｉｄｏｎｇＷａｎｇ；ＹｕｒｕｉＺｈａｏ；Ｌｉａｎｃｈｅｎｇ（ＡｎａｌｙｔｉｃａｌａｎｄＴｅｓｔｉｎｇＣｅｎｔｅｒ，ＳｏｕｔｈｅａｓｔＵｎｉｖｅｒｓｉｔｙ，...     

含有热力偏导数的流体热力性质的计算——Lee-Kesler方程的导数压缩性系数及其应用

本文用流体的压缩性系数Z、导数压缩性系数Z_P、Z_T及比热的特定关系式来表述常遇的含有热力偏导数的流体热力性质。为了推荐Z_P、Z_T的通用计算公式及图表,本文导出了Lee-Kesler方程导数压缩性系数Z_P~（（O）or（R））、Z_T（（O）or（R））的分析表达式。在P_r=0.1—10、T_r=0.3—4范围内,算得L-K方程Z_P（（O））、Z_P（（l））、Z_T（（O））、Z_T（（l））数值并列成表格。所提供的Z_P（（O）or（R））、Z_T（（O）or（R））表达式或表格,可用来机算或手算非极性和轻微极性流体的热力性质,诸如流体等熵指数、流体声速、等压及等容比热比、比热差等。 对CO_2、F-22、N_2进行了上述热力性质计算,所得结果和有关文献比较,误差在工程允许范围内。