Design,Facile Synthesis and Characterization of Porphyrin-Zirconium-Ferrite@SiO2 Core-Shell and Catalytic Application in Cyclohexane Oxidation

Silicon - In this study, a new magnetic ZrFe2O4@SiO2-TCPP nanocatalyst with high efficiency was used for the oxidation of cyclohexane to cyclohexanone (Ke) and cyclohexanol (Al). The mesoporous...     

TVD-MRDL: traffic violation detection system using MapReduce-based deep learning for large-scale data

Maintaining a fluid and safe traffic is a major challenge for human societies because of its social and economic impacts. Various technologies have considerably paved the way for the elimination of traffic problems and have been able to effectively detect drivers’ violations. However, the high volume of the real-time data collected from surveillance cameras and traffic sensors along with the data obtained from individuals have made the use of traditional methods ineffective. Therefore, using Hadoop for processing large-scale structured and unstructured data as well as multimedia data can be of great help. In this paper, the TVD-MRDL system based on the MapReduce techniques and deep learning was employed to discover effective solutions. The Distributed Deep Learning System was implemented to analyze traffic big data and to detect driver violations in Hadoop. The results indicated that more accurate monitoring automatically creates the power of deterrence and behavior change in drivers and it prevents drivers from committing unusual behaviors in society. So, if the offending driver is identified quickly after committing the violation and is punished with the appropriate punishment and dealt with decisively and without negligence, we will surely see a decrease in violations at the community level. Also, the efficiency of the TVD-MRDL performance increased by more than 75% as the number of data nodes increased.

     

A Model for Identifying the Behavior of Alzheimer’s Disease Patients in Smart Homes

Wireless Personal Communications - In recent years, Smart Cities and Smart Homes have been studied as an important field of research. The design and construction of smart homes have flourished so...     

Microstructural and microwave dielectric properties of LZT (Li2ZnTi3O8) ceramics sintered in presence of bismuth borate glass for LTCC applications

In the present research, the Li₂ZnTi₃O₈(LZT) ceramics were synthesized throughout solid-state ceramic processing, then mixed with bismuth borate (BiBO) glass prepared based on conventional melt quenching method. Wetting behavior of BiBO glass on the LZT ceramic substrate was monitored by hot stage microscopy. Afterward, dielectric LZT ceramics containing different amounts of BiBO glass (0.25–6 wt%) were sintered at various temperatures. X-ray diffraction and electron back scatter diffraction examinations revealed the presence of two crystalline phases of Li₂ZnTi₃O₈ and Bi₂Ti₂O₇. The maximum value of relative density (above 95%) was obtained in the case of specimens contained more than 5 wt% glass. The microwave dielectric properties of the finally sintered BiBO glass containing LZT ceramics were as follows: dielectric constant (ε_r) = 21.44–25.09, quality factor (Q × f) = 10839–54708 GHz and temperature coefficient of resonant frequency (τ_f) = (? 15.58) ? (? 12.86)ppm/°C.     

Preparation, Characterization and Photocatalytic Properties of Ba-Cd-Sr-Ti Doped Fe3O4 Nanohollow Spheres on Removal of Congo Red Under Visible-Light Irradiation

In this study, Ba-Cd-Sr-Ti doped Fe₃O₄ nanohollow spheres were successfully prepared via a simple solvothermal method. The crystal size, structure, morphology and elemental analysis of the as-prepared sample were investigated in detail by X-ray diffraction (XRD), FT-IR, scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) spectroscopy, respectively. Magnetic hysteresis measurement was carried out on a vibrant sample magnetometer (VSM) showing the soft ferromagnetic property at room temperature. The synthesized nanohollow spheres were employed as a photocatalyst to study the photocatalytic degradation of dye contaminations. The UV-Vis results showed that the specimen could well catalyze the decolorizing of congo red (CR) solution and a removal efficiency of 99.5 % was obtained at pH 6. The optical characteristic of the products was studied by estimating the band-gap energy based on diffuse-reflectance spectroscopy (DRS) which represented the doped magnetite with semiconductor metals to be more prone in the visible region as compared to UV region. Some factors such as initial dye concentration, pH, and contact time influencing the decomposition of CR were evaluated.     

Novel NGR anchored pullulan micelles for controlled and targeted delivery of doxorubicin to HeLa cancerous cells

Doxorubicin (DOX) is used to treat different kinds of cancers, including cervix carcinoma. However, it has various side effects such as cardiotoxicity. Nano-sized controlled releasing carriers such as polymeric micelles are of interesting approaches to overcome these side effects of doxorubicin in cancer chemotherapy. Regarding the up-regulation of CD13/APN receptors on the cervix carcinoma cells, which can bind to peptide sequences specially NGR (asparagine–glycine–arginine) with high affinity, peptide sequence (NGR) targeted micelles would lead to effective treatment of this carcinoma. In this study, the NGR peptide sequence was synthesized using the solution-phase strategy from asparagine, glycine, and arginine residues. The pullulan–retinoic acid conjugate and pullulan–retinoic acid–NGR conjugate were prepared by the amide and ester bond formation between the hydroxyl groups of pullulan and carboxylic acid groups of retinoic acid and peptide sequence. Pullulan–retinoic acid–NGR micelles were prepared by the direct dissolution method. The optimized micelles, according to their particle size (124.5 nm), zeta potential (? 3.65 mV), entrapment efficiency (85%), and release of DOX (70%, within 72 h) were assessed for their cytotoxicity on HeLa cells using MTT assay. NGR-targeted pullulan/retinoic acid micelles had higher cytotoxicity than the free DOX in cell culture studies on the HeLa cell line, and this can be a promising result in the treatment of cervix carcinoma.     

Thermosensitive folic acid-targeted poly (ethylene-<Emphasis Type="Italic">co</Emphasis>-vinyl alcohol) hemisuccinate polymeric nanoparticles for delivery of epirubicin to breast cancer cells

A novel thermosensitive folic acid (FA)-targeted succinylated poly (ethylene-co-vinyl alcohol) (EVOH) (EVOHS-FA) nanocarrier was synthesized for the specific delivery of epirubicin (EPI) to MCF-7 breast cancer cell line. Three different ratios of synthesized EVOH-Suc were reacted with FA. The structure of the desired products (EVOHS₄₀-FA, EVOHS₆₀-FA and EVOHS₈₀-FA) was confirmed by ¹H NMR and FTIR techniques. Nanoparticles were obtained by nano-precipitation procedure using DMSO/H₂O as solvent/anti-solvent. The particle size, zeta potential, entrapment efficacy and in vitro release profile of the final formulations in different temperatures were measured. The optimized nanoparticles had the particle size of 214 ± 8.5 nm, zeta potential of ?29.6 mV, PDI of 0.198 ± 0.04, and a high encapsulation efficiency that released the drug efficiently within 450 h at the temperature of 40 °C compared to 37 °C. The morphology of nanoparticles was studied by scanning electron microscopy. The in vitro cytotoxicity was evaluated using the MTT assay on MCF-7 cell lines in response to temperatures of 37 and 40 °C. The MTT assay indicated that the targeted nanoparticles carrying EPI were significantly more cytotoxic than the non-targeted nanoparticles and the free drug at 40 °C.     

Investigation on the effects of microwave and conventional heating methods on the phytochemicals of pomegranate (Punica granatum L.) and black mulberry juices

Black mulberry and pomegranate juices were concentrated by conventional and microwave heating at different operational pressures (7.3, 12, 38.5, and 100 kPa). The effects of each heating method on the phytochemical changes (total anthocyanin content and antioxidant activity) of juices were investigated. The effect of various heating methods on the profile of the pomegranate anthocyanins were conducted using high-performance liquid chromatography–mass spectrometry (HPLC–MS). The main anthocyanins of pomegranate quantified by HPLC–MS were cyanidin, delphidin, pelargonidin, 3-glucoside, and 3, 5-diglucoside. In black mulberry juice, the final juice concentration of 42° Brix was achieved in 140, 120, and 95 min at 100, 38.5, and 7.3 kPa respectively and the final pomegranate juice concentration of 40° Brix was achieved in 140, 127, and 109 min at 100, 38.5, and 12 kPa respectively by using a rotary evaporator. Applying microwave energy decreased the required times to 115, 95, and 60 min for black mulberry juice and to 118, 95, and 75 min for pomegranate juice. Results showed that anthocyanin degradation and consequently decrease in antioxidant activity were more pronounced in rotary evaporation compared to microwave heating method.     

An efficient improvement remote user mutual authentication and session key agreement scheme for E-health care systems

The E-health care systems allow patients to gain the health monitoring facility and access medical services remotely. A secure mechanism for mutual authentication and session key agreement is the most important requirements for E-Health Care Systems. Recently, Amin et al.’s proposed a mutual authentication and session key agreement protocol and claimed that their scheme is secure against all possible attacks. In this paper, we show that not only their scheme is vulnerable to privileged-insider attack, replay attack, session key disclosure attack, but also does not provide patient untraceability and backward secrecy. In order to withstand the mentioned security weaknesses, we propose an efficient remote mutual authentication scheme for the systems which are using ECC and Fuzzy Extractor. The proposed scheme not only resists against different security attacks, but it also provides an efficient registration, login, mutual authentication, session key agreement, and password and biometric update phases. During the experimentation, it has been observed that the proposed scheme is secure against various known attacks. Beside, our scheme is robust against privileged-insider attack that it rarely checked in security analysis. The informal analysis will ensure that our scheme provides well security protection against the different security attacks. Furthermore, we analyzed the security of the scheme using AVISPA software and Random Oracle Model. The formal analysis results and performance evaluation vouch that our scheme is also secure and efficient in computation and communication cost.