Cellulose as a binding material in graphitic anodes for Li ion batteries: a performance and degradation study

Four types of cellulose, in particular carboxy methyl cellulose (CMC), are tested as potential binding materials in graphitic anodes for lithium ion batteries. It is shown that a minimum content of a cellulose which gives acceptable anode properties (reversible capacity>300 mA h g⁻¹ during the first 10 cycles, irreversible loss<20%) is about 2 wt.%, which is less than in the case of conventional polymeric binders (5-10 wt.%). Kinetics of insertion-deinsertion and passivation processes seem not to be affected by the presence of cellulose. Explanation for the electrode failure at cellulose contents lower than 1 wt.% is given based on X-ray diffraction and microscopy investigations. Finally, the structure (distribution) of cellulose in the composite anode material is discussed and (indirectly) checked with a series of experiments. Most results are compared with the corresponding results obtained either with gelatin or conventional polymeric binders or both.     

Quantitative measures for self-organizing topographic maps

Self-organizing topographic maps have found many applications as systems capable of unsupervised learning. They are based on the competitive learning algorithm applied to low-dimensional (in practice one, two or three-dimensional) structure of artificial neurons. The iterative algorithm used for competitive learning converges slowly and is computationally very intensive. In this paper, direct mapping on the continuous space based on the minimization principle is used to map the high-dimensional input data to the low-dimensional target space. The problem of finding the best low-dimensional representation of the data is reduced to a minimization problem or to the solution of a system of nonlinear algebraic equations.     

Formation of oxidising species and their role in the viscosity loss of cereal beta-glucan extracts

The aim of this study was to determine the role of the formation of radicals and hydrogen peroxide in the viscosity loss of beta-glucan extracts from oat and barley. Radicals derived from endogenous H₂O₂ were formed spontaneously in all extracts. The decomposition of H₂O₂ by catalase had little or no effect on the viscosity, and the radical formation detected and measured by electron spin resonance (ESR) spectroscopy did not predict the shelf life of crude beta-glucan extracts. The addition of FeSO₄ accelerated the radical formation and viscosity loss, revealing the sensitivity of the extract viscosity towards catalysts for oxidation. Using 50% cadoxen in the extracts slowed down the viscosity loss in all extracts but still led to a 10–70% decrease of the initial viscosities during 4 weeks of storage. The results suggest that the viscosity loss may be a result from multiple mechanisms including chemical reactions during storage as well as aggregation and conformational changes.     

Ship roll damping control

The technical feasibility of roll motion control devices has been amply demonstrated for over 100 years. Performance, however, can still fall short of expectations because of difficulties associated with control system designs, which have proven to be far from trivial due to fundamental performance limitations and large variations of the spectral characteristics of wave-induced roll motion. This tutorial paper presents an account of the development of various ship roll motion control systems together with the challenges associated with their design. It discusses the assessment of performance and the applicability of different mathematical models, and it surveys the control methods that have been implemented and validated with full scale experiments. The paper also presents an outlook on what are believed to be potential areas of research within this topic.     

Molecular Heterojunctions of Oligo(phenylene ethynylene)s with Linear to Cruciform Framework

Electrical transport properties of molecular junctions are fundamentally affected by the energy alignment between molecular frontier orbitals (highest occupied molecular orbital (HOMO) or lowest unoccupied molecular orbital (LUMO)) and Fermi level (or work function) of electrode metals. Dithiafulvene (DTF) is used as substituent group to the oligo(phenylene ethynylene) (OPE) molecular wires and different molecular structures based on OPE3 backbone (with linear to cruciform framework) are achieved, with viable molecular orbitals and HOMO–LUMO energy gaps. OPE3, OPE3–DTF, and OPE3–tetrathiafulvalene (TTF) can form good self‐assembled monolayers (SAMs) on Au substrates. Molecular heterojunctions based on these SAMs are investigated using conducting probe–atomic force microscopy with different tips (Ag, Au, and Pt) and Fermi levels. The calibrated conductance values follow the sequence OPE3–TTF > OPE3–DTF > OPE3 irrespective of the tip metal. Rectification properties (or diode behavior) are observed in case of the Ag tip for which the work function is furthest from the HOMO levels of the OPE3s. Quantum chemical calculations of the transmission qualitatively agree with the experimental data and reproduce the substituent effect of DTF. Zero‐bias conductance, and symmetric or asymmetric couplings to the electrodes are investigated. The results indicate that improved fidelity of molecular transport measurements may be achieved by systematic studies of homologues series of molecular wires applying several different metal electrodes.     

厌氧氨氧化技术用于高氨废水脱氮

在简要介绍厌氧氨氧化菌生理生化特性的基础上,总结了目前应用厌氧氨氧化的主要工艺及其工程实例,重点分析了厌氧氨氧化技术在处理高氨废水实际工程应用过程中需要解决的关键技术,为厌氧氨氧化技术在污水处理工程中的推广提供技术借鉴.     

Ligand‐Free Synthesis of Aluminum‐Doped Zinc Oxide Nanocrystals and their Use as Optical Spacers in Color‐Tuned Highly Efficient Organic Solar Cells

The color of polymer solar cells using an opaque electrode is given by the reflected light, which depends on the composition and thickness of each layer of the device. Metal‐oxide‐based optical spacers are intensively studied in polymer solar cells aiming to optimize the light absorption. However, the low conductivity of materials such as ZnO and TiO₂ limits the thickness of such optical spacers to tenths of nanometers. A novel synthesis route of cluster‐free Al‐doped ZnO (AZO) nanocrystals (NCs) is presented for solution processing of highly conductive layers without the need of temperature annealing, including thick optical spacers on top of polymer blends. The processing of 80 nm thick optical spacers based on AZO nanocrystal solutions on top of 200 nm thick polymer blend layer is demonstrated leading to improved photocurrent density of 17% compared to solar cells using standard active layers of 90 nm in combination with thin ZnO‐based optical spacers. These AZO NCs also open new opportunities for the processing of high‐efficiency color tuned solar cells. For the first time, it is shown that applying solution‐processed thick optical spacer with polymer blends of different thicknesses can process solar cells of similar efficiency over 7% but of different colors.     

On the Expressive Power of Temporal Concurrent Constraint Programming Languages: (invited talk)

The tcc paradigm is a formalism for timed concurrent constraint programming. Several tcc languages differing in their way of expressing infinite behavior have been proposed in the literature. In this work we study the expressive power of some of these languages. In particular, we show that: (1) recursive procedures with parameters can be encoded into parameterless recursive procedures with dynamic scoping, and viceversa. (2) replication can be encoded into parameterless recursive procedures with static scoping, and viceversa. (3) the languages from (1) are strictly more expressive than the languages from (2). Furthermore, we show that behavioral equivalence is undecidable for the languages from (1), but decidable for the languages from (2). The undecidability result holds even if the process variables take values from a fixed finite domain.(Joint work with Mogens Nielsen and Frank D. Valencia)     

Do glycerolipids display lateral heterogeneity in the thylakoid membrane?

The lateral heterogeneity of lipids in the thylakoid membrane has been questioned for over 20 yrs. It is generally believed that glycerolipids are asymmetrically distributed within the plane of the membrane. In the present investigation, we isolated several thylakoid membrane domains by using sonication followed by separation in an aqueous dextran-polyethylene glycol two-phase system. This technique, which avoids detergent treatments, allowed us to obtain stroma and grana lamellae vesicles as well as grana central core and grana margin vesicles from thylakoids. The relative distribution of the four lipid classes, i.e., monogalactosyldiacylglycerol, digalactosyldiacylglycerol, sulfoquinovosyldiacylglycerol, and phosphatidylglycerol, was found to be statistically identical in all four thylakoid fractions and in whole thylakoids. Similarly, the relative amount of fatty acids in each individual lipid and the eight main phosphatidylglycerol molecular species was identical in all thylakoid membrane fractions tested as well as in the intact thylakoid membrane. Based on presently available procedures for obtaining thylakoid subfractions that are unable to discriminate microdomains within the membrane, it is concluded that glycerolipids are evenly distributed within the plane of the thylakoid membrane. These data are discussed in terms of “bulk” and “specific” lipids.     

Petri nets,event structures and domains,part I

The general aim of this paper is to find a theory of concurrency combining the approaches of Petri and Scott (and others).In part I we introduce our formalisms. To connect the abstract ideas of events and domains of information, we show how casual nets induce certain kinds of domains where the information points are certain sets of events. This allows translations between the languages of net theory and domain theory. Following the idea that events of causal nets are occurrences, we generalise causal nets to occurrence nets, by adding forwards conflict. Just as infinite flow charts unfold finite ones, so transition nets can be unfolded into occurrence nets. Next we extend the above connections between nets and domains to these new nets. Event structures which are intermediate between nets and domains play an important part in all our work. Finally, as an example of how concepts translate from one formalism to the other, we show how Petri's notion of confusion ties up with Kahn and Plotkin's concrete domains.In part II we shall continue the job of connecting up notions within net theory and the theory of domains. In particular, we shall examine the idea of states of computations.