The coating of cadmium compounds with copper compounds

Fine particles of cadmium carbonate (CdCO₃) were prepared by heating aqueous solutions containing dissolved urea and cadmium sulfate at 85°C for 1 h. Effect of the composition of the reactant mixture on the morphology of the precipitated particles was investigated. It was found that the cadmium sulfate content of the reactant mixture significantly affected the shape and size of the precipitated particles. At certain range of reactant mixture composition, cauliflower-shaped uniform particles were obtained. The later particles were coated with basic copper carbonate (Cu₂(OH)₂CO₃) by heating aqueous dispersions, containing CdCO₃ particles, copper (II) nitrate, and urea at 85°C for various periods of time with constant stirring. The coating process was found sensitive to the experimental conditions and in most of the trials; mixtures of the coated and coating precursor particles were obtained. As such, extensive optimizations were carried out and conditions were established for the production of uniformly coated particles.On calcination at 700°C for 1 h, the CdCO₃ particles converted into CdO, whereas the coated particles (CdCO_{3 (core)}/Cu₂(OH)₂CO_{3 (coating)} transformed into CdO_(core)/CuO_(coating)) without sintering. In the coated particles, the core and coating materials stayed mutually inert during the calcination reaction and independently converted into their respective oxides.All the calcined and uncalcined products were characterized by various physical and chemical methods.     

Edible vaccine protects mice against Escherichia coli heat-labile enterotoxin (LT): potatoes expressing a synthetic LT-B gene

The authors have designed and constructed a plant-optimize synthetic gene encoding the Escherichia coli heat-labile enterotoxin B subunit (LT-B), for use in transgenic plants as an edible vaccine against enterotoxigenic E. coli. Expression of the synthetic LT-B gene in potato plants under the control of a constitutive promoter yielded increased accumulation of LT-B in leaves and tubers, as compared to the bacterial LT-B gene. The plant-derived LT-B assembled into native pentameric structures as evidenced by its ability to bind ganglioside. The authors demonstrated immunogenicity by feeding mice the raw tubers and comparing the anti-LT-B serum IgG and faecal IgA to that produced in mice gavaged with bacterial LT-B. Mice were fed three weekly doses of 5 g tuber tissue containing either 20 or 50 micrograms LT-B, or gavaged weekly with 5 micrograms of LT-B from recombinant E. coli. One week after the third dose, mice immunized with potato LT-B had higher levels of serum and mucosal anti-LT-B than those gavaged with bacterial LT-B. Mice were challenged by oral administration of 25 micrograms LT, and protection assessed by comparing the gut/carcass mass ratios. Although none of the mice were completely protected, the higher dose potato vaccine compared favourably with the bacterial vaccine. These findings show that an edible vaccine against E. coli LT-B is feasible.     

Synthesis and thermomechanical characterization of polyurethane elastomers extended with α,ω‐alkane diols

A series of polyurethane (PU) elastomers was prepared by the reaction of poly(?‐caprolactone) and 4,4′‐diphenylmethane diisocyanate, which was extended with a series of chain extenders (CEs) having 2–10 methylene units in their structure. The completion of the reaction was confirmed by Fourier transform infrared spectroscopy. The chemical structures of the synthesized PU samples were characterized with Fourier transform infrared, ¹H‐NMR, and ¹³C‐NMR spectroscopy, and the thermal properties were determined by thermogravimetric analysis, DSC, and dynamic mechanical thermal analysis techniques. The mechanical properties were also studied and are discussed. The thermogravimetric analysis and DSC analysis showed that CE length had a considerable effect on the thermal properties of the prepared samples. The dynamic mechanical thermal analysis and damping peaks were also affected by the number of methylene units in the CE length. The elastomer extended with 1,2‐ethane diol exhibited optimum thermal properties, whereas the elastomer based on 1,10‐decane diol displayed the worst thermal properties. Tensile strength and elongation at break decreased with increasing CE length, whereas hardness showed the opposite trend. The glass‐transition temperature moved toward lower temperatures with increasing CE length. The decrease in the glass‐transition temperature and tensile properties were interpreted in terms of decreasing hard segments and increasing chain flexibility. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

An efficient numerical algorithm for the study of time fractional Tricomi and Keldysh type equations

Engineering with Computers - This work addresses a hybrid scheme for the numerical solutions of time fractional Tricomi and Keldysh type equations. In proposed methodology, Haar wavelets are used...     

A hybridisation of metaheuristics for flow shop scheduling

The present paper deals with the formation of an optimal sequence of flow shop scheduling (FSS) for efficient operation. The primary concern of FSS is to obtain the optimal sequence, which minimises the idle time, tardiness, makespan, etc. Among these, the criteria of minimising the makespan plays a vital part. Thus, in this paper, the sequencing of the FSS for minimising the makespan is addressed. An effective hybrid has been formed with the metaheuristics, namely an ant system and a genetic algorithm (GA). A number of illustrative examples with different combinations of machines and jobs have been solved using the proposed hybrid method.     

A New Maximum EWMA Control Chart for Simultaneously Monitoring Process Mean and Dispersion Using Auxiliary Information

The maximum exponentially weighted moving average (MaxEWMA) control charts have gained considerable attention for simultaneously detecting both increases and decreases in the mean and/or dispersion of a process. In this paper, we propose a new auxiliary information‐based (AIB) MaxEWMA control chart, called the AIB‐MaxEWMA chart. The AIB‐MaxEWMA chart encompasses the existing MaxEWMA chart. Extensive Monte Carlo simulations are performed to evaluate the average run length, standard deviation of the run length, and diagnostic abilities of the AIB‐MaxEWMA chart. An extensive comparison reveals that the AIB‐MaxEWMA chart performs uniformly better than the MaxEWMA chart. An example is also used to explain the implementation and working of the AIB‐MaxEWMA chart. Copyright © 2017 John Wiley & Sons, Ltd.     

An efficient numerical algorithm for multi-dimensional time dependent partial differential equations

An efficient and robust numerical scheme based on Haar wavelets and finite differences is suggested for the solution of two-dimensional time dependent linear and nonlinear partial differential equations (PDEs). Excellent feature of the scheme is the conversion of linear and non-linear PDEs to algebraic equations which are comparatively easy to handle. Convergence of the scheme, which guarantees small error norm as the resolution level increases, is also an important part of this work. Different error norms are computed to check efficiency of the technique. Computations verify accuracy, flexibility and low computational cost of the method.     

New Synthetic Control Charts for Monitoring Process Mean and Process Dispersion

A statistical quality control chart is widely recognized as a potentially powerful tool that is frequently used in many manufacturing and service industries to monitor the quality of the product or manufacturing processes. In this paper, we propose new synthetic control charts for monitoring the process mean and the process dispersion. The proposed synthetic charts are based on ranked set sampling (RSS), median RSS (MRSS), and ordered RSS (ORSS) schemes, named synthetic‐RSS, synthetic‐MRSS, and synthetic‐ORSS charts, respectively. Average run lengths are used to evaluate the performances of the control charts. It is found that the synthetic‐RSS and synthetic‐MRSS mean charts perform uniformly better than the Shewhart mean chart based on simple random sampling (Shewhart‐SRS), synthetic‐SRS, double sampling‐SRS, Shewhart‐RSS, and Shewhart‐MRSS mean charts. The proposed synthetic charts generally outperform the exponentially weighted moving average (EWMA) chart based on SRS in the detection of large mean shifts. We also compare the performance of the synthetic‐ORSS dispersion chart with the existing powerful dispersion charts. It turns out that the synthetic‐ORSS chart also performs uniformly better than the Shewhart‐R, Shewhart‐S, synthetic‐R, synthetic‐S, synthetic‐D, cumulative sum (CUSUM) ln S², CUSUM‐R, CUSUM‐S, EWMA‐ln S², and change point CUSUM charts for detecting increases in the process dispersion. A similar trend is observed when the proposed synthetic charts are constructed under imperfect RSS schemes. Illustrative examples are used to demonstrate the implementation of the proposed synthetic charts. Copyright © 2014 John Wiley & Sons, Ltd.     

An Improved Maximum Exponentially Weighted Moving Average Control Chart for Monitoring Process Mean and Variability

Maximum exponentially weighted moving average (MaxEWMA) control charts have gained considerable attention for detecting changes in both process mean and process variability. In this paper, we propose an improved MaxEWMA control charts based on ordered ranked set sampling (ORSS) and ordered imperfect ranked set sampling (OIRSS) schemes for simultaneous detection of both increases and decreases in the process mean and/or variability, named MaxEWMA‐ORSS and MaxEWMA‐OIRSS control charts. These MaxEWMA control charts are based on the best linear unbiased estimators of location and scale parameters obtained under ORSS and OIRSS methods. Extensive Monte Carlo simulations have been used to estimate the average run length and standard deviation of run length of the proposed MaxEWMA control charts. These control charts are compared with their counterparts based on simple random sampling (SRS), that is, MaxEWMA‐SRS and MaxGWMA‐SRS control charts. The proposed MaxEWMA‐ORSS and MaxEWMA‐OIRSS control charts are able to perform better than the MaxEWMA‐SRS and MaxGWMA‐SRS control charts for detecting shifts in the process mean and dispersion. An application to real data is provided to illustrate the implementation of the proposed MaxEWMA control charts. Copyright © 2013 John Wiley & Sons, Ltd.     

Synthesis and characteristics of fly ash and bottom ash based geopolymers–A comparative study

The research was carried out to develop geopolymers mortars and concrete from fly ash and bottom ash and compare the characteristics deriving from either of these products. The mortars were produced by mixing the ashes with sodium silicate and sodium hydroxide as activator solution. After curing and drying, the bulk density, apparent density and porosity, of geopolymer samples were evaluated. The microstructure, phase composition and thermal behavior of geopolymer samples were characterized by scanning electron microscopy, XRD and TGA-DTA analysis respectively. FTIR analysis revealed higher degree of reaction in bottom ash based geopolymer. Mechanical characterization shows, geopolymer processed from fly ash having a compressive strength 61.4 MPa and Young's modulus of 2.9 GPa, whereas bottom ash geopolymer shows a compressive strength up to 55.2 MPa and Young's modulus of 2.8 GPa. The mechanical characterization depicts that bottom ash geopolymers are almost equally viable as fly ash geopolymer. Thermal conductivity analysis reveals that fly ash geopolymer shows lower thermal conductivity of 0.58 W/mK compared to bottom ash geopolymer 0.85 W/mK.