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Filled fibrous sorbents modified with transition metal ferro- and ferricyanides capable to recover americium(III) and rare-earth metals(III) from nitric acid solutions were prepared. The most complete and rapid recovery is attained on complex-forming and cation-exchange sorbents (as filled fibrous materials) saturated with nickel ions. The sorbents are characterized by good kinetic properties and can be used for recovery of the above metals. 相似文献
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E. A. Zakharchenko D. A. Malikov G. V. Myasoedova O. B. Mokhodoeva N. P. Molochnikova Yu. M. Kulyako 《Radiochemistry》2012,54(2):159-163
The sorption properties of solid-phase extractants (SPEs) prepared by impregnation of Taunit carbon nanotubes with adducts
of diphenyl(dibutylcarbamoylmethyl)phosphine oxide (CMPO) and tri-n-octylphosphine oxide (TOPO) in HNO3 solutions were studied. The SPEs exhibit high ability to sorb U(VI), Pu(IV), Np(V), Am(III), and Eu(III) from nitric acid
solutions, with good kinetic properties. The impregnation conditions and distribution coefficients of the radionuclides in
their recovery from 3 M HNO3 were determined. The possibility of preparing SPEs by Taunit impregnation in HNO3 solutions with adducts of tributyl phosphate (TBP) and N,N′-dimethyl-N,N′-dioctylhexylethoxymalonamide (DMDOHEMA) and with Cyphos IL-101 phosphonium ionic liquid was demonstrated. 相似文献
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The possibility of using POLIORGS 33-n and 34-n fibrous “filled” sorbents with amidoxime groups for recovering U(VI), Am(III),
and Pu(IV) from alkaline solutions of various compositions was studied. These sorbents exhibit high performance and excellent
kinetic properties in recovery of uranium and transuranium elements from alkaline solutions. The distribution coefficients
in their sorption from alkaline solutions at various (even high) values of pH and salt content were determined.
Original Russian Text N.P. Molochnikova, I.G. Tananaev, G.V. Myasoedova, B.F. Myasoedov, 2007, published in Radiokhimiya,
2007, Vol. 49, No. 1, pp. 58–60. 相似文献
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V. P. Morgalyuk N. P. Molochnikova G. V. Myasoedova I. G. Tananaev 《Radiochemistry》2006,48(6):580-583
The extraction of U(VI), Am(III), and Pu(VI) from nitric acid solutions in the form of complexes with alkylenebis(diphenylphosphine) dioxides and their sorption with POLIORGS F-6 sorbent prepared by noncovalent immobilization of methylenebis(diphenylphosphine) dioxide (MDPPD) on a KhAD-7M? polymeric matrix were studied. The preconcentration conditions and distribution coefficients of U(VI), Am(III), and Pu(IV) in their sorption from 3 M HNO3 were determined. The possibility of concentrating actinides from multicomponent solutions was demonstrated. The composition and nature of complexes of U(VI) with MDPPD were determined from the 31P NMR data. 相似文献
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G. V. Myasoedova N. P. Molochnikova A. G. Tkachev E. N. Tugolukov S. V. Mishchenko B. F. Myasoedov 《Radiochemistry》2009,51(2):156-158
The possibility of using Taunit carbon nanostructural material for sorption recovery of radionuclides from aqueous solutions was examined. Taunit efficiently recovers Am, Pu, Eu, U, and Tc from weakly acidic and neutral solutions. Taunit is a suitable support for preparing solid extractants based on a phosphonium ionic liquid and diphenyl(dibutylcarbamoylmethyl)phosphine oxide for recovery of actinides from nitric acid solutions. 相似文献
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S. A. Perevalov N. P. Molochnikova G. V. Myasoedova B. F. Myasoedov 《Radiochemistry》2007,49(4):415-418
Sorption of Np(VII), Np(VI), and Np(V) from 1 M NaOH by complexing fibrous “filled” sorbents was examined. POLIORGS 33-n and 34-n sorbents containing amidoxime and hydrazidine groups efficiently recover Np in the highest oxidation states and exhibit good kinetic properties. During sorption, Np(VII) is reduced with the sorbent to Np(VI) having a higher, under the actual conditions, distribution coefficient. The distribution coefficients, ml g?1, were estimated at 4.6 × 103 for Np(VII), 1.4 × 104 for Np(VI), and 3.6 × 102 for Np(V). 相似文献
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Sorption preconcentration of U(VI) on POLIORGS 34-n fibrous filled sorbent with amidoxime groups from model solutions like natural water was studied under static and dynamic conditions. The equilibrium (distribution coefficient) and kinetic (diffusion coefficient) parameters of the sorption were determined. Parameters of dynamic preconcentration of uranium by sorption on disks and in a column packed with POLIORGS 34-n under indicated conditions were calculated by mathematical modeling using the experimental data. 相似文献