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1.
Marta Valkov Pavel Letinský Lenka Matjov Kateina Klemencov Michal Ritz Christian Schimpf Mykhailo Motylenko David Rafaja Jakub Blík 《International journal of molecular sciences》2022,23(15)
Hematite (α-Fe2O3) catalysts prepared using the precipitation methods was found to be highly effective, and therefore, it was studied with methane (CH4), showing an excellent stable performance below 500 °C. This study investigates hematite nanoparticles (NPs) obtained by precipitation in water from the precursor of ferric chloride hexahydrate using precipitating agents NaOH or NH4OH at maintained pH 11 and calcined up to 500 °C for the catalytic oxidation of low concentrations of CH4 (5% by volume in air) at 500 °C to compare their structural state in a CH4 reducing environment. The conversion (%) of CH4 values decreasing with time was discussed according to the course of different transformation of goethite and hydrohematites NPs precursors to magnetite and the structural state of the calcined hydrohematites. The phase composition, the size and morphology of nanocrystallites, thermal transformation of precipitates and the specific surface area of the NPs were characterized in detail by X-ray powder diffraction, transmission electron microscopy, infrared spectroscopy, thermal TG/DTA analysis and nitrogen physisorption measurements. The results support the finding that after goethite dehydration, transformation to hydrohematite due to structurally incorporated water and vacancies is different from hydrohematite α-Fe2O3. The surface area SBET of Fe2O3_NH-70 precipitate composed of protohematite was larger by about 53 m2/g in comparison with Fe2O3_Na-70 precipitate composed of goethite. The oxidation of methane was positively influenced by the hydrohematites of the smaller particle size and the largest lattice volume containing structurally incorporated water and vacancies. 相似文献
2.
A. L. Rudenko V. V. Mishakin A. V. Gonchar K. V. Kurashkin A. E. Fomin 《Power Technology and Engineering (formerly Hydrotechnical Construction)》2020,53(6):687-689
At the hydroelectric unit No. 11 of the Nizhnekamsk hydroelectric power plant, the filling wedges of a rotor were investigated by ultrasound in the free st 相似文献
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The effect of a magnetic field and surfactants on the rheological properties of strontium ferrite suspensions has been studied. An applied magnetic field is shown to raise the suspension viscosity, which is attributable to the formation of three-dimensional chain structures made up of ferrite particles. After the magnetic field is removed, these structures do not fully break down, which leads to hysteretic behavior of the suspension viscosity. The introduction of polyelectrolytes reduces the viscosity of the suspension both in a magnetic field and after the field is removed. This is due to the formation of an electrical double layer on the particle surface, which reduces interparticle friction and the strength of the three-dimensional structures. The results of this study may be useful in devising processes for enhancing the texture and density of highly anisotropic strontium ferrite materials produced by wet pressing. 相似文献
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A. V. Volodarskii A. A. Mikhelev M. I. Davidzon M. Ya. Antimirov A. A. Panferova A. D. Dvoiris A. G. Sirotin A. Sh. Leizerovich E. R. Plotkin Yu. L. Izrailev A. A. Armand V. V. Krasheninnikov Yu. V. Mironov V. K. Safonov A. Z. Volynets L. K. Tsabek I. V. Rozen A. G. Zhdanov V. E. Lyusternik B. V. Zheleznyi B. S. Gonchar A. M. Aizen M. K. Kleiner V. F. Stepanchuk M. L. Guris V. M. Popov N. M. Nedosekina V. A. Palagin V. F. Dunskii N. V. Nikitin Yu. T. Borshchevskii I. M. Fedotkin M. N. Chepurnoi V. É. Shnaider 《Journal of Engineering Physics and Thermophysics》1972,22(5):652-662
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Gonchar J 《Architectural record》2007,(10):159-62, 164, 166
8.
Alcohol oxidase- and formaldehyde dehydrogenase-based enzymatic methods for formaldehyde assay in fish food products 总被引:2,自引:0,他引:2
For Gadoid fishes, formaldehyde can be generated in tissues in huge amounts during endogenous enzymatic degradation of natural osmoprotectant trimethylamine-N-oxide. This paper describes two enzymatic methods for assay of formaldehyde in fish food products using alcohol oxidase (AOX) and formaldehyde dehydrogenase (FdDH) isolated from the thermotolerant methylotrophic yeast Hansenula polymorpha. AOX-based method exploits an ability of the enzyme to oxidise a hydrated form of formaldehyde to formic acid and hydrogen peroxide monitored in peroxidase-catalysed colorimetric reaction. In FdDH-based method, a monitored coloured formazane is formed from nitrotetrazolium salt during reduction by NADH, produced in formaldehyde-dependent reaction. It was demonstrated an applicability of both methods for assay of formaldehyde in fish products. The optimal protocols for analysis procedures have been elaborated and analytical parameters of both enzymatic methods have been established. The both methods were demonstrated that some fish products (hake and cod) contain high formaldehyde concentrations (up to 100 mg/kg wet weight). 相似文献
9.
Hryhorii P. Parkhomenko Mykhailo M. Solovan Sanjay Sahare Andriy I. Mostovyi Damir Aidarkhanov Nora Schopp Taras Kovaliuk Marat Kaikanov Annie Ng Viktor V. Brus 《Advanced functional materials》2024,34(10):2310404
This work investigates the radiation resistance of high-performance multi-component perovskite solar cells (PSCs) for the first time under extreme short-pulse proton irradiation conditions. The devices are subjected to high-intensity 170 keV pulsed (150 ns) proton irradiation, with a fluence of up to 1013 p cm−2, corresponding to ≈30 years of operation at low Earth orbit. A complex material characterization of the perovskite active layer and device physics analysis of the PSCs before and after short-pulse proton irradiation is conducted. The obtained results indicate that the photovoltaic performance of the solar cells experiences a slight deterioration up to 20 % and 50 % following the low 2 × 1012 p cm−2 and high 1 × 1013 p cm−2 proton fluences, respectively, due to increased non-radiative recombination losses. The findings reveal that multi-component PSCs are immune even to extreme high-intense short-pulse proton irradiation, which exceeds harsh space conditions, including intense coronal ejection events usually associated with solar flares. 相似文献
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