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1.
Tatsuro Kijima Kouji Ohshima Hideo Kise 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1994,59(1):61-65
Racemic amino acid esters were optically resolved via hydrolysis in organic solvents by the catalysis of an industrial alkaline protease, “Alcalase”. The products which were composed mainly of L-amino acids were insoluble and easily separated by filtration. The activity of the enzyme and enantiomeric excess of the products were significantly dependent on the nature of solvent and the water content in the reaction media. Generally, high values of enantiomeric excess were obtained at low water contents. Many natural and unnatural amino acids were resolved by this method. 相似文献
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3.
Present-day power systems operate with high reliability, and it is rare that a blackout will extend over an entire system swiftly and securely. This paper considers automatic power supply to loads after a complete blackout of a system. First, taking into account characteristics of generators, loads, and initial power sources, a method is proposed of allocating several generators to each load in parallel to the system and supplying power to the load sequentially. Second, to remove the imbalance between supply and demand of power, a method is proposed of adjusting the amount of supply and generation according to a present imbalance and the sum of past ones. Third, to automatically issue orders for start-up, parallel, follow-up, stand-by, and stoppage of generators, several rules for each power station are set and an expert system is made based on them. Finally, the expert system is applied to a model power system, and it is verified that it can restore loads without any trouble for a complete blackout which occur at any time of a day and in any restoration pattern. 相似文献
4.
The effect of pressure on the melting, solid-solid transition, and crystallization of poly(trans-1,4-butadiene) (PTBD) was investigated using the pressure range of 1–3000 kg/cm2. D.t.a. measurements showed that, the melting and transition temperatures increase with increasing pressure, whose pressure coefficients are 38°C per 1000 kg/cm2 and 22°C per 1000 kg/cm2, respectively. These values were in fairly close agreement with those calculated from the Clausius-Clapeyron equation. Morphological studies using electron microscope and small-angle X-ray scattering method revealed that, the samples crystallized with relatively small supercoolings under normal or high pressure, are formed of distinct lamellae 400–800 Å thick. The lamellar thickness was inappreciably dependent on crystallization pressure. The significant effect of pressure on crystallization was recognized in a tendency of the crystallinity to increase, with increasing crystallization pressure. This pressure effect was explained by the mechanism that, the increased pressure might make the packing of molecular chains in liquid, more dense and that the secondary crystallization might be accelerated, to increase the lateral dimensions of lamellae. 相似文献
5.
Naoto Suzuki 《Electrical Engineering in Japan》2010,171(2):23-30
In Kyushu Electric Power's 6.6‐kV distribution system, after a single‐phase ground fault occurred in the circuit of a distribution line, we experienced a phenomenon in which the analogue ground directional relays of the other circuits linked to the same bank were simultaneously tripped. In this paper, focus is placed on the mechanism and possibility of simultaneous tripping of ground directional relays. This mechanism was examined in an experiment carried out using an analogue simulator. The results of the test revealed that such simultaneous tripping was attributable to the neutral instability phenomenon of grounding potential transformers installed in an isolated neutral system. © 2010 Wiley Periodicals, Inc. Electr Eng Jpn, 171(2): 23–30, 2010; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.20919 相似文献
6.
Tsuyoshi Kijima Yu Nagatomo Hirokatsu Takemoto Masafumi Uota Daisuke Fujikawa Yuzo Sekiya Teppei Kishishita Makoto Shimoda Takumi Yoshimura Hideya Kawasaki Go Sakai 《Advanced functional materials》2009,19(4):545-553
Nanohole‐structured single‐crystalline Pt nanosheets have been synthesized by the borohydride reduction of Na2PtCl6 confined to the lyotropic liquid crystals (LLCs) of polyoxyethylene (20) sorbitan monooleate (Tween 80) with or without nonaethylene‐glycol (C12EO9). The Pt nanosheets of around 4–10 nm in central thickness and up to 500 nm or above in diameter have a number of hexagonal‐shaped nanoholes ∼1.8 nm wide. High‐resolution electron microscope images of the nanosheets showed atomic fringes with a spacing of 0.22 nm indicating that the nanosheets are crystallographically continuous through the nanoholed and non‐holed areas. The inner‐angle distributions for the hexagonal nanoholes indicate that the six sides of the nanoholes are walled with each two Pt (111), Pt (1 1) and Pt (010) planes. The formation mechanism of nanoholed Pt nanosheets is discussed on the basis of structural and compositional data for the resulting solids and their precursory LLCs, with the aid of similar nanohole growth observed for a Tween 80 free but oleic acid‐incorporated system. It is also demonstrated that the nanoholed Pt nanostructures loaded on carbon exhibit fairly high electrocatalytic activity for oxygen reduction reaction and a high performance as a cathode material for polymer‐electrolyte fuel cells, along with their extremely high thermostability revealed through the effect of electron‐irradiation. 相似文献
7.
Benzobisthiazole as Weak Donor for Improved Photovoltaic Performance: Microwave Conductivity Technique Assisted Molecular Engineering 下载免费PDF全文
Masashi Tsuji Akinori Saeki Yoshiko Koizumi Naoto Matsuyama Chakkooth Vijayakumar Shu Seki 《Advanced functional materials》2014,24(1):28-36
New donor–acceptor‐type copolymers comprised of benzobisthiazole (BBTz) as a weak donor rather than acceptor are proposed. This approach can simultaneously lead to deepening the HOMO and LUMO of the polymers with moderate energy offset against fullerene derivatives in bulk heterojunction organic photovoltaics. As a proof‐of‐concept, BBTz‐based random copolymers conjugated with typical electron acceptors: thienopyrroledione (TPD) and benzothiadiazole (BT) based on density functional theory calculations are synthesized. Laser‐flash and Xe‐flash time‐resolved microwave conductivity (TRMC) evaluations of polymer:[6,6]‐phenyl C61 butyric acid methyl ester (PCBM) blends are conducted to screen the feasibility of the copolymers, leading to optimization of processing conditions for photovoltaic device application. According to the TMRC results, alternating BBTz‐BT copolymers are designed, exhibiting extended photoabsorption up to ca. 750 nm, deep HOMO (–5.5 to –5.7 eV), good miscibility with PCBM, and inherent crystalline nature. Moreover, the maximized PCE of 3.8%, the top‐class among BBTz‐based polymers reported so far, is realized in an inverted cell using TiOx and MoOx as the buffer layers. This study opens up opportunities to create low‐bandgap polymers with deep HOMO, and shows how the device‐less TRMC evaluation is of help for decision‐making on judicious molecular design. 相似文献
8.
This paper considers the optimal spare ordering policies for a cold standby redundant system with two dissimilar units. Especially, the planned maintenance schedule with salvage cost is discussed. The failure time distributions for respective units are assumed to be arbitrary. By applying the expected cost per unit time in the steady-state and the stationary availability as criteria of optimality, the optimal ordering policy minimizing or maximizing each criterion is obtained under some economical and/or physical assumptions. Finally, numerical examples are presented, and the effect of the failure time distributions for the optimal ordering policy is examined in detail. 相似文献
9.
Naoto Kimbara Akio Nishijima Toshio Sato Yuji Yoshimura Hiromichi Shimada Nobuyuki Matsubayashi Akinori Yukimura 《Catalysis Letters》1990,6(3-6):409-415
TiN supported molybdenum sulfide catalysts showed much higher activity for cleavage of C-C bonds than oxide supported molybdenum sulfide catalysts, indicating the possibility of a new generation of supports for hydroprocessing catalysts. 相似文献
10.
We discuss optimum inspection policies by introducing the inspection density. We derive the optimum inspection policy by using this inspection density. The models discussed are: 1) the basic model, 2) the basic model with checking time, and 3) the basic model with imperfect inspection. For each model, we obtain the approximate optimum inspection policy minimizing the total s-expected cost by applying the calculus of variations. 相似文献