Production of biodiesel from waste fryer grease using mixed methanol/ethanol system

Transesterification of waste fryer grease (WFG) containing 5–6 wt.% free fatty acid (FFA) was carried out with methanol, ethanol, and mixtures of methanol/ethanol maintaining the oil to alcohol molar ratio of 1:6, and initially with KOH as a catalyst. Mixtures of methanol and ethanol were used for transesterification in order to use the better solvent property of ethanol and rapid equilibrium using methanol. Formation of soap by reaction of FFA present in WFG with KOH instigated difficulty in the separation of glycerol from biodiesel ester. To untangle this problem, two-stage (acid and alkali catalyzed) method was used for biodiesel synthesis. More than 90% ester was obtained when two-stage method was used compared to ∼ 50% ester in single stage alkaline catalyst. In the case of mixed alcohol, a relatively smaller amount of ethyl esters was formed along with methyl esters. Acid value, viscosity, and cetane number of all the esters prepared from WFG were within the range of the ASTM standard. Esters obtained from WFG showed good performance as a lubricity additive.     

Effect of Calcium Lactate, 4-Hexyl Resorcinol and Vacuum Packing on Physico-chemical, Sensory and Microbiological Qualities of Minimally Processed Litchi (Litchi chinensis Sonn.)

Litchi (Litchi chinensis Sonn.) fruits are very susceptible to pericarp browning which adversely affects consumer acceptability even though the aril portion remains in excellent condition. Litchi arils (litchis) were treated with a solution containing 0–2% (w/v) calcium lactate (CL), 0–0.02% (w/v) 4‐hexyl resorcinol (4‐HR) and 1% potassium sorbate. The pH of solution was adjusted to 4.0 with citric acid. Treated litchis were packed in polystyrene trays, over‐wrapped with polypropylene film, vacuum‐packed (0, 47409.3, 94831.9 Pa) and stored at 4 ± 2 °C. Drip losses, pH, total soluble solids (TSS), sensory attributes and microbiological quality of stored samples were estimated. A four‐factor, three‐level experimental design (D₆ Hokes design) with 19 experiments was chosen. Mathematical models were developed to analyse and predict the effect of CL, 4‐HR, in‐package vacuum and storage time on the responses. TSS, pH and sensory scores decreased significantly (P 0.01), whereas drip losses and microbial count increased significantly (P 0.01) with time. Drip loss was significantly (P 0.1) reduced by addition of CL. 4‐HR prevented browning and changes in colour score during storage were significantly less. Vacuum in packages exerted significant (P 0.01) effect over pH, TSS, sensory and microbiological qualities of minimally processed litchis.     

Laser Induced Liquid Phase Reaction Synthesis Assisted Joining of Metal Matrix Composites

A Laser Induced Liquid Phase Reaction Synthesis Assisted Joining technique is employed for SiC-particulate/Al-alloy composite to produce joints. Joints in SiC/Al-alloy composite are produced by synthesis of suitable material product as a result of interaction between composite and Ti (or Ti-alloy) reactive filler material induced by laser energy in the joint region. Such reaction product minimizes or eliminates the formation of deleterious aluminum carbide phase in the joint region depending upon the type and nature of die interfacial reactive filler material and also the laser processing parameters. A laser beam is utilized to both synthesize the interfacial reactant mixture and to heat the base material adjacent to the joint region to minimize the thermal stresses. The technique along with suitable filler material, further can be extended to a variety of metal matrix composite systems including combinations of Gr/Al, B/Al, B₄C/Mg, Steel/Al, W/Al, Al₂ O₃ and Gr/Cu which are excellent for use in various automotive, aerospace and electronic applications. Preliminary observations describing the proof of concept of laser induced reaction joining of metal matrix composites are reported     

Response of wheat (Triticum aestivum) and pearl-millet (Pennistum americanum) to zinc fertilizers on two soils

Responses of ZnSO₄, Zn₃ (PO₄)₂ · 4H₂O, ZnO, ZnNH₄PO₃ · 2H₂O and zincated superphosphate were studied on wheat (Triticum aestivum) and pearl-millet (Pennistem americanum) in Balsamand sand (Ustipsament) and Ladwa fine loam (Typic Camborthids). In Balsamand sand all Zn fertilizers increased wheat and pearl-milllet grain yield significantly over control but ZnNH₄ PO₄ · 2H₂O and zincated super were the best sources. Straw yield was also highest due to zincated super and ZnNH₄PO₄ · 2H₂O applications. Zinc sulphate was significantly inferior to zincated super and ZnNH₄PO₄ · 2H₂O. In Ladwa fine loam, all fertilizers gave significantly higher grain yield of wheat and pearl-millet than control except ZnO in pearl-millet. Highest yield in this soil was obtained by ZnSO₄ · 7H₂O followed by ZnNH₄ PO₄ · 2H₂O and then zincated super.In Balsamand sand, the Zn fertilizers significantly increased the Zn concentration and Zn uptake of wheat grain. In pearl-millet, only Zn uptake was increased significantly with Zn fertilizers. Zincated super gave highest Zn uptake.The concentration of P in wheat grain was increased by Zn fertilizers in Balsamand sand, and also in pearl-millet where zincated super and ZnNH₄PO₄ were most effective in increasing the P content.When Zn fertilizers were applied to preceding pearl-millet the effect on succeeding wheat crop were in the same order as direct application of Zn fertilizers. Zincated super was the best and ZnO worst with respect to wheat grain and straw yield and uptake of Zn and P.     

Synthesis of poly(vinyl propionate) from poly(vinyl alcohol) in nonaqueous medium using ethyl nitrate dimethyl sulfoxide as a catalyst

Poly(vinyl alcohol) (PVA) can be dissolved in a nonaqueous medium in the presence of catalytic concentration of ethyl nitrate dimethyl sulfoxide, C₂H₅ONO₂·DMSO. From the PVA solution, poly(vinyl propionate), PVPR was prepared by the homogeneous esterification of PVA with propionic acid. The ester thus formed contained some unconverted hydroxyl group. The formation of the ester was confirmed by the IR and ¹H‐NMR spectra. The molecular weight of the ester was determined by GPC and intrinsic viscosity (η) was determined by viscometric method. Glass transition temperature, T_g, was obtained from differential scanning calorimetric (DSC) analysis. Thermal stabilities of the ester were checked by thermogravimetric analysis (TGA) and differential thermogravimetric (DTG) analysis. The efficiency of the ester as a flow improver of crude oil was also examined. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 5675–5679, 2006     

Evolution of Surface Morphology in Laser-Dressed Alumina Grinding Wheel Material

An approach to laser dressing of alumina grinding wheels is proposed based on solidification microstructures associated with rapid cooling rates obtained in laser surface processing. Laser dressing of alumina grinding wheels forms surface microstructures characterized by multifaceted grains that are expected to facilitate the micro-scale material removal during precision machining. A detailed investigation of variation of grain size and melt depth with laser fluence is conducted. The results are correlated with calculated cooling rates derived from a thermal model. In addition, based on microscopic observations, the formation of surface grains by stacking of individual multifaceted grains formed during laser dressing is suggested.     

Solving a real-time allocation problem with constraint programming

In this paper, we present an original approach (CPRTA for “Constraint Programming for solving Real-Time Allocation”) based on constraint programming to solve a static allocation problem of hard real-time tasks. This problem consists in assigning periodic tasks to distributed processors in the context of fixed priority preemptive scheduling. CPRTA is built on dynamic constraint programming together with a learning method to find a feasible processor allocation under constraints. Two efficient new approaches are proposed and validated with experimental results. Moreover, CPRTA exhibits very interesting properties. It is complete (if a problem has no solution, the algorithm is able to prove it); it is non-parametric (it does not require specific tuning) thus allowing a large diversity of models to be easily considered. Finally, thanks to its capacity to explain failures, it offers attractive perspectives for guiding the architectural design process.     

Mirror uncertainty and uniqueness conditions for determining shape and motion from orthographic projection

This paper presents new forms of necessary and sufficient conditions for determining shape and motion to within a mirror uncertainty from monocular orthographic projections of any number of point trajectories over any number of views. The new forms of conditions use image data only and can therefore be employed in any practical algorithms for shape and motion estimation. We prove that the mirror uncertainty for the three view problem also exists for a long sequence: if shapeS is a solution, so is its mirror imageS which is symmetric toS about the image plane. The necessary and sufficient conditions for determining the two sets of solutions are associated with the rank of the measurement matrixW.If the rank ofW is 3, then the original 3D scene points cannot be coplanar and the shape and motion can be determined to within a mirror uncertainty from the image data if and only if there are three distinct views. This condition is different from Ullman's theorem (which states thatthree distinct views of four noncoplanar points suffice to determine the shape and motion up to a reflection) in two aspects: (1) it is expressed in terms of image data; (2) it applies to a long image sequence in a homogeneous way.If the rank ofW is 2 and the image points in at least one view are not colinear in the image plane, then there are two possibilities: either the motion is around the optical axis, or the 3-D points all lie on the same plane. In the first case, the motion can be determined uniquely but the shape is not determined. In the second case, a necessary and sufficient condition is to be satisfied and at least 3 point trajectories over at least 3 distinct views are needed to determine the shape in each view to within a mirror uncertainty, and the number of motion solutions is equal to the combinatorial number of the possible positions of the plane in different views. The necessary and sufficient condition is associated with the rank of a matrixC: ifC has a rank of 1, the plane is undetermined; ifC has a rank of 2 (implying there are exactly 3 distinct views), then a necessary and sufficient condition, whose physical meaning is not completely clear, is to be satisfied to determine the plane to within 2 sets; ifC has a rank of 3 (implying there are 4 or more distinct views), then the plane can always be determined to within two sets.If the rank ofW is 2 or 1 and the image points in each view are colinear in the image plane, then the three dimensional motion problem reduces to a two dimensional motion problem. In this case, the uniqueness condition is associated with the rank of the reduced measurement matrix . If has a rank of 2, then the original 3D points cannot be colinear in the space and the shape and motion can be determined to within two sets if and only if three or more views are distinct. If has a rank of 1, there are two possibilities: if the rows of are identical, then either the original 3D points are not colinear and the motion is zero, or the points are colinear and possibly move between two mirror symmetric positions; if the rows of are not identical, then the motion is not determined.All proofs are constructive and thus define an algorithm for determining the uniqueness of solution as well as for estimating shape and motion from point trajectories.