A power-adaptable A/D converter with integrated data compression

A novel adaptable analog/digital converter (ADC) that combines analog/digital conversion and entropy-coding for integrated data compression and low-power operation is reported. The converter has high flexibility of operation in terms of adaptable resolution, conversion rate and input signal statistics. This feature allows to adaptively react to changes of the situation and to put the device in each case into the optimum configuration. The ADC has been realized in a 0.6 μm CMOS technology with a peak resolution of 12 bit and 200 kS/s maximum sampling rate. A comprehensive power model of the converter is presented that reflects precisely the power consumption determined from experiments. The model is very useful for optimizing the converter configuration in the node of a wireless sensor network for specific situations. A feasible real-life application is demonstrated.     

Self-standing crystalline TiO2 nanotubes/CNTs heterojunction membrane: synthesis and characterization

In the present study, we report for the first time synthesis of TiO(2) nanotubes/CNTs heterojunction membrane. Chemical vapor deposition (CVD) of CNTs at 650 °C in a mixture of H(2)/He atmosphere led to in situ detachment of the anodically fabricated TiO(2) nanotube layers from the Ti substrate underneath. Morphological and structural evolution of TiO(2) nanotubes after CNTs deposition were investigated by field- emission scanning electron microscopy (FESEM), glancing angle X-ray diffraction (GAXRD), and X-ray photoelectron spectroscopy (XPS) analyses.     

Interface architecture determined electrocatalytic activity of Pt on vertically oriented TiO(2) nanotubes

The surface atomic structure and chemical state of Pt is consequential in a variety of surface-intensive devices. Herein we present the direct interrelationship between the growth scheme of Pt films, the resulting atomic and electronic structure of Pt species, and the consequent activity for methanol electro-oxidation in Pt/TiO(2) nanotube hybrid electrodes. X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS) measurements were performed to relate the observed electrocatalytic activity to the oxidation state and the atomic structure of the deposited Pt species. The atomic structure as well as the oxidation state of the deposited Pt was found to depend on the pretreatment of the TiO(2) nanotube surfaces with electrodeposited Cu. Pt growth through Cu replacement increases Pt dispersion, and a separation of surface Pt atoms beyond a threshold distance from the TiO(2) substrate renders them metallic, rather than cationic. The increased dispersion and the metallic character of Pt results in strongly enhanced electrocatalytic activity toward methanol oxidation. This study points to a general phenomenon whereby the growth scheme and the substrate-to-surface-Pt distance dictates the chemical state of the surface Pt atoms, and thereby, the performance of Pt-based surface-intensive devices.     

Effect of cysteine on the electrochemical behavior of Cu10Ni alloy in sulfide polluted environments: Experimental and theoretical aspects

Electrochemical techniques were used to investigate the effect of cysteine (cys) on the dissolution behavior of Cu10Ni alloy in sulfide-polluted salt water through the analysis of the alloy electrochemical behavior including Tafel polarization and electrochemical frequency modulation (EFM) along with scanning electron microscopy (SEM) and energy dispersive X-ray diffraction (EDX). The results showed that cys acts as a mixed type inhibitor. The dissolution rate decreases with increasing cys concentration and increases with increasing the temperature. An adherent layer of inhibitor molecules on the alloy surface is proposed to account for their inhibitive action. The adsorption of cys on the active cathodic sites was found to follow the Langmuir adsorption isotherm from which the thermodynamic parameters of adsorption and corrosion processes were determined and discussed. A synergistic effect was observed between cys and potassium iodide (KI). EFM data are in good agreement with SEM and EDX results.     

Ge-doped ZnO nanorods grown on FTO for photoelectrochemical water splitting with exceptional photoconversion efficiency

In this study, a considerable effort has been devoted for the synthesis of Ge-doped ZnO nanorods on FTO as an efficient and robust photoanode material for solar water splitting. A unique, optimized, and ultra-rapid fabrication method to produce uniform nanorods (30–70 nm in diameter) has been demonstrated using radio frequency sputtering followed by electrochemical anodization. The effect of Ge doping on the conductivity, charge carrier concentration, optical, and photoelectrochemical properties of ZnO was investigated using scanning electron microscope (SEM), glancing angle X-ray diffraction (GAXRD), UV–Vis spectrometer, and Mott Schottky analysis. Glancing angle XRD confirmed the presence of wurtzite structure with a preferable orientation around (101) plane, which is of particular interest for many applications. As evidenced by the photoelectrochemical and transient photocurrent measurements, the fabricated Ge-doped ZnO nanorods exhibited enhanced photocurrent (12 mA/cm²) with an exceptional open circuit voltage of ?1.07 V_SCE (?0.416 V_RHE) under AM1.5G illumination, compared to the undoped ZnO based-photoanodes. Moreover, the Ge-doped ZnO nanorods showed unprecedented photoconversion efficiency of 3.6% under AM1.5G illumination. Therefore, the fabricated Ge-doped ZnO nanorods could be a promising conductive photoanode for water splitting.     

Concentration and Exposure Assessment of Mercury in Commercial Fish and Other Seafood Marketed in Oman

The results of this study present analytical data of the mercury levels in several fish and shellfish species to create awareness among individuals of the risks associated with consuming fish contaminated with mercury. Mercury concentrations varied from a mean of 0.02 mg/kg in Indian mackerel to 0.19 mg/kg in shark in both fresh and frozen fish, from 0.02 mg/kg in sardines to 0.18 mg/kg in skipjack tuna in canned fish, and from 0.02 mg/kg in Indian mackerel to 0.79 mg/kg in shark in dried fish. Shellfish contained a slightly higher amount of mercury than fresh or frozen fish with a mean of 0.09 mg/kg. Trophic position, followed by habitat, was the most important factors for variability in mercury concentrations in fish and shellfish. The maximum safe weekly intake (MSWI) values of mercury were significantly higher for herbivores than for carnivores. The MSWI value for total mercury in the case of consuming most (72%) fish species was more than 5 kg; however, the MSWI value was never more than 5 kg in most (66%) shellfish species. Risks were identified upon consumption of 120 g of dried shark when exceeding the provisional tolerable weekly intake threshold (1.6 μg/kg) for methylmercury. Therefore, fish‐eating populations should reduce the quantity of dried shark to efficiently diminish the exposure to mercury.     

Enhanced photoelectrochemical water splitting via engineered surface defects of BiPO4 nanorod photoanodes

Herein, we report on the defect engineering of BiPO₄ nanorods (NRs) via a facile room-temperature template-free co-precipitation method, followed by hydrogen treatment. The hydrogen treatment temperature determined the type of induced defects in the fabricated BiPO₄ NRs and consequently their photocatalytic performance. Upon varying the annealing temperature, the x-ray diffraction (XRD) analysis showed phase transformation and x-ray photoelectron spectroscopy (XPS) analysis revealed variation in the oxygen vacancy content. At moderate treatment temperatures (200–300 °C), shallow defects were predominant, which extended the optical activity of the material to the visible region and increased the photocurrent 3 times when compared to that of bare BiPO₄ NRs. However, treatment at higher temperatures completely altered the crystalline structure, destructed the morphology of the BiPO₄ NRs, and severely affected the photoelectrochemical performance.