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Hydroxyapatite (HAp) nanocrystals with different levels of fluorine substitution (P/F = 0, 6, 4 and 2) on the OH sites were produced via hydrothermal method. The fluorine substitution was found to alter the morphology of crystals appreciably. The aspect ratio and the crystallinity of HAp crystals increased with increasing fluorine substitution. The presence of broad ring and hallow ring patterns in electron diffraction suggests the low-crystalline nature of HAp crystals. With increasing fluorine substitution, the diffraction patterns exhibited discrete rings and numerous diffraction spots, implying the increased crystallinity. Raman spectra from the HAp nanoparticles also support the less-crystalline nature of the pristine HAp and the enhanced crystallization by fluorine substitution. In HAp crystals processed with no fluorine substitution, surface energy and planar Ca2+ density are less sensitive to the crystallographic orientation because of its low-crystalline nature, favoring equi-axed or slightly elongated particles. The addition of fluorine apparently increased the crystallinity, enhancing the orientation dependent growth and accordingly the aspect ratio. Osteoblast proliferation was observed to be enhanced by fluorine substitution in HAp. In vitro biological data support that the excellent osteoblastic cell viability and functional activity of the fluoridated apatite.  相似文献   
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A naturalistic field observation study is presented, exploring the experienced riders’ eye fixations on specific traffic objects and their relative s  相似文献   
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We need every tool we can get our hands on in the fight against global warming; a truly low‐carbon liquid fuel is clearly a tool we cannot give up lightly and arguably a tool we cannot do without. Unfortunately, our current policies do not require or reward broadly sustainably and truly low‐carbon biomass. What's more, the small policy steps forward are under atttack and the comprehensive policy solutions are not even being debated. As a result, any supply estimate that does not start by identifying the policies that would guide the market to choose sustainably managed feedstocks in sustainable quantities can be nothing more than a proof of concept, technical assessment. These estimates are misleadingly high in the current policy climate. Nevertheless to stop global warming we must try to get the right policies in place and with an aggressive package of policies, they might actually turn out to be low. A modest proposal for a billion gallon challenge with rich incentives and rigorous environmental requirements (perhaps building of voluntary sustainability certification standards such as the Roundtable on Sustainable Biofuels) is offered as a way to launch the advanced biofuels industry on the right track in a way will build public support.  相似文献   
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The biaxial orientation behavior of poly(ethylene 2,5‐furandicarboxylate) (PEF) is studied in comparison to poly(ethylene terephthalate) (PET). PEF is a polyester that can be produced through similar steps as PET but using 100% biobased 2,5‐furandicarboxylic acid instead of terephthalic acid. This work highlights the stress–strain behavior of PEF during biaxial orientation at various temperatures. Strain hardening and strain‐induced crystallization in the oriented PEF samples generally appeared at higher stretch ratios for PEF than for PET at comparable molecular weight, while somewhat lower degrees of crystallinity are reached in PEF. Shrinkage in oriented PEF is found to be on par with PET in the region of the glass transition. Higher modulus and improved barrier properties, compared to PET, are found in the oriented materials when sufficiently high stretch ratios are applied in biaxial orientation.  相似文献   
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Two studies were conducted to investigate whether a meaningful task-switching construct could be identified and, if so, to determine how it was related to measures of higher order cognition and to adult age. Both studies revealed that measures of task switching were moderately correlated across different combinations of tasks and that a switching construct could be distinguished from a construct reflecting processing speed. The results of the 2nd study revealed that although the task-switching construct was related to age and to measures of episodic memory, inductive reasoning, and spatial visualization, most of the relations between the switching construct and both age and other measures of cognition were shared with other variables. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
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Legal information certification and secured storage combined with documents electronic signature are of great interest when digital documents security and conservation are in concern. Therefore, these new and evolving technologies offer powerful abilities, such as identification, authentication and certification. The latter contribute to increase the global security of legal digital archives conservation and access. However, currently used cryptographic and hash coding concepts cannot intrinsically enclose cognitive information about both the signer and the signed content. Indeed, an evolution of these technologies may be necessary to achieve full text researches within hundreds or thousands of electronically signed documents. This article aims at describing a possible model along with associated processes to create and make use of these new electronic signatures called “meaningful electronic signatures” as opposed to traditional electronic signatures based on bit per bit computation.  相似文献   
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The group velocity dispersion (GVD) coefficient of four different dyes in solution is measured as a function of wavelength and concentration using a white-light Michelson interferometer. We find that the wavelength dependence of the GVD can be considerably different at wavelengths above and below the absorption resonance in a dye. Above the absorption resonance, the dye molecules can make a strong, wavelength-dependent contribution to the GVD of the solution. Below the absorption resonance, the dye molecules tend to contribute negligibly to the GVD of the solution. We find that the contribution of the dye molecules to the GVD can be modeled quite accurately using a simple Lorentz model with parameters set using the measured linear absorption properties of the dye.  相似文献   
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Adult age differences in Wisconsin Card Sorting Test (WCST) measures were examined before and after statistical control of age-related differences in measures of feedback usage, working memory, and perceptual-comparison speed. The proportion of age-related variance associated with a summary measure of WCST performance was greatly reduced after controlling for measures of feedback usage, working memory, and perceptual-comparison speed. Furthermore, the age-related variance associated with the feedback-usage measure was reduced after controlling for working memory and perceptual-comparison speed measures. These results are consistent with the idea that age-related performance differences in the WCST are partially mediated by adult age differences in feedback usage and that age differences in feedback usage are mediated by age differences in working memory, which are in turn mediated by age-related reductions in processing speed, indexed by measures of perceptual-comparison speed. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
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Stimuli‐responsive materials are so named because they can alter their physicochemical properties and/or structural conformations in response to specific stimuli. The stimuli can be internal, such as physiological or pathological variations in the target cells/tissues, or external, such as optical and ultrasound radiations. In recent years, these materials have gained increasing interest in biomedical applications due to their potential for spatially and temporally controlled release of theranostic agents in response to the specific stimuli. This article highlights several recent advances in the development of such materials, with a focus on their molecular designs and formulations. The future of stimuli‐responsive materials will also be explored, including combination with molecular imaging probes and targeting moieties, which could enable simultaneous diagnosis and treatment of a specific disease, as well as multi‐functionality and responsiveness to multiple stimuli, all important in overcoming intrinsic biological barriers and increasing clinical viability.  相似文献   
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