全文获取类型
收费全文 | 2472篇 |
免费 | 56篇 |
国内免费 | 2篇 |
专业分类
电工技术 | 16篇 |
化学工业 | 360篇 |
金属工艺 | 24篇 |
机械仪表 | 19篇 |
建筑科学 | 16篇 |
能源动力 | 74篇 |
轻工业 | 72篇 |
水利工程 | 5篇 |
无线电 | 59篇 |
一般工业技术 | 188篇 |
冶金工业 | 1592篇 |
原子能技术 | 16篇 |
自动化技术 | 89篇 |
出版年
2023年 | 14篇 |
2022年 | 31篇 |
2021年 | 43篇 |
2020年 | 30篇 |
2019年 | 38篇 |
2018年 | 43篇 |
2017年 | 45篇 |
2016年 | 56篇 |
2015年 | 21篇 |
2014年 | 34篇 |
2013年 | 64篇 |
2012年 | 52篇 |
2011年 | 60篇 |
2010年 | 39篇 |
2009年 | 33篇 |
2008年 | 26篇 |
2007年 | 23篇 |
2006年 | 25篇 |
2005年 | 20篇 |
2004年 | 13篇 |
2003年 | 15篇 |
2002年 | 12篇 |
2001年 | 12篇 |
2000年 | 9篇 |
1999年 | 61篇 |
1998年 | 547篇 |
1997年 | 271篇 |
1996年 | 184篇 |
1995年 | 102篇 |
1994年 | 86篇 |
1993年 | 120篇 |
1992年 | 24篇 |
1991年 | 29篇 |
1990年 | 21篇 |
1989年 | 18篇 |
1988年 | 22篇 |
1987年 | 20篇 |
1986年 | 20篇 |
1985年 | 23篇 |
1984年 | 10篇 |
1983年 | 11篇 |
1982年 | 31篇 |
1981年 | 26篇 |
1980年 | 23篇 |
1979年 | 7篇 |
1977年 | 38篇 |
1976年 | 60篇 |
1975年 | 4篇 |
1973年 | 4篇 |
1972年 | 4篇 |
排序方式: 共有2530条查询结果,搜索用时 15 毫秒
1.
2.
Liangtao Yang Liang-Yin Kuo Juan Miguel López del Amo Prasant Kumar Nayak Katherine A. Mazzio Sebastian Maletti Daria Mikhailova Lars Giebeler Payam Kaghazchi Teófilo Rojo Philipp Adelhelm 《Advanced functional materials》2021,31(38):2102939
A known strategy for improving the properties of layered oxide electrodes in sodium-ion batteries is the partial substitution of transition metals by Li. Herein, the role of Li as a defect and its impact on sodium storage in P2-Na0.67Mn0.6Ni0.2Li0.2O2 is discussed. In tandem with electrochemical studies, the electronic and atomic structure are studied using solid-state NMR, operando XRD, and density functional theory (DFT). For the as-synthesized material, Li is located in comparable amounts within the sodium and the transition metal oxide (TMO) layers. Desodiation leads to a redistribution of Li ions within the crystal lattice. During charging, Li ions from the Na layer first migrate to the TMO layer before reversing their course at low Na contents. There is little change in the lattice parameters during charging/discharging, indicating stabilization of the P2 structure. This leads to a solid-solution type storage mechanism (sloping voltage profile) and hence excellent cycle life with a capacity of 110 mAh g-1 after 100 cycles. In contrast, the Li-free compositions Na0.67Mn0.6Ni0.4O2 and Na0.67Mn0.8Ni0.2O2 show phase transitions and a stair-case voltage profile. The capacity is found to originate from mainly Ni3+/Ni4+ and O2-/O2-δ redox processes by DFT, although a small contribution from Mn4+/Mn5+ to the capacity cannot be excluded. 相似文献
3.
Bibhuti Bhusan Nayak 《传热工程》2019,40(8):679-692
The thermo-fluidic transport characteristics of the fly ash–water slurry flow in a straight horizontal pipe are predicted by deploying two different multiphase modeling strategies, viz. the mixture and the Eulerian multiphase models. Comparisons between the two model predictions in terms of the pressure drop and heat transfer coefficient are done along with the comparisons between the single (water) and the two phase system (slurry). Spherical fly ash particles, with diameter of 13 µm for an average inflow velocity ranging from 1 to 5 m/s and particle concentrations within 0–40% by volume for each velocity are considered as the dispersed phase carried by the carrier phase water. Significant differences between the two model predictions can be observed both from the qualitative and quantitative perspectives. This finally leads to the appropriate choice of the multiphase model for predicting the thermo-fluidic transport characteristics in slurry flow. 相似文献
4.
We report a 20 month old female patient with diploid-triploid mixoploidy (46,XX/69,XXX) syndrome with hypothyroidism and precocious puberty. The triploid cell line was only expressed in the fibroblast culture and comprised the majority (95%) of the cells. Chromosome analysis of the fetal blood sample and peripheral blood sample were normal. The patient shows typical features of full triploidy (growth and severe mental retardation, cranial and facial dysmorphism, complete syndactyly of fingers 3/4, partial syndactyly of toes 2/3) and facial but no body asymmetry. At the age of 5 months central hypothyroidism and precocious puberty were diagnosed. Thin pigmented streaks were visible on the wrists and legs of the patient at the age of 16 months. This is the first patient reported so far with 46,XX/69,XXX mixoploidy suffering from hypothyroidism and precocious puberty. 相似文献
5.
GS Kelner JM Minnerath MK Jenkins R Jemmerson 《Canadian Metallurgical Quarterly》1993,23(8):1992-1998
Male and female A/J mice were examined for their ability to elicit T lymphocyte and antibody (Ab) responses to the male-specific Ag, mouse testicular cytochrome c (Mt cyt). T lymphocytes from both male and female mice primed in vivo responded to the Ag in in vitro proliferation assays, and the dose-response curves were statistically indistinguishable. In addition, similar levels of Ab to Mt cyt were observed in immunized male and female mice. The B cells producing the Ab had switched isotypes to IgG1 and IgG2a, indicating that the self-reactive T helper (Th) cells in male mice were functional. Thus, male mice do not appear to be immunologically tolerant to Mt cyt, at least at the Th and B lymphocyte levels. No evidence for disease was found in male mice primed with Mt cyt. Major histocompatibility complex (MHC) class II-positive antigen-presenting cells are present in the testes and these were shown in vitro to process and present Mt cyt to a T cell hybridoma specific for the synthetic peptide Mt cyt 93-104. However, the hybridoma was not activated in the absence of exogenous Mt cyt 93-104 or Mt cyt, indicating that endogenous Mt cyt is not normally processed in sufficient quantity to effectively load MHC class II molecules with this particular Mt cyt-derived peptide. Notwithstanding any immunologic privilege of the testes, the lack of tolerance to Mt cyt and its failure to elicit an autoimmune disease could extend from the low levels of processed Mt cyt Ag available for T cell recognition. The T cell response elicited by Mt cyt contrasts the lack of response to mouse somatic cytochrome c which differs from Mt cyt at 13 amino acid residues and is expressed in most tissues and at higher levels. 相似文献
6.
AL Jensen MK Thomsen H Aaes M Andreasen J S?ndergaard 《Canadian Metallurgical Quarterly》1993,37(3-4):329-336
Growth hormone (GH) has recently been shown to affect polymorphonuclear neutrophil granulocyte (PMN) function and to be secreted by mononuclear cells, indicating that the hormone may be active in an immunophysiologic network, acting as an endo- or paracrine priming agent. The purpose of the present study was to evaluate the chemotactic responsiveness of canine peripheral PMN in a dog with acromegaly, caused by spontaneous, progesterone-induced hypersecretion of GH and, secondary to this, a seven-fold increase in insulin-like growth factor I (IGF-I). The chemotactic responsiveness towards zymosan-activated serum (ZAS) and leukotriene B4 (LTB4) was evaluated at a time when the dog suffered from acromegaly and again 57 days after corrective surgery (ovariohysterectomy). The experiments showed that PMN from the patient exhibited enhanced chemotactic migration that appeared to be associated with the hypersomatotropic condition as judged from the reversibility of the phenomenon. The glucose intolerance and elevated serum alkaline phosphatase that were observed in the acromegalic dog were also shown to be reversible following surgery. 相似文献
7.
8.
The graft copolymerization of methyl methacrylate onto natural rubber (NR) was carried out varying the concentration of monomer, initiator, thiourea, and silver nitrate over a wide range. The grafting reaction was temperature-dependent. From the Arrhenius plot, the overall energy of activation was computed. A suitable reaction scheme and rate expression for the rate of polymerization was suggested. 相似文献
9.
This paper presents a quantum protocol that demonstrates that weak coin flipping with bias ≈0.239, less than 1/4, is possible. A bias of 1/4 was the smallest known, and followed from the strong coin flipping protocol of Ambainis in [33rd STOC, 2001] (also proposed by Spekkens and Rudolph [Phys. Rev. A 65 (2002) 012310]). Protocols with yet smaller bias ≈0.207 have independently been discovered by Ambainis (2001) and Spekkens and Rudolph [Phys. Rev. Lett. 89 (2002) 227901]. We also present an alternative strong coin flipping protocol with bias 1/4 with analysis simpler than that of Ambainis [33rd STOC, 2001]. 相似文献
10.