Impact of non‐solvent on regeneration of cellulose dissolved in 1‐(carboxymethyl)pyridinium chloride ionic liquid

Cellulose dissolved in ionic liquid (1‐(carboxymethyl)pyridinium chloride)/water (60/40 w/w) mixture is regenerated in various non‐solvents, namely water, ethanol, methanol and acetone, to gain more insight into the contribution of non‐solvent medium to the morphology of regenerated cellulose. To this end, the initial and regenerated celluloses were characterized with respect to crystallinity, thermal stability, chemical structure and surface morphology using wide‐angle X‐ray diffraction, thermogravimetric analysis, Fourier transform infrared spectroscopy and scanning electron microscopy. According to the results, regardless of non‐solvent type, all regenerated samples have the same chemical structure and lower crystallinity in comparison to the initial cellulose, making them a promising candidate for efficient biofuel production based on enzymatic hydrolysis of cellulose. The reduction in crystallinity of regenerated samples is explained based on the potential of the non‐solvent to break the hydrogen bonds between cellulose chains and ionic liquid molecules as well as the affinity of water and non‐solvent which can be evaluated based on Hansen solubility parameter. The latter also determines the phase‐separation mechanism during the regeneration process, which in turn affects surface morphology of the regenerated cellulose. The pivotal effect of regenerated cellulose crystallinity on its thermal stability is also demonstrated. Regenerated cellulose with lower crystallinity is more susceptible to molecular rearrangement during heating and hence exhibits enhanced thermal stability. © 2019 Society of Chemical Industry     

Oil Spill Cleanup from Sea Water by Sorbent Materials

Three sorbents were compared in order to determine their potential for oil spill cleanup. Polypropylene nonwoven web, rice hull, and bagasse with two different particle sizes were evaluated in terms of oil sorption capacities and oil recovery efficiencies. Polypropylene can sorb almost 7 to 9 times its weight from different oils. Bagasse, 18 to 45 mesh size, follows polypropylene as the second sorbent in oil spill cleanup. Bagasse, 14 to 18 mesh size, and rice hull have comparable oil sorption capacities, which are lower than those of the two former sorbents. It was found that oil viscosity plays an important role in oil sorption by sorbents. All adsorbents used in this work could remove the oil from the surface of the water preferentially.     

Long‐term water uptake behavior of natural fiber/polypropylene composites

Composites of different natural fibers and polypropylene were prepared and their long‐term water absorption behaviors were studied. Wood flour, rice hulls, newsprint fibers, and kenaf fibers (at 25 and 50% by weight contents) were mixed with polypropylene and 1 and 2% compatibilizer, respectively. Water absorption tests were carried out on injection‐molded specimens at room temperature for 5 weeks. Measurements were made every week and water absorption was calculated. Water diffusion coefficients were also calculated by evaluating the water absorption isotherms. Results indicated a significant difference among different natural fibers, with kenaf fibers and newsprint fibers exhibiting the highest and wood flour and rice hulls the lowest water absorption values, respectively. The difference between 25 and 50% fiber contents for all composite formulations increased at longer immersion times. Water diffusion coefficients of the composites were found to be about 3 orders of magnitude higher than that of pure PP. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci, 2006     

Study on the performance of Cd2+ sorption using dimethylethylenediamine-modified zinc-based MOF (ZIF-8-mmen): optimization of the process by RSM technique

ABSTRACT

Cadmium as a highly toxic metal is released into the environment through paper production, metal processing, phosphate fertilizers, insecticides, and treatment of wastewater. Cadmium also inhibits the body activities and is very toxic for kidney and other organisms. In the current study, zinc-based metal–organic framework, zeolitic imidazolate framework (ZIF)-8, was synthesized and modified by dimethylethylenediamine (ZIF-8-mmen) for the removal of cadmium. To optimize the experiments, response surface methodology was applied with three variables including pH, adsorbent dosage, and contact time using central composite design. The optimum conditions for pH, dosage, and time were 2, 0.1 g, and 89 min, respectively, with removal efficiency of 85.38%. The Langmuir isotherm (q _m = 1000 mg/g) indicates the monolayer adsorption. The kinetic studies reveal that the Lagergren model was predominant and cadmium was not chemisorbed. Thermodynamic parameters show spontaneous, endothermic, and physisorption processes.     

Computational auditory models in predicting noise reduction performance for wideband telephony applications

The performance of several noise reduction algorithms intended for wideband telephony was evaluated both subjectively and objectively. The chosen algorithms were based on statistical modeling, spectral subtraction, Wiener filtering, or subspace modelling principles. A customized wideband noise reduction database containing speech samples corrupted by three types of background noises at three SNR levels, along with their enhanced versions was created. The overall quality of the speech samples in the database was subsequently rated by a group of listeners with normal hearing capabilities. Comprehensive statistical analyses were performed to assess the reliability of the subjective data, and to assess the performance of noise reduction algorithms across varied noisy conditions. The subjective quality ratings were then used to investigate the performance of several auditory model-based objective quality metrics. Key results from these investigations include: (a) there was a high degree of inter- and intra-subject reliability in the subjective ratings, (b) noise reduction algorithms enhance speech quality for only a subset of the noise conditions, and (c) auditory model-based metrics perform similarly in predicting speech quality ratings, when speech quality scores pertaining to a particular noise condition were averaged.     

Evaluation of antifungal effect of iron‐oxide nanoparticles against different Candida species

Iron‐oxide nanoparticles (IONPs) have been widely favoured due to their biodegradable, low cytotoxic effects and having reactive surface which can be altered with biocompatible coatings. Considering various medical applications of IONPs, the authors were encouraged to study whether IONPs could be effective against fungal infections caused by Candida species. In this study, IONPs were characterised by scanning electron microscopy, X‐ray diffraction, Fourier transform infrared spectroscopy and vibrating sample magnetometer. The goal of this study was to evaluate the antifungal activity of IONPs against different Candida spp. compared with fluconazole (FLC). IONPs were spherical with the size of 30–40 nm. The minimum inhibitory concentration (MIC) and minimum fungicidal concentration (MFC) values of IONPs ranged from 62.5 to 500 µg/ml and 500 to 1000 μg/ml, respectively. The MIC and MFC of FLC were in range of 16–128 μg/ml and 64–512 μg/ml, respectively. The growth inhibition value indicated that Candida tropicalis, Candida albicans and Candida glabrata spp. were most susceptible to IONPs. The finding showed that the IONPs possessed antifungal potential against pathogenic Candida spp. and could inhibit the growth of all the tested Candida spp. Further studies, both in vitro and in vivo (including susceptibility, toxicity, Probability of kill (PK) and efficacy studies) are needed to determine whether IONPs are suitable for medicinal purposes.Inspec keywords: iron compounds, nanoparticles, nanomedicine, biomedical materials, microorganisms, cellular biophysics, toxicology, drugs, scanning electron microscopy, X‐ray diffraction, Fourier transform infrared spectraOther keywords: antifungal effect, iron‐oxide nanoparticles, Candida species, biodegradable effects, cytotoxic effects, reactive surface, biocompatible coatings, medical applications, IONP, fungal infections, Candidiasis, immunocompromised hosts, antifungal drugs, resistant organisms, antifungal properties, side effects, chemical drugs, scanning electron microscopy, X‐ray diffraction, Fourier transform infrared spectroscopy, vibrating sample magnetometer, antifungal activity, disc diffusion, broth microdilution, minimal inhibitory concentration, minimum fungicidal concentration, Candida tropicalis, Candida Albicans, Candida glabrata, antifungal potential, Fe₃ O₄      

Flexible amorphous‐silicon non‐volatile memory

Abstract— The development of a flexible, rewritable, non‐volatile memory (NVM) that is implemented on a standard, low‐temperature a‐Si:H process without additional mask steps is reported. This NVM is a part of a flexible‐display system. Each NVM cell is composed of differentially configured thin‐film‐transistors (TFTs). The cell reads out one of two stable states depending on the relative threshold voltages of the differentially configured TFTs. Information is stored in each cell by increasing the threshold voltage of one differential TFT or the other, utilizing the well‐known electrical‐stress degradation intrinsic to a‐Si:H TFTs. The stored information is retained indefinitely with no applied power. A test array of individually addressable NVM cells has been successfully fabricated and tested on flexible stainless‐steel substrates. Read and write operation, as well as preliminary reliability measurements, are described. The design is readily scalable to large memory arrays.     

Using hash tables to manage the time-storage complexity in a point location problem: Application to explicit model predictive control

The online computational burden of linear model predictive control (MPC) can be moved offline by using multi-parametric programming, so-called explicit MPC. The solution to the explicit MPC problem is a piecewise affine (PWA) state feedback function defined over a polyhedral subdivision of the set of feasible states. The online evaluation of such a control law needs to determine the polyhedral region in which the current state lies. This procedure is called point location; its computational complexity is challenging, and determines the minimum possible sampling time of the system. A new flexible algorithm is proposed which enables the designer to trade off between time and storage complexities. Utilizing the concept of hash tables and the associated hash functions, the proposed method solves an aggregated point location problem that overcomes prohibitive complexity growth with the number of polyhedral regions, while the storage–processing trade-off can be optimized via scaling parameters. The flexibility and power of this approach is supported by several numerical examples.     

PDDRA: A new pre-fetching based dynamic data replication algorithm in data grids

In recent years, grid technology has had such a fast growth that it has been used in many scientific experiments and research centers. A large number of storage elements and computational resources are combined to generate a grid which gives us shared access to extra computing power. In particular, data grid deals with data intensive applications and provides intensive resources across widely distributed communities. Data replication is an efficient way for distributing replicas among the data grids, making it possible to access similar data in different locations of the data grid. Replication reduces data access time and improves the performance of the system. In this paper, we propose a new dynamic data replication algorithm named PDDRA that optimizes the traditional algorithms. Our proposed algorithm is based on an assumption: members in a VO (Virtual Organization) have similar interests in files. Based on this assumption and also file access history, PDDRA predicts future needs of grid sites and pre-fetches a sequence of files to the requester grid site, so the next time that this site needs a file, it will be locally available. This will considerably reduce access latency, response time and bandwidth consumption. PDDRA consists of three phases: storing file access patterns, requesting a file and performing replication and pre-fetching and replacement. The algorithm was tested using a grid simulator, OptorSim developed by European Data Grid projects. The simulation results show that our proposed algorithm has better performance in comparison with other algorithms in terms of job execution time, effective network usage, total number of replications, hit ratio and percentage of storage filled.