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1.
Factorial design and principal component models are used to determine how ab initio H-bond stretching frequencies depend on characteristics of the molecular orbital wave functions of acetylene–HX, ethylene–HX and cyclopropane–HX π-type hydrogen complexes with X=F, Cl, CN, NC and CCH. The results obtained for the three sets of complexes show that factorial design and principal component analyses complement each other. Factorial design calculations clearly show that these frequencies are affected mostly by inclusion of electron correlation on the calculation level. On average, their values are increased by about 25 cm−1 due to a change from the Hartree–Fock (HF) to Möller–Plesset 2 (MP2) level. Valence, diffuse and polarization main effects as well as valence–diffuse, diffuse–correlation and polarization–correlation interaction effects are also important to better describe a factorial model to the H-bond stretching frequencies of these hydrogen complexes. This simplified model has been successful in reproducing the complete ab initio results, which correspond to two hundred and forty calculations. Principal component analyses applied only to hydrogen-bonded complexes whose experimental frequencies are known, has revealed that the six-dimensional original space can be accurately represented by a bidimensional space defined by two principal components. Its graphical representation reveals that the experimental intermolecular stretching frequencies are in closest agreement with the MP2/6–31+G and MP2/6–311+G ab initio results.  相似文献   
2.
Direct charging of thin slabs of low carbon steel (0.05%C) was investigated by using laboratory tests on a thin-slab-casting Simulator linked with the hot deformation Simulator (Wumsi). Starting with a different initial thickness of simulated thin slabs (45 down to 25 mm) the total strain ?∑ was varied. Hot deformation schedules (with and without roughing) with different finishing temperatures TF lead to some differences in the hot strip microstructure. Nevertheless, after cold rolling and batch annealing, a rather uniform pancake-structure and a pronounced {111}-texture were achieved in the cold strip without any significant relation to the processing routs. The measurement of final mechanical properties proved that a good deep drawability of cold strip can be achieved with direct charging of thin slabs, well comparable to that after a conventional cold charging of thick slabs.  相似文献   
3.
The MSMIE protocol [SBC89] allows processors in a distributed system to communicate via shared memory. It was designed to meet the reliability and efficiency needs of applications such as nuclear safety systems. We present a formal model of the MSMIE protocol expressed in the notation CCS. Desirable properties of the protocol are expressed in the modal mu-calculus, an expressive modal logic. We show that the protocol lacks an important liveness property. In actual operation, additional operating constraints are checked to avoid potential problems. We present a modified protocol and show that it possesses the liveness property even without checking operating constraints. We also show how parts of the analysis were automated with the Concurrency Workbench.  相似文献   
4.
5.
Unilateral spatial neglect declines when participants reach to grip the center of long metal rods compared with when they point to the perceived center, suggesting that visuomotor control systems are less affected by neglect than other representational systems (I. H. Robertson, D. Nico, & B. Hood, 1995). In this study, 16 participants with unilateral left neglect actually picked up rods, and we predicted short-term improvements in neglect because of induced conflict between a phenomenally symmetrical visual world on the one hand and a proprioceptively conveyed rightward-biased world on the other. With participants serving as their own controls, significant short-term improvements in neglect were found on 2 out of 4 neglect tasks after participants experienced proprioceptive feedback discrepant from the judgments they made on the basis of visual information alone. (PsycINFO Database Record (c) 2010 APA, all rights reserved)  相似文献   
6.
The hypothesis of object representation by synchronization in the visual cortex has been supported by our recent experiments in monkeys. They demonstrated local synchrony among /spl gamma/ activities (30-90 Hz) and their perceptual modulation, according to the rules of figure-ground segregation. However, /spl gamma/-synchrony in primary visual cortex is restricted to few mm, challenging the synchronization hypothesis for larger cortical object representations. The restriction is due to randomly changing phase relations among locally synchronized patches which, however, form continuous waves of /spl gamma/-activity, traveling across object representations. The phase continuity of these waves may support coding of object continuity. Interactions across still larger distances, measured among cortical areas in human data, involve amplitude envelopes of /spl gamma/ signals. Based on models with spiking neurons we discuss potentially underlying mechanisms. Most important for /spl gamma/ synchronization are local facilitatory connections with distance-dependent delays. They also explain the occurrence of /spl gamma/ waves and the restriction of /spl gamma/-synchrony. Fast local feedback inhibition generates /spl gamma/ oscillations and supports local synchrony, while slow shunting inhibitory feedback supports figure-ground segregation. Finally, dispersion in inter-areal far projections destroys coherence of /spl gamma/ signals, but preserves their amplitude modulations. In conclusion, we propose that the hypothesis of associative processing by /spl gamma/ synchronization be extended to more general forms of signal coupling.  相似文献   
7.
This work is concerned with the efficient design of a reverse logistics network using an extended version of models currently found in the literature. Those traditional, basic models are formulated as mixed integer linear programs (MILP-model) and determine which facilities to open that minimize the investment, processing, transportation, disposal and penalty costs while supply, demand and capacity constraints are satisfied. However, we show that they can be improved when they are combined with a queueing model because it enables to account for (1) some dynamic aspects like lead time and inventory positions, and (2) the higher degree of uncertainty inherent to reverse logistics. Since this extension introduces nonlinear relationships, the problem is defined as a mixed integer nonlinear program (MINLP-model). Due to this additional complexity, the MINLP-model is presented for a single product-single-level network. Several examples are solved with a genetic algorithm based on the technique of differential evolution.  相似文献   
8.
Florence     
Nico Calavita 《Cities》1985,2(2):106-110
In 1284 the Florence Commune started building the last set of walls that were to surround the city until the second half of the 19th century. In response to the strong demographic and economic expansion of the 13th century, the new walls would have to contain a space commensurate with the present and future grandeur of the Commune.1 When completed in 1333, the walls circled the city for 8.5 kilometres and contained 73 towers, 15 doors and an area five times that included in the previous walls.  相似文献   
9.
We investigated whether changes in iron metabolism and the transferrin receptor (TRF-R) expression were involved in the antileukaemic effects of arabinoside cytosine (ara-C). Treatment with 100 nM ara-C for 48h reduced thymidine uptake and increased the surface expression of the TRF-R on leukaemic blasts derived from 13/16 (81%) patients and on the HL-60 and U-937 cell lines. Whereas intracellular non-haem iron was strongly depleted 24 h after ara-C addition, TRF-R up-regulation and recovery of intracellular non-haem iron concentration occurred together after a longer exposure of the cultured cells to the drug. Since iron is an essential regulator of cell proliferation we have evaluated the effects of the combination between ara-C and the iron chelator desferioxamine (DSF) on the growth of HL-60 and U-937 cells. We found that desferioxamine strongly potentiated the effects of ara-C on leukaemic cell growth inhibition and apoptosis. This is the first report of a positive interaction between ara-C and an iron chelator in terms of antileukaemic effects.  相似文献   
10.
Signal processing using orthogonal cutting force components for tool condition monitoring has established itself in literature. In the application of single axis strain sensors however a linear combination of cutting force components has to be processed in order to monitor tool wear. This situation may arise when a single axis piezoelectric actuator is simultaneously used as an actuator and a sensor, e.g. its vibration control feedback signal exploited for monitoring purposes. The current paper therefore compares processing of a linear combination of cutting force components to the reference case of processing orthogonal components. Reconstruction of the dynamic force acting at the tool tip from signals obtained during measurements using a strain gauge instrumented tool holder in a turning process is described. An application of this dynamic force signal was simulated on a filter-model of that tool holder that would carry a self-sensing actuator. For comparison of the orthogonal and unidirectional force component tool wear monitoring strategies the same time-delay neural network structure has been applied. Wear-sensitive features are determined by wavelet packet analysis to provide information for tool wear estimation. The probability of a difference less than 5 percentage points between the flank wear estimation errors of above mentioned two processing strategies is at least 95 %. This suggests the viability of simultaneous monitoring and control by using a self-sensing actuator.  相似文献   
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