Enhanced structural and optical properties of ZnO nanopowder with tailored visible luminescence as a function of sodium hydroxide to zinc sulfate mass ratio

ZnO nanopowders of tailored particle sizes were synthesized using a simple wet chemical method, by controlling the mass ratio of the precursors. The physical properties were investigated as a function of OH^?/Zn²⁺ mass ratio (x). The structural properties of the synthesized nanoparticles (NPs) are studied using X-ray diffraction (XRD). XRD patterns show pure wurtzite structure. Microstructural parameters dependence on x ratio was studied based on Williamson-Hall model. We notice an increase in crystallite size (17–24?nm) and a decrease in strain values when the x ratio increases (0.5–1.4). The best crystallinity corresponds to the higher mass ratio. Indeed, for x?=?1.4 we obtain the largest crystallite size, the lowest strain and stacking faults. The TEM images support the XRD results. Raman spectra confirm the purity of the synthesized ZnO powder. Furthermore, the optical properties were examined by UV–vis and Photoluminescence as a function of precursor’s ratio. Absorption data show a band gap red-shift of the ZnO-NPs with increase in particle’s size. Moreover, we found that the ZnO-NPs luminescence in the visible range can be engineered by changes of x ratio. This constitutes an advantage for the use of ZnO-NPs in different wavelength areas in optoelectronic applications covering UV-Blue-Green domain for the LED design, sensors…     

Characterisation of gamma‐irradiated polyetherimide films with infrared spectroscopy and thermally stimulated current measurements

The performance of insulators is usually affected by the presence of space charges. The evolution of these charges under applied constraints in many cases leads to the degradation of these materials. To evaluate the performance of an insulator it is necessary to study the evolution of the physical and chemical properties in the presence of space charges. In this paper, the effect of gamma irradiation on the space charge behaviour in polyetherimide (PEI; Ultem 1000) has been investigated at different radiation doses. Space charge measurements were made using thermally stimulated currents. Infrared spectroscopy characterisation was performed to investigate the effect of gamma irradiation on the physicochemical properties of PEI. The results obtained show minor differences in the infrared spectra, mainly in the 410 cm^?1 region. It is found that irradiation leads to a few structural changes in the material. The thermostimulated depolarisation current (TSDC) results show that β relaxations in PEI are affected by gamma irradiation. The activation energies of dipoles were calculated from the TSDC curves. Copyright © 2006 Society of Chemical Industry     

A multiparametric computer analysis of carcinoma of the colon

From 1957 to 1973, 656 patients with carcinoma of the entire colon, excluding those with carcinoma of the rectum, were reviewed with the aid of a computer. Of 457 patients, 69.7 per cent were observed for a minimum of five years. Sixty-five per cent of the lesions were located in the cecum or sigmoid colon. In patients with type A lesion, the five year plus survival rate was 71.15 per cent while, in patients with type D lesions, the five year plus survival rate was zero per cent. Patients who presented with intestinal obstruction had a significantly lower five year survival rate. Roentgenographic visualization of the cecum was significantly less accurate in demonstrating carcinoma when compared with that of the sigmoid colon. An emergency surgical procedure had a significantly higher operative mortality than did elective procedures. In both groups of patients undergoing emergency and elective operations, primary resection and anastomosis led to similar operative mortality rates, although staged procedures resulted in the lowest operative mortality in both groups. In the group of patients who had elective operations, resection an primary anastomosis led to a significantly lower wound infection and fistula rate when compared with the group of patients who had emergency procedures. In comparison with other series, no improvement in survival was illustrated in patients with carcinoma of the colon. The use of new modalities of adjuvant therapy, such as radiotherapy or chemotherapy, or both, actually should be evaluated.     

An event-based approach for formally verifying runtime adaptive real-time systems

Real-time and embedded systems are required to adapt their behavior and structure to runtime unpredicted changes in order to maintain their feasibility and usefulness. These systems are generally more difficult to specify and verify owning to their execution complexity. Hence, ensuring the high-level design and the early verification of system adaptation at runtime is very crucial. However, existing runtime model-based approaches for adaptive real-time and embedded systems suffer from shortcoming linked to efficiently and correctly managing the adaptive system behavior, especially that a formal verification is not allowed by modeling languages such as UML and MARTE profile. Moreover, reasoning about the correctness and the precision of high-level models is a complex task without the appropriate tool support. In this work, we propose an MDE-based framework for the specification and the verification of runtime adaptive real-time and embedded systems. Our approach stands for Event-B method to formally verify resources behavior and real-time constraints. In fact, thanks to MDE M2T transformations, our proposal translates runtime models into Event-B specifications to ensure the correctness of runtime adaptive system properties, temporal constrains and nonfunctional properties using Rodin platform. A flood prediction system case study is adopted for the validation of our proposal.