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排序方式: 共有237条查询结果,搜索用时 15 毫秒
1.
We have developed a diffusion-controlled size-selective method for sensing chloride ion in the presence of bromide ion, based on a thin, nanoporous, plasma-polymerized coating of hexamethyldisiloxane on an Ag/AgCl electrode. Sub-nanometer-sized pores responsible for a highly cross-linked polymer network in the plasma-polymerized coating allowed diffusion-controlled permeation of chloride ion while blocking the larger bromide ion. An electrode coating of thickness greater than 70 nm enabled chloride detection in the concentration range 1-10 mM in the presence of 0.63 mM bromide ion. Advantages of this approach are: (1) simple design compared with ionophore-based strategies and (2) compatibility with microfabrication and mass production processes. 相似文献
2.
Interaction of cation-exchange membrane with polycation I. Poly(N-methyl-4-vinylpyridinium chloride)
We elucidated the effect of the molecular weight of poly(N-methyl-4-vinylpyridinium chloride) (PMVP) on its adsorbed or ion-exchanged amount on the cation-exchange membrane and the preferntial permselectivity of the membrane for sodium ion to calcium ion. The amount of the adsorbed or ion-exchanged PMVP increases with time and then attains to a definite value at a definite concentration. Also, the ultimate value increases with increasing the concentration of PMVP. When the molecular weight of PMVP is 3090, the ratio of the pyridinium groups of PMVP ion-exchanged with the sulfonic acid groups on the membrane surface to the total pyridinium groups of the cohered PMVP is in the range of 70–80%. The relative transport number of calcium ions to sodium ions(PNaCa) decreases with increasing the amount of adsorbed or ion-exchanged PMVP and the numbe rof non-ion-exchanged pyridinium groups of PMVP and the number of non-ion-exchanged pyridinium groups of PMVP on the membrane surface. The smaller the molecular weight of PMVP, the more the adsorbed or ion-exchanged amount and the more preferable the permselectivity for sodium ion. 相似文献
3.
Nobuhiko Yabu Kouhei Nagano Nozomu Izumi 《Journal of the Society for Information Display》2015,23(6):246-252
Using shorter wavelength for exposure light is one way to achieve high resolution while keeping sufficient depth of focus. We show exposure results for high resolution to confirm the effect of deep UV exposure light. With deep UV light, 1.2‐µm line and space pattern and 1.8‐µm contact hole pattern are resolved while keeping sufficient depth of focus. 相似文献
4.
Nobuhiko Hayashi Yusuke Kato Manfred Sigrist 《Journal of Low Temperature Physics》2005,139(1-2):79-96
The low-temperature shrinking of the vortex core (Kramer-Pesch effect) is studied for an isolated single vortex for chiral
p-wave and s-wave superconducting phases. The effect of nonmagnetic impurities on the vortex core radius is numerically investigated
in the Born limit by means of a quasiclassical approach. It is shown that in the chiral p-wave phase the Kramer-Pesch effect
displays a certain robustness against impurities owing to a specific quantum effect, while the s-wave phase reacts more sensitively
to impurity scattering. This suggests chiral p-wave superconductors as promising candidates for the experimental observation
of the Kramer-Pesch effect. 相似文献
5.
Nobuhiko Tamura Norimichi Tsumura Yoichi Miyake 《Journal of the Society for Information Display》2003,11(2):333-339
Abstract— A color management system (CMS) such as ICC profile or sRGB space have been proposed for color transformation and reproduction of cross media. In such a CMS, accurate colorimetric characterization of a display device plays a critical role in achieving device‐independent color reproduction. In the case of a CRT, colorimetric characterization based on a GOG model is accurate enough for this purpose. However, there is no effective counterpart in liquid‐crystal displays (LCDs) since the characterization of an LCD has many difficulties, such as channel interaction and non‐constancy of channel chromaticity. In this paper, a new method of display characterization is proposed which is applicable to the assessment of color reproduction of LCDs. The proposed method characterizes an electro‐optical transfer function considering both channel interaction and non‐constancy of channel chromaticity. Experimental results show that the proposed method is very effective in the colorimetry of LCDs. 相似文献
6.
Kate J. Norris Andrew J. Lohn Takehiro Onishi Elane Coleman Vernon Wong Ali Shakouri Gary S. Tompa Nobuhiko P. Kobayashi 《Journal of Electronic Materials》2012,41(5):971-976
We report the growth of erbium monoantimonide (ErSb) thin films on indium antimonide (100) substrates by low-pressure metalorganic
chemical vapor deposition. The growth rate of ErSb thin films shows strong dependency on the growth temperature and the Sb/Er
precursor molar flow rate ratio. Scanning electron microscopy, energy-dispersive x-ray spectroscopy, and x-ray diffractometry
(XRD) were employed to study the ErSb thin films grown under the growth conditions that gave the maximum growth rate in the
range we investigated. We also report the growth of two types of nanocomposites in which ErSb nanocolumns or nanoslabs with
lengths ~500 nm and diameters 20 nm to 30 nm are embedded in Zn-doped InGaSb (ErSb/InGaSb:Zn) and ErSb nanoparticles with
diameters of ~30 nm are embedded in Zn-doped InSbAs (ErSb/InSbAs:Zn). These nanocomposites were intended to increase phonon
scattering in a mid-to-long phonon wavelength range to reduce lattice thermal conductivity. We used time-domain thermoreflectance
to measure total thermal conductivity for the two types of nanocomposites, obtaining 4.0 ± 0.6 W/mK and 6.7 ± 0.8 W/mK for
the ErSb/InAsSb:Zn and ErSb/InGaSb:Zn nanocomposites, respectively, which suggests that the thermal conductivity was close
to or slightly smaller than the alloy limit of the two ternary alloy hosts. The two nanocomposites were further studied by
transmission electron microscopy (TEM) to reveal their microscopic features and by XRD to assess their crystalline structures. 相似文献
7.
8.
Effect of supercritical CO2 extraction process parameters on oil yield and pigment content from by‐product hemp cake 下载免费PDF全文
Krunoslav Aladić Senka Vidović Jelena Vladić Davor Balić Huska Jukić Stela Jokić 《International Journal of Food Science & Technology》2016,51(4):885-893
This research gives an insight into the possibility of exploiting the one of the food industry's by‐products – pressed hemp cake. The complete recovery of oil from pressed hemp cake was achieved. Residual oil that remained in cake after pressing was extracted with supercritical CO2 by applying different process parameters. Optimal extraction conditions were determined using response surface methodology. Total pigment contents of the oils obtained were determined. Extraction pressure had the most significant influence on yield and pigment content of extracted hemp cake oil. Depending on the pressure, the chlorophyll a content ranged from 101.11 to 378.28 mg kg?1 and chlorophyll b from 65.14 to 189.78 mg kg?1, while total carotene content was in the range from 33.58 to 132.67 mg kg?1. The remaining oil in pressed hemp cake after supercritical CO2 extraction was determined to be 0.56 ± 0.08% and the defatted cake was rich in proteins and fibre. 相似文献
9.
Stela Jokić Sandra Svilović Zoran Zeković Senka Vidović 《International Journal of Food Science & Technology》2011,46(5):1031-1037
The solubility of soybean oil in supercritical carbon dioxide has been determined in the pressure range of 100–300 bar and in the temperature range of 313–323 K. The obtained values (from 0.0005 to 0.02055 g L?1) have been correlated using four different empirical equations proposed correspondingly by Chrastil, del Valle and Aquilera, Adachi and Lu and Sparks et al. Since the Sparks et al. equation provided the lowest average absolute relative deviation (AARD) (10.25%) than other models in the examined experimental range, a modified equation of Sparks et al. model was developed for predicting the solubility of soybean oil in supercritical carbon dioxide as a function of temperature and density. An improved equation showed the lowest deviation (2.15%) between experimental data than the other empirical equations considered in this study. The proposed equation was also applied for correlating the solubility of linoleic acid (AARD was 2.40%). 相似文献
10.
Igor Jerković Marina Rajić Zvonimir Marijanović Mate Bilić Stela Jokić 《分离科学与技术》2016,51(18):2925-2931
Supercritical (SC) CO2 extraction of dried Immortelle flowers was performed at different process parameters. The optimal extraction conditions related to the yield were determined by response surface methodology (yield 4.09% at 20 MPa and 52°C). The extracts were analyzed by GC-MS and tremetone derivatives dominated: bitalin A, 12-acetoxytremetone, gnaphaliol, 1-[2-(2-methyl-2,3-dihydroxypropyl)-2,3-dihydro-1-benzofuran-5-yl]ethanone, isobutyl bitalin A, and 1-[2-(acetylprop-1-en-2-yl)-3-hydroxy-2,3-dihydro-1-benzofuran-5-yl]ethanone. Striking differences were found among the essential oil and SC-CO2 extracts composition. The major oil compounds were γ-curcumene, α-pinene, β-selinene, α-selinene, and limonene. Mono- and sesquiterpene were found among minor constituents of the extracts. Neryl acetate was present in the extracts and essential oil. 相似文献