Silicon carbide filaments: Microstructure

The microstructure of chemically vapour deposited silicon carbide filaments has been examined using transmission electron microscopy. The filament bulk consisted of heavily faulted columnar subgrains of-SiC which were preferentially oriented such that {1 1 1} planes were parallel to the surface of the carbon fibre substrate. The protective coating on the filament surface was characterized by several microstructurally distinct layers, all of which consisted primarily of carbon. The first layers of the coating contained small crystallites of SiC in addition to turbostratic carbon, while the outer layers showed no evidence of SiC. Implications of the filament microstructure with respect to mechanical properties are discussed.     

Effect of thermal hysteresis on the gas permeation properties of 6FDA‐based polyimides

The effect of thermal hysteresis on the polymer chain packing and permeation properties of two 6FDA‐based polyimide isomers was investigated. Thermal quenching resulted in a small increase in the fractional free volume of the polyimides with respect to the samples that had been annealed. Quenching from above the glass‐transition temperature also resulted in larger increases in the permeabilities for both 6FDA–6FmDA and 6FDA–6FpDA with respect to annealed samples. Meta‐connected 6FDA–6FmDA exhibited a larger increase in the permeability after quenching than the para‐connected isomer, 6FDA–6FpDA. This larger increase in the permeability for 6FDA–6FmDA may have been due to differences in the effects of the increases in the free volume on the intersegmental resistance to chain motions. Although physical aging over a 3‐month period resulted in a reduction in the permeability of quenched samples of 6FDA–6FpDA, the quenched samples maintained higher permeabilities than the annealed samples. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1174–1182, 2004     

A Fully Integrated 0.13- μm CMOS Digital Low-IF DBS Satellite Tuner Using a Ring Oscillator-Based Frequency Synthesizer

A low-IF fully integrated tuner for DBS satellite TV applications has been realized in 0.13-mum CMOS. A wideband ring oscillator-based frequency synthesizer having a large frequency step was used to downconvert a cluster of channels to a sliding low-IF frequency, while the second downconversion to baseband was performed in the digital domain. Eliminating the inductors and using a small-area oscillator has reduced both the parasitic magnetic and substrate coupling, allowing single-chip integration of the sensitive tuner and the noisy digital demodulator. A significant reduction in die area was achieved by using a single oscillator to cover the entire satellite TV spectrum, while a noise attenuator was cascaded with the PLL passive loop filter to reduce the equivalent VCO tuning gain. This improves PLL noise and spur performance and allows the on-chip integration of the loop filter. The digital low-IF tuner allows the use of a discrete step AGC loop that results in lower noise figure and higher linearity. Automatic signal path gain and bandwidth digital calibration was realized using replica ring oscillators. Tuner specifications include: 90 dB gain range, 10 dB noise figure at max gain, +25dBm IIP3 at min gain, 1.3deg rms integrated phase noise, <-50dBc spurs, 0.5-W power consumption from dual 1.8/3.3-V supplies, and 1.8times1.2 mm² die area     

Effects of Preprocessing on Multi-Direction Properties of Aluminum Alloy Cold-Spray Deposits

The effects of powder preprocessing (degassing at 400 °C for 6 h) on microstructure and mechanical properties of 5056 aluminum deposits produced by high-pressure cold spray were investigated. To investigate directionality of the mechanical properties, microtensile coupons were excised from different directions of the deposit, i.e., longitudinal, short transverse, long transverse, and diagonal and then tested. The results were compared to properties of wrought 5056 and the coating deposited with as-received 5056 Al powder and correlated with the observed microstructures. Preprocessing softened the particles and eliminated the pores within them, resulting in more extensive and uniform deformation upon impact with the substrate and with underlying deposited material. Microstructural characterization and finite element simulation indicated that upon particle impact, the peripheral regions experienced more extensive deformation and higher temperatures than the central contact zone. This led to more recrystallization and stronger bonding at peripheral regions relative to the contact zone area and yielded superior properties in the longitudinal direction compared with the short transverse direction. Fractography revealed that crack propagation takes place along the particle-particle interfaces in the transverse directions (caused by insufficient bonding and recrystallization), whereas through the deposited particles, fracture is dominant in the longitudinal direction.     

SiC-Whisker-Reinforced Glass-Ceramic Composites: Interfaces and Properties

Different types of SiC whiskers were incorporated into lithium aluminosilicate (LAS) and calcium aluminosilicate (CAS) glass-ceramic matrices. Interfaces in these composites were characterized using Auger spectroscopy, scanning electron microscopy (SEM), and transmission electron microscopy (TEM), and the observations were correlated with measurements of fracture toughness and strength. The chemistry and morphology of the resulting interfaces affected the composite strength and toughness and controlled the mode of crack propagation. Certain types of SiC whiskers were characterized by a carbon-rich near-surface chemistry that became more carbon rich after composite fabrication. In these materials, the flexural strength at 20°C increased by up to 400% and the fracture toughness increased by up to 500%. Crack propagation modes were characterized by crack deflection, whisker–matrix debonding, and crack bridging. In contrast, SiC whiskers with stoichiometric near-surface chemistry generally did not form carbon-rich interfaces during composite fabrication, resulting in composites with low strength and fracture toughness.     

Vitreous carbon micro-lattice structures

A new approach is presented to fabricate open-cellular carbon materials with an ordered, lattice-type micro-scale architecture. The carbon micro-lattice materials were fabricated by pyrolyzing a polymer precursor template formed from an interconnected three-dimensional array of self-propagating photopolymer waveguides. Impregnating the polymer precursor template with acrylonitrile increased the carbon yield of the material from 19% to 46%. Structural analysis and density measurements of the solid carbon phase are consistent with vitreous carbon. Compression experiments yielded a compressive modulus (E) of 1.1 GPa and a failure strength (σ_f) of 10.2 MPa for a structure with relative density of 12.8%.     

Nucleation and Growth Characteristics of Cavities during the Early Stages of Tensile Creep Deformation in a Superplastic Zirconia–20 wt% Alumina Composite

Constant-stress tensile creep experiments on a superplastic 3-mol%-yttria-stabilized tetragonal zirconia composite with 20 wt% alumina revealed that cavities nucleate relatively early during tensile deformation. The number of cavities nucleated increases with increasing imposed stress. The cavities nucleate at triple points associated largely with an alumina grain, and then grow rapidly in a cracklike manner to attain dimensions on the order of the grain facet size. It is suggested that coarser-grained superplastic ceramics exhibit lower ductility due to the ease in formation of such grain boundary facet-cracks and their interlinkage to form a macroscopic crack of critical dimensions.     

The unification hierarchy is undecidable

In unification theory, equational theories can be classified according to the existence and cardinality of minimal complete solution sets for equation systems. For unitary, finitary, and infinitary theories minimal complete solution sets always exist and are singletons, finite, or possibly infinite sets, respectively. In nullary theories, minimal complete sets do not exist for some equation systems. These classes form the unification hierarchy.We show that it is not possible to decide where a given equational theory resides in the unification hierarchy. Moreover, it is proved that for some classes this problem is not even recursively enumerable.