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Y. Fujishiro T. Sato A. Okuwaki 《Journal of materials science. Materials in medicine》1995,6(3):172-176
Coating of hydroxyapatite on various metal plates was carried out by a homogeneous precipitation technique using hydrothermal reactions in Ca(edta)2-–NaH2PO4 at 140–200°C and pH 3.4–10.0. Hydroxyapatite films were formed on the surface of the iron plates in solutions at an initial pH above 4.7, whereas aggregates consisting of needle-like hydroxyapatite crystal radiating from a point in the form of flower deposited as islands on the surface of aluminum, copper and titanium plates. The upper part of the film formed on the surface of the iron plates consisted of needle-like hydroxyapatite particles whereas the bottom of the film consisted of spherical hydroxyapatite particles. The length of the needle-like hydroxyapatite particles increased with decreasing concentration of Ca(edta)2-. 相似文献
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Iron powders were oxidized in NaOH solutions of 5–25 mol kg–1 at 403–563 K and 5 MPa of oxygen partial pressure. Various types and morphologies of iron compounds such as fine particles of Fe3O4, micaceous -Fe2O3, and coagulated particles of -NaFeO2 were formed depending on the experimental conditions. The observed critical concentrations of NaOH above which -NaFeO2 was formed was in good agreement with those thermodynamically calculated for the hydrolysis equilibrium of -NaFeO2. 相似文献
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Metal nitrides and carbides powders were synthesized by the spark discharge method in liquid ammonia at 100 °C and 11 kV of the spark discharge voltage and in n-heptane at 25 °C and 7.5 kV using the pellets of aluminum, titanium, iron and chromium as the starting material. The main products were AlN, TiN0.51, -Fe, -Cr2N in liquid ammonia, and Al4C3, TiC, -Fe, Fe2C and Cr7C3 in n-heptane. The agglomerated particle size decreased with increasing melting point of the metal used as the starting material. 相似文献
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Tsugio Sato Kenji Dosaka Toshiaki Yoshioka Akitsugu Okuwaki Kazuo Torii Yoshiro Onodera 《Journal of the American Ceramic Society》1992,75(3):552-556
Amorphous CeO2 –ZrO2 gels were prepared by coprecipitation in ammonia solutions. The onset of crystallization of the gels, from calcining in air, was 420°C, while 200° to 250°C in the presence of water and organic solvents such as methanol and ethanol. The sintering behaviors of CeO2 –ZrO2 powders were sensitive to the crystallizing conditions, since hard agglomerates formed when the precipitated gels were crystallized by normal calcination in air, whereas soft agglomerates formed when they were crystallized in water or organic solvents. CeO2 –ZrO2 powders crystallized in methanol and water at 250°C were sintered to full theoretical density at 1150° and 1400°C, respectively, whereas that crystallized by calcination in air at 450°C was sintered to only 95.2% of theoretical density, even at 1500°C. 相似文献
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Hiroki Tanaka Tatsunari Takahashi Manami Konishi Nae Takata Masaki Gomi Daiki Shirane Ryo Miyama Shinya Hagiwara Yuki Yamasaki Yu Sakurai Keisuke Ueda Kenjirou Higashi Kunikazu Moribe Eiji Shinsho Ruka Nishida Kaori Fukuzawa Etsuo Yonemochi Koji Okuwaki Yuji Mochizuki Yuta Nakai Kota Tange Hiroki Yoshioka Shinya Tamagawa Hidetaka Akita 《Advanced functional materials》2020,30(34)
RNA‐based therapeutics is a promising approach for curing intractable diseases by manipulating various cellular functions. For eliciting RNA (i.e., mRNA and siRNA) functions successfully, the RNA in the extracellular space must be protected and it must be delivered to the cytoplasm. In this study, the development of a self‐degradable lipid‐like material that functions to accelerate the collapse of lipid nanoparticles (LNPs) and the release of RNA into cytoplasm is reported. The self‐degradability is based on a unique reaction “Hydrolysis accelerated by intra‐Particle Enrichment of Reactant (HyPER).” In this reaction, a disulfide bond and a phenyl ester are essential structural components: concentrated hydrophobic thiols that are produced by the cleavage of the disulfide bonds in the LNPs drive an intraparticle nucleophilic attack to the phenyl ester linker, which results in further degradation. An oleic acid‐scaffold lipid‐like material that mounts all of these units (ssPalmO‐Phe) shows superior transfection efficiency to nondegradable or conventional materials. The insertion of the aromatic ring is unexpectedly revealed to contribute to the enhancement of endosomal escape. Since the intracellular trafficking is a sequential process that includes cellular uptake, endosomal escape, the release of mRNA, and translation, the improvement in each process synergistically enhances the gene expression. 相似文献
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Okuwaki T. Kugiya F. Kumasaka N. Yoshida K. Tsumita N. Tamura T. 《IEEE transactions on magnetics》1985,21(5):1365-1367
5.25 inch high density perpendicular magnetic recording floppy disk drive has beer developed by employing new types of high saturation magnetization ring head, Co-Cr single layer medium with Ge underlayer, head slider with ellipsoidal surface configuration to assure intimate head to medium contact, and signal equalization. By these combination, recording density D50 of 145 kFCI, peakshift of 28 % at 100 kFCI, signal to noise ratio of 40.4 dB for cut-off frequency 4.25 MHz, overwrite signal to noise ratio of 27 dB, measured by writing signals at 48 kFCI over previously written 100 kFCI signals were obtained as typical recording characteristics. These results would indicate that floppy disk drive with 100 kFCI recording density has enough system margin by above-mentioned combination. In this paper, design and performance of newly developed floppy disk drive are described. 相似文献
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The oxidation behaviours of iron powders, ca. 100 m in diameter, in 5–50 m NaOH, 5–40 m KOH and 5–40 m LiOH solutions at 373–573 K were investigated in the absence and presence of oxygen, where m is molality. The oxidation of iron proceeded noticeably above 423 K to form Fe3O4, -Fe2O3, -NaFeO2, -Fe2O3, Li
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Fe3–xO4 and -LiFeO2 depending on the reaction conditions. The rate of oxidation in LiOH solutions was much slowerthan those in NaOH and KOH solutions. 相似文献