Ozone effects on Sphagnum mosses,carbon dioxide exchange and methane emission in boreal peatland microcosms

Microcosms of a boreal peatland originating from an oligotrophic fen in Eastern Finland were fumigated under four ozone concentrations (0, 50, 100 and 150 ppb O3) in laboratory growth chambers during two separate experiments (autumn and summer) for 4 and 6 weeks, respectively. Ozone effects on Sphagnum mosses and the fluxes of carbon dioxide and methane were evaluated. In both experiments, the three Sphagnum species studied showed only a few significant responses to ozone. In the autumn experiment, membrane permeability of S. angustifolium, measured as conductivity and magnesium leakage, was significantly higher under ozone fumigation (P = 0.005 and < 0.001, respectively), and there was a distinct dose-dependence. S. magellanicum showed no clear responses, either for membrane leakage or pigment content. There were no substantial ozone responses in the gross photosynthesis or net CO2 exchange during the 6-week-long summer experiment, but dark ecosystem respiration was transiently increased by ozone concentration of 100 ppb after 14 days of exposure (P < 0.05). Fumigation with 100 ppb of ozone, however, more than doubled (P < 0.05) methane emission from the peatland monoliths. Our results suggest that increasing tropospheric ozone concentration may cause substantial changes in the carbon gas cycling of boreal peatlands, even though these changes are not closely associated with the changes in Sphagnum vegetation.     

The validity and reliability of a portable slip meter for determining floor slipperiness during simulated heel strike

A previously developed test rig was used as starting point for designing a portable slip meter with two new features. First, an inflatable pneumatic test wheel, consisting of six slider units, was introduced as the impacting contact element relative to floor surface. Second, an inductive trigger was built into the system to facilitate a precise timing of the slider-floor contact during the test. This new test rig was designed to measure transitional friction properties of contaminated floor surfaces during simulated heel strike, which is considered the most critical phase of gait from the slip and fall point of view. Another objective was to quantify the validity and reliability of this test method in the laboratory, but not yet in the field. The measurement process was evaluated on eight wet and oily floor surfaces (vinyl and ceramic tile floorings) using two slider materials (plain, profiled), two normal loads (100, 200 N), and two sliding velocities (0.15, 0.30 m/s) as independent variables. The outputs of the portable slip meter, in terms of transitional friction coefficients, were compared to force platform-based friction values and to slip resistance values obtained with a slip simulator apparatus for laboratory testing of shoes and floor surfaces. The outputs were also evaluated against slipperiness ratings made by three male subjects in paired comparison trials, in which the subjects walked over eight wet floor surfaces wearing shoes with the plain soling material. The results showed that test option 200 N and 0.15m/s led to optimum validity despite its tendency to promote frictional vibrations (stick-slip) in the contact surface. Compared to the lower sliding speed, the higher speed reduced both stick-slip and measurement bias. Test option 200 N and 0.30 m/s was the most reliable one in this experiment. It yielded lower friction coefficients than any other test option and reduced the likelihood of underestimating slip and fall hazards. The results implied that the minimum friction coefficient was 0.25 for preventing a fall on wet floor surfaces, whereas the limit for preventing a slip was in the range 0.30-0.35. Transitional friction measurement was found to be a valid and reliable indicator for slip resistance. A more accurate control of the normal force during testing is needed for actual field use of the test method.     

Structure, hardness and thermal stability of TiAlN and nanolayered TiAlN/CrN multilayer films

TiAlN films were deposited on silicon (1 1 1) substrates from a TiAl target using a reactive DC magnetron sputtering process in Ar+N₂ plasma. Films were prepared at various nitrogen flow rates and TiAl target compositions. Similarly, CrN films were prepared from the reactive sputtering of Cr target. Subsequently, nanolayered TiAlN/CrN multilayer films were deposited at various modulation wavelengths (Λ). X-ray diffraction (XRD), energy dispersive X-ray analysis, nanoindentation and atomic force microscopy were used to characterize the films. The XRD confirmed the formation of superlattice structure at low modulation wavelengths. The maximum hardness of TiAlN/CrN multilayers was 3900 kg/mm², whereas TiAlN and CrN films exhibited maximum hardnesses of 3850 and 1000 kg/mm², respectively. Thermal stability of TiAlN and TiAlN/CrN multilayer films was studied by heating the films in air in the temperature range (T_A) of 500-900 °C for 30 min. The XRD spectra revealed that TiAlN/CrN multilayers were stable up to 800 °C and got oxidized substantially at 900 °C. On the other hand, the TiAlN films were stable up to 700 °C and got completely oxidized at 800 °C. Nanoindentation measurements performed on the films after heat treatment showed that TiAlN retained a hardness of 2200 kg/mm² at T_A=700 °C and TiAlN/CrN multilayers retained hardness as high as 2600 kg/mm² upon annealing at 800° C.     

A comparative study of reactive direct current magnetron sputtered CrAlN and CrN coatings

Approximately 1.5 μm thick CrN and CrAlN coatings were deposited on silicon and mild steel substrates by reactive direct current (DC) magnetron sputtering. The structural and mechanical properties of the coatings were characterized using X-ray diffraction (XRD) and nanoindentation techniques, respectively. The bonding structure of the coatings was characterized by X-ray photoelectron spectroscopy (XPS). The surface morphology of the coatings was studied using scanning electron microscopy (SEM) and atomic force microscopy (AFM). The XRD data showed that the CrN and CrAlN coatings exhibited B1 NaCl structure. Nanoindentation measurements showed that as-deposited CrN and CrAlN coatings exhibited a hardness of 18 and 33 GPa, respectively. Results of the surface analysis of the as-deposited coatings using SEM and AFM showed a more compact and dense microstructure for CrAlN coatings. The thermal stability of the coatings was studied by heating the coatings in air from 400 to 900 °C. The structural changes as a result of heating were studied using micro-Raman spectroscopy. The Raman data revealed that CrN coatings got oxidized at 600 °C, whereas in the case of CrAlN coatings, no detectable oxides were formed even at 800 °C. After annealing up to 700 °C, the CrN coatings displayed a hardness of only about 7.5 GPa as compared to CrAlN coatings, which exhibited hardness as high as 22.5 GPa. The potentiodynamic polarization measurements in 3.5% NaCl solution indicated that the CrAlN coatings exhibited superior corrosion resistance as compared to CrN coatings.     

Performance and stability of poly(phenylene vinylene) based polymer light emitting diodes with caesium carbonate cathode

We have studied the phenomena resulting from the combination of a hole-conducting poly(phenylene vinylene) (PPV) based light emitting polymer with a highly efficient electron injection layer of caesium carbonate (Cs₂CO₃) in light emitting diodes. A strong dependence between the thickness of the applied Cs₂CO₃ and the electro-optical performance of the diodes is detected and already with ultrathin Cs₂CO₃ layers high efficiency diodes are achieved. The Cs₂CO₃ is shown to diffuse into the polymer layer leading to an increased electron density but also quenching of both electro and photoluminescence when the amount of applied Cs₂CO₃ is increased. During electrical stressing the electron density decreases assumably through degradation of the n-doping and quenching Cs₂CO₃ species inducing an unusual increasing luminescence behavior.     

Improvement in the properties of nickel by nano-Cr2O3 incorporation

Nano-ceramic composite coatings were prepared by the electrodeposition method using sulphamate electrolyte. Nickel was chosen as the metal matrix and nano-Cr₂O₃ particles were chosen as the reinforcement. The surface morphology and the particle distribution in the coating were analysed using field emission scanning electron microscope (FESEM). The particle content was obtained using energy dispersive X-ray analysis (EDAX). A change in the surface morphology of Ni was seen on the incorporation of Cr₂O₃ particles. The coatings were characterized for their structure and no change in the diffraction pattern was seen between plain Ni and Ni-Cr₂O₃ composite. The mechanical property like microhardness and tribological behaviour of the nano-composite coatings was studied and it was observed that the incorporation of Cr₂O₃ particles enhanced the mechanical properties of Ni matrix. The nano-composites were analysed for their thermal stability and corrosion resistance. An improvement in thermal stability was observed but no change in the corrosion behaviour of Ni was seen on the incorporation of nano chromium oxide particles.     

Enteropathogenic Yersinia in the Pork Production Chain: Challenges for Control

Enteropathogenic Yersinia comprising pathogenic Yersinia enterocolitica and Yersinia pseudotuberculosis, are zoonotic pathogens causing foodborne intestinal illness in humans. Y. enterocolitica is common in pork production and pork is associated with infections in humans. Therefore, there is a need to reduce the occurrence and spread of these pathogens within the pork production chain. It would be most effective to control enteropathogenic Yersinia at the farm level. However, at present, feasible intervention methods are lacking and more research is needed. The most effective way to prevent the spread of Y. enterocolitica is to buy piglets from Y. enterocolitica‐negative farms. At slaughterhouses, the occurrence of enteropathogenic Yersinia can be reduced but not completely removed by slaughter hygiene and changing slaughter methods. After slaughter, it is difficult to control enteropathogenic Yersinia, since they can survive and even multiply during cold storage and under modified atmosphere. In addition, current knowledge and actions in both domestic and professional kitchens are insufficient for the prevention of yersiniosis. The significance of Y. pseudotuberculosis carried by pigs is uncertain. Although data are still lacking for pathogenic Y. enterocolitica in many aspects, there is even a greater lack of information regarding Y. pseudotuberculosis in pork production. There is a definite need for further research on these pathogens.     

Controlling the crystallinity and roughness of atomic layer deposited titanium dioxide films

The surface roughness of thin films is an important parameter related to the sticking behaviour of surfaces in the manufacturing of microelectomechanical systems (MEMS). In this work, TiO2 films made by atomic layer deposition (ALD) with the TiCl4-H2O process were characterized for their growth, roughness and crystallinity as function of deposition temperature (110-300 degrees C), film thickness (up to approximately 100 nm) and substrate (thermal SiO2, RCA-cleaned Si, Al2O3). TiO2 films got rougher with increasing film thickness and to some extent with increasing deposition temperature. The substrate drastically influenced the crystallization behaviour of the film: for films of about 20 nm thickness, on thermal SiO2 and RCA-cleaned Si, anatase TiO2 crystal diameter was about 40 nm, while on Al2O3 surface the diameter was about a micrometer. The roughness could be controlled from 0.2 nm up to several nanometers, which makes the TiO2 films candidates for adhesion engineering in MEMS.     

Spectrally selective NbAlN/NbAlON/Si3N4 tandem absorber for high-temperature solar applications

A new spectrally selective NbAlN/NbAlON/Si₃N₄ tandem absorber was deposited on copper substrates using a reactive direct current magnetron sputtering system. A high solar absorptance (0.956) and a low emittance (0.07) were achieved by gradually decreasing the refractive index from the substrate to the surface. The tandem absorber was characterized using solar spectrum reflectometer and emissometer, X-ray photoelectron spectroscopy, phase-modulated spectroscopic ellipsometry, atomic force microscopy and micro-Raman spectroscopy techniques. In order to study the thermal stability of the tandem absorbers, they were subjected to heat treatment (in air and vacuum) at different durations and temperatures. The tandem absorber deposited on copper substrate exhibited high solar selectivity in the order of 13–15 even after heat treatment in air up to 500 °C for 2 h. These tandem absorbers also exhibited high thermal stability (450 °C) in air for longer durations (116 h). The onset of oxidation for the tandem absorber deposited on silicon substrates was 650 °C, indicating a high oxidation resistance. The results of the present study indicate the importance of NbAlN/NbAlON/Si₃N₄ tandem absorber for high-temperature solar selective applications.     

Performance analysis of power generating sludge combustion plant and comparison against other sludge treatment technologies

Expectations on wastewater sludge treatment and recovery of its energy and material contents are increasing because of the tightening legislation and the obligation to reduce environmental impacts of sludge disposal. The objective of this study was to analyze the performance of a heat and power generating sludge combustion plant from technical and economical viewpoints and to compare the studied concept to optional sludge treatment technologies. The plant performance was modeled for sewage sludge produced by approximately 200,000 inhabitants. Two plant sizes below 1000 kWe range were investigated, the smaller plant using sludge as the only fuel and the larger plant with wood chips as the additional fuel. The plants were compared with heat-only plants of similar size. The payback periods for heat-only plants are typically shorter than with the cogenerating plants because the changes in plant investment affect stronger the economy than do the revenues from selling electricity. The gate fee of sludge treatment has the strongest effect on the payback period. The selection of the plant concept (cogeneration, heat only or pure electricity generation) is, however, affected more by the local demand of heat and electricity than pure economy. The selection of the optimal technology for sludge treatment is a complicated task. The studied concept can be the optimal choice, for example, if there is no cement kiln or co-combustion possibility near the source of sludge, if there is no land enhancement demand for the digested sludge, or if the energy surplus from combustion compared to anaerobic digestion is considered more valuable than nutrient recovery possibility from digestion. If the new technology concept is found competitive, it still has to meet the challenge of acceptability from the business, social and cultural points of view.