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排序方式: 共有632条查询结果,搜索用时 15 毫秒
1.
Rizwan Ullah Khan Haojie Yu Li Wang Lisong Teng Zain-ul-Abdin Ahsan Nazir Shah Fahad Tarig Elshaarani Fazal Haq Di Shen 《应用聚合物科学杂志》2020,137(46):49424
The development of safe drug carriers is cardinal in cancer therapy, which can target the cancer cells and release the loaded drug on-demand without damaging the healthy cells of the body. In our work, we synthesized three different biodegradable polymers, poly[(ethyl aminobezoate) (ethyl glycinato) phosphazenes] (PABGPs), in different mole ratio of side groups. The successful synthesis of these PABGPs was confirmed by 1H NMR, 31P NMR, FT-IR, and gel permeation chromatography. These PABGPs were fabricated into drug (camptothecin, CPT, a hydrophobic anticancer drug) loaded nanoparticles. These drug-loaded nanoparticles showed good drug release behaviors under normal physiological conditions (pH 7.4 and temperature 37°C). These PABGPs-based nanoparticles may find their application as effective drug carriers for cancer therapy. 相似文献
2.
Shafeeque G. Ansari Mushtaq Ahmad Dar Young-Soon Kim Hyung-Kee Seo Gil-Sung Kim Rizwan Wahab Zubaida A. Ansari Jae-Myung Seo Hyung-Shik Shin 《Korean Journal of Chemical Engineering》2008,25(3):593-598
A comparative study for the nucleation of diamond was carried out using surface treatment like (i) surface scratching with
1 μm diamond paste and (ii) surface etching using chlorine plasma at different RF powers (50, 100 and 150 W). Atomic force
microscopic study shows variation in roughness from 31 nm to 110 nm. Scratching results in random scratches, whereas plasma
etches a surface uniformly. Scanning electron microscopic observations show well faceted crystallites with a predominance
of angular shaped grains corresponding to 〈100〉 and 〈110〉 crystallite surfaces for the scratched as well as plasma etched
substrate. Surface etching at 150 W plasma power results in a better growth in comparison with 50 and 100 W plasma powers.
Chlorine-radical is found responsible for the changes in the growth morphology. Raman spectroscopy shows a sharp peak at 1,332
cm−1 and a peak at ∼1,580 cm−1 for both samples. 相似文献
3.
This paper describes different dynamic tests carried out on three bridges, B14, B15, and B13, over highway E19, which connects Brussels and Antwerpen in Belgium. Different excitation types are considered: a drop weight, a heavy truck on the bridge, and ambient vibrations mainly due to the traffic under the bridge. Finite-element models are constructed to support and verify the dynamic measurements. The modal parameters are extracted from the response time series using the data dependent system approach. A vector autoregressive model is developed and successfully applied to the measured responses in time domain. Good correlation between the finite-element simulations and the experiments is obtained. 相似文献
4.
Observations of fatigue-induced slip patterns on the surface of polycrystalline gold (+99.9%) using the scanning tunnelling microscope (STM) are presented. The samples were cycled in four-point bending between zero and 0.0025 strain for 250 and 2500 cycles. STM observations of the sample fatigued for 250 cycles revealed broad slip bands 0.38–0.69 m wide containing narrow slip bands 0.015–0.123 m wide and fine slip lines 0.006 m wide. The depth of these features are 20–57 nm for broad slip bands, 3–7 nm for narrow slip bands, and approximately 2–4 nm for fine slip lines. The sample fatigued for 2500 cycles showed similar values for the width of the slip bands and slip lines except that their depth was increased by a factor of between 2 and 4 times for the narrow slip bands and the fine slip lines. Apparent persistent slip bands (PSBs) spaced 2.4 m, 300–500 nm deep were also observed. These results demonstrate that STM is a significant new tool for observing and distinguishing various types of fatigue-induced surface slip patterns on suitably prepared samples. The vertical resolution obtained with STM is vastly superior to current SEM and TEM methods. 相似文献
5.
A 2-D five-noded finite element which contains a singularity is developed. The new element is compatible with cubic standard isoparametric elements. The main advantage of using cubic isoparametric elements over quadratic elements is to reduce the number of elements required to model a structure for results of comparable accuracy. The element is tested on two different examples. In the first example, an edge crack problem is analyzed using two different meshes. The second example is a crack perpendicular to the interface problem which is solved for two different specific composites. The results obtained using the proposed element are compared with those obtained using other existing elements in the literature. Those comparisons demonstrate the superiority of the present technique in using less number of elements and nodes to produce accurate results. 相似文献
6.
Miscible polymer blends based on various ratios of poly(vinyl acetate) (PVAc) and poly(methyl methacrylate) (PMMA) were prepared in film form by the solution casting technique using benzene as a common solvent. The thermal decomposition behavior of these blends and their individual homopolymers before and after γ‐irradiation at various doses (50–250 kGy) was investigated. The thermogravimetric analysis technique was utilized to determine the temperatures at which the maximum value of the rate of reaction (Tmax) occurs and the kinetic parameters of the thermal decomposition. The rate of reaction curves of the individual homopolymers or their blends before or after γ‐ irradiation displayed similar trends in which the Tmax corresponding to all polymers was found to exist in the same position but with different values. These findings and the visual observations of the blend solutions and the transparency of the films gave support to the complete miscibility of these blends. Three transitions were observed along the reaction rate versus temperature curves; the first was around 100–200°C with no defined Tmax, which may arise from the evaporation of the solvent. The second Tmax was in the 340–380°C range, which depended on the polymer blend and the γ‐irradiation condition. A third transition was seen in the rate of reaction curves only for pure PVAc and its blends with PMMA with ratios up to 50%, regardless of γ‐ irradiation. We concluded that γ‐irradiation improved the thermal stability of PVAc/PMMA blends, even though the PMMA polymer was degradable by γ irradiation. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 99: 1773–1780, 2006 相似文献
7.
The initial rate of colloid deposition onto semi‐permeable membranes is largely controlled by the coupled influence of permeation drag and particle‐membrane colloidal interactions. Recent studies show that the particle‐membrane interactions are subject to immense local variations due to the inherent morphological heterogeneity (roughness) of reverse osmosis (RO) and nanofiltration (NF) membranes. This experimental investigation reports the effect of membrane roughness on the initial deposition of polystyrene latex particles on a rough NF membrane during cross flow membrane filtration under different operating pressures and solution chemistries. Atomic force microscopy was used to characterize the roughness of the membrane and observe the structure of particle deposits. At the initial stages of fouling, the AFM images show that more particles preferentially accumulate near the “peaks” than in the “valleys” of the rough NF membrane surface. 相似文献
8.
Raina Aman Qazi Mohammad Saleem Khan Luqman Ali Shah Rizwan Ullah Ayesha Kausar Rozina Khattak 《Polymer-Plastics Technology and Engineering》2020,59(9):928-951
ABSTRACTFabrication of electronic materials from nanocomposite of biopolyesters reinforced with carbon nanotubes can be regarded as the effective alternative for conventional nanocomposites consisting of non-biodegradable polymers. Commercial availability of biopolyester-based nanocomposites is limited because of their high cost compared to other polymers, but the factor of their compostable nature is worthless for environmental protection. Such nanocomposites have potential applications in biodegradable sensors, EMI materials, etc. In this review, the current progress of biopolyester/CNTs nanocomposites in the field of biodegradable electronics is reviewed and also the impact of CNTs dispersion on electrical, thermal and mechanical properties of eco composites is stipulated. 相似文献
9.
Nouman Ali Shah Yue Ren Ri-Tong Lan Jia-Cheng Lv Rizwan M. Gul Peng-Fei Tan Shishu Huang Lin Tan Jia-Zhuang Xu Zhong-Ming Li 《应用聚合物科学杂志》2021,138(43):51261
Highly crosslinked ultrahigh molecular weight polyethylene (UHMWPE) stabilized by vitamin E (VE) is widely applied in artificial joints as the bearings. Despite the approval, there is a discord that VE lowers the crosslinking efficiency, limiting its use at high concentration. In this work, we aim to obtain highly crosslinked and oxidation resistant UHMWPE through the conjunction of tea polyphenol and chemical crosslinking. We hypothesized that highly incorporated tea polyphenol with multiple reactive sites can ameliorate crosslinking efficiency of chemical crosslinked UHMWPE in comparison to VE. Epigallocatechin gallate (EGCG) as representative tea polyphenol was incorporated into UHMWPE at high concentration (2–8 wt%), followed by chemical crosslinking with 2 wt% organic peroxide. Unlike VE/UHMWPE blends as the control, chemical crosslinking achieved an increasing trend in crosslink density of EGCG/UHMWPE blends with increasing antioxidant concentration. High concentration of EGCG also enhanced the oxidation stability of UHMWPE. Intriguingly, EGCG endowed UHMWPE with an excellent antimicrobial property, which was inefficient in VE/UHMWPE. Cell viability was hardly affected by the high loaded antioxidant and peroxide. The chemically crosslinked UHMWPE blended with EGCG is proved to be a reasonable, cost effective and realistic alternative for use in artificial joints. 相似文献
10.
Muhammad Waseem Rizwan Ahmed Muhammad Irfan Shahid Qamar 《Quantum Information Processing》2013,12(12):3649-3664
We present a scheme for the implementation of three-qubit Grover’s algorithm using four-level superconducting quantum interference devices (SQUIDs) coupled to a superconducting resonator. The scheme is based on resonant, off-resonant interaction of the cavity field with SQUIDs and application of classical microwave pulses. We show that adjustment of SQUID level spacings during the gate operations, adiabatic passage, and second-order detuning are not required that leads to faster implementation. We also show that the marked state can be searched with high fidelity even in the presence of unwanted off-resonant interactions, level decay, and cavity dissipation. 相似文献