TiO2/modified natural clay semiconductor as a potential electrode for natural dye-sensitized solar cell

TiO₂/modified natural bentonite clay semiconductor, as a potential electrode of dye-sensitized solar cell, having a Ti:Si molar ratio of 85:15 was, for the first time, compared with pure TiO₂ (commercial P25) electrode in terms of solar cell efficiency and characteristics. 4-Chloro-2,5-difluorobenzoic acid and 4-(chloromethyl)benzoyl chloride were added to the electrodes to increase light harvesting ability of natural dyes extracted from red cabbage, rosella, and blue pea. The results showed that the TiO₂/clay semiconductor provided a higher surface area but a slightly lower efficiency than the pure TiO₂. The best natural sensitizer was found to be the dye extracted from red cabbage. Besides, the 4-(chloromethyl)benzoyl chloride provided a higher short circuit current for the TiO₂/clay semiconductor.     

Preparation of sol–gel TiO2/purified Na-bentonite composites and their photovoltaic application for natural dye-sensitized solar cells

The sol–gel TiO₂/purified natural clay electrodes having Ti:Si molar ratios of 95:5 and 90:10 were initially prepared, sensitized with natural red cabbage dye, and compared to the sol–gel TiO₂ electrode in terms of physicochemical characteristics and solar cell efficiency. The results showed that the increase in purified Na-bentonite content greatly increased the specific surface area and total pore volume of the prepared sol–gel TiO₂/purified Na-bentonite composites because the clay platelets prevented TiO₂ particle agglomeration. The sol–gel TiO₂/5 mol% Si purified Na-bentonite and sol–gel TiO₂/10 mol% Si purified Na-bentonite composites could increase the film thickness of solar cells without cracking when they were coated as a scattering layer on the TiO₂ semiconductor-based film, leading to increasing the efficiency of the natural dye-sensitized solar cells in this work.     

The rates of desulfurization of liquid iron by solid CaO and CaO-saturated liquid iron oxide at 1600‡c

The rates of desulfurization of Fe-O-S melts by CaO crucibles and by CaO-saturated liquid iron oxide have been measured at 1600 ‡C. It was found that irons containing 1.62 wt pct and 0.64 wt pct sulfur and 0.070 wt pct oxygen are desulfurized by a reaction with the containing CaO crucible which does not involve the formation of a CaS product layer. The rate of desulfurization reaction is controlled by diffusion of sulfur in the iron melt, and a value of 6.7 ±1.7 × 10^-5 cm² per second was obtained for the diffusion coefficient of sulfur in liquid iron. Iron containing 0.088 wt pct sulfur and 0.070 wt pct oxygen is not desulfurized by solid CaO. The rate of desulfurization of liquid iron containing 0.088 wt pct sulfur and 0.070 wt pct oxygen by CaO-saturated liquid iron oxide is significantly greater than that calculated on the assumption of diffusion control in the metal phase, and evidence is presented in support of speculation that the reaction rate is enhanced by Marangoni turbulence at the slag-metal interface. The addition of 4 wt pct CaF₂ to the CaO-saturated liquid iron oxide has no influence on the rate of desulfurization of the melt. A. Saelim formerly Lecturer, Faculty of Engineering, Prince of Songkla University, Thailand     

Preparation and characterization of amphotericin B-loaded silk fibroin nanoparticles-in situ hydrogel composites for topical ophthalmic application

Journal of Materials Science - The objective of this study was to develop and characterize a novel combined systems of amphotericin B-loaded silk fibroin nanoparticles (AmB-FNPs) and in situ...     

Geothermal energy in Phrao Basin, Chiang Mai, Thailand

Phrao Basin is famous for its geothermal and seismic activities. There are five geothermal manifestations along the western margin of the basin. These geothermal sites are probably controlled by the major fault extending northward from the Sankamphaeng geothermal field. Geological, geochemical and geophysical studies, along with 2 boreholes of 150 m depth, were aimed at investigating the potential of this area. The results indicated that the intermediate depth of the geothermal reservoir may produce enough hot fluids for various uses, albeit on a small-scale. Several industries that could be attracted to Phrao Basin by development of these geothermal areas have been identified.