Oil Families and Their Potential Sources in the Southern Gulf of Suez, Egypt

Four oil families are identified in the southern Gulf of Suez, through high-resolution geochemical studies including gas chromatography, gas chromatography-mass spectrometry, and carbon isotope analyses. Biological features characterize oils in family 1a, suggesting tertiary carbonate source rocks for these oils, rich in type II organic matter and deposited under anoxic depositional environment. Family 1b oil shows minor variations in the source of organic matter and the depositional environment, as it was derived from carbonate source rock with more algal and bacterial contribution and minor input of terrestrial organic sources, deposited under less saline condition compared to family 1a oil. Family 2 oil, although genetically related to family 1a oil, has some distinctive features, such as diasterane to sterane and pristane to phytane ratios, which suggest clay-rich source rocks and a more oxic depositional environment. Also, the lack of oleanane indicates pre-tertiary source rocks for this oil. In contrast, family 3 oil is of mixed sources (marine and non-marine), generated from low sulfur and clay-rich source rock of tertiary and/or younger age. Family 4 oil seems to be mixed from family 1b and family 3 oils, sourced mainly from carbonate source rocks rich in clay minerals with algal and bacterial contributions. Family 4 oil is highly mature, family 1b oil lies within equilibrium values (peak oil generation stage), while the other families are more or less near equilibrium.     

Oil Spill Cleanup from Sea Water by Sorbent Materials

Three sorbents were compared in order to determine their potential for oil spill cleanup. Polypropylene nonwoven web, rice hull, and bagasse with two different particle sizes were evaluated in terms of oil sorption capacities and oil recovery efficiencies. Polypropylene can sorb almost 7 to 9 times its weight from different oils. Bagasse, 18 to 45 mesh size, follows polypropylene as the second sorbent in oil spill cleanup. Bagasse, 14 to 18 mesh size, and rice hull have comparable oil sorption capacities, which are lower than those of the two former sorbents. It was found that oil viscosity plays an important role in oil sorption by sorbents. All adsorbents used in this work could remove the oil from the surface of the water preferentially.     

Novel hybrid DNN approaches for speaker verification in emotional and stressful talking environments

Neural Computing and Applications - In this work, we conducted an empirical comparative study of the performance of text-independent speaker verification in emotional and stressful environments....     

Employing both gender and emotion cues to enhance speaker identification performance in emotional talking environments

Speaker recognition performance in emotional talking environments is not as high as it is in neutral talking environments. This work focuses on proposing, implementing, and evaluating a new approach to enhance the performance in emotional talking environments. The new proposed approach is based on identifying the unknown speaker using both his/her gender and emotion cues. Both Hidden Markov Models (HMMs) and Suprasegmental Hidden Markov Models (SPHMMs) have been used as classifiers in this work. This approach has been tested on our collected emotional speech database which is composed of six emotions. The results of this work show that speaker identification performance based on using both gender and emotion cues is higher than that based on using gender cues only, emotion cues only, and neither gender nor emotion cues by 7.22 %, 4.45 %, and 19.56 %, respectively. This work also shows that the optimum speaker identification performance takes place when the classifiers are completely biased towards suprasegmental models and no impact of acoustic models in the emotional talking environments. The achieved average speaker identification performance based on the new proposed approach falls within 2.35 % of that obtained in subjective evaluation by human judges.     

Modulation Based Combination of High Level Features Generated from SCCF & Contourlet Transforms for CBIR Applications

The need for suitable and cost-effective technologies rise with the growth of the internet of things (IoT) applications. These aim at handling voluminous data transmission in addition to minimum energy and latency cost constraints. LoRa networks are recommended for applications in confined spaces, long ranges, and less battery consumption requirements. However, the end devices in these networks communicate to all gateways in their ranges, thereby expediting energy unproductively in redundant transmissions. In our article, we explore the possibilities of whether LoRa networks could employ the advantages of clustering and propose two algorithms, path-based and data-centric, for such networks. We suggest that LoRaWAN technology with clustering can be apt for long-range, low power consumption IoT applications in the future. We study the impact of network density, node range, and cluster range on the energy consumption in data transmissions. The algorithms are compared with the inherent star-based communication of LoRa networks based on energy consumed, and our results show that, for dense deployments, clustering becomes advantageous.

     

Dynamic estimation of the modeling error statistics in Diffuse Optical Tomography

Diffuse Optical Tomography (DOT) is a non-invasive imaging technique that suffers from a typical large-scale and ill-posed inverse problem with low spatial resolution. In DOT, the inverse problem is computationally intensive and decreasing the computation complexity and making it well-posed is the one of the most challenging research areas. More precisely, one of the well-known complexity reduction techniques is defined as applying modelling error originated from discretization of forward problem. Applying the discretization error in Bayesian inference has already been discussed; the method in which the likelihood is modified by an off-line prior density estimation. This paper implements a new method to enhance the modelling error approach using an iterative scheme to update statistical parameters of modelling discrepancy in DOT. The algorithm is very similar to Ensemble Kalman Filter. Moreover, the reconstruction process in the applied method is conducted by a small sample size rather than off-line method. Hence, the computation complexity is decreased and the algorithm converges in few iterations. The efficiency of the proposed method is illustrated by simulations.     

Probabilistic design of ground improvement by vertical drains for soil of spatially variable coefficient of consolidation

The design of soil consolidation via prefabricated vertical drains (PVDs) has been traditionally carried out deterministically and thus can be misleading due to the ignorance of the uncertainty associated with the inherent variability of soil properties. To treat such uncertainty in the course of design of soil improvement by PVDs, more rational probabilistic methods are necessary. In this paper, a simplified probabilistic method is proposed in which the inherent variability of the coefficient of consolidation, which is the most significant uncertain soil parameter that affects the consolidation process, is considered. An easy-to-use design procedure and charts are provided for routine use by practitioners.     

Injectable polyethylene glycol-laponite composite hydrogels as articular cartilage scaffolds with superior mechanical and rheological properties

In this study, injectable PEG-based hydrogels containing Laponite particles with mechanical and structural properties close to the natural articular cartilage are introduced. The nanocomposites are fabricated by imide ring opening reactions utilizing synthesized copolymers containing PEG blocks and nanoclay through a two-step thermal poly-(amic acid) process. Butane diamine is used as nucleophilic reagent and hydrogels with interconnected pores with sizes in the range of 100–250?µm are prepared. Improved viscoelastic properties compared with the conventional PEG hydrogels are shown. Evaluation of cell viability utilizing human mesenchymal stem cells determines cytocompatibility of the nanocomposite hydrogels.     

Morphology and crystallization behavior of nylon 6‐clay/neat nylon 6 bicomponent nanocomposite fibers

Nylon 6‐clay hybrid/neat nylon 6, sheath/core bicomponent nanocomposite fibers containing 4 wt % of clay in sheath section, were melt spun at different take‐up speeds. Their molecular orientation and crystalline structure were compared to those of neat nylon 6 fibers. Moreover, the morphology of the bicomponent fibers and dispersion of clay within the fibers were analyzed using scanning electron microscopy and transmission electron microscopy (TEM), respectively. Birefringence measurements showed that the orientation development in sheath part was reasonably high while core part showed negligibly low birefringence. Results of differential scanning calorimetry showed that crystallinity of bicomponent fibers was lower than that of neat nylon 6 fibers. The peaks of γ‐crystalline form were observed in the wide‐angle X‐ray diffraction of bicomponent and neat nylon 6 fibers in the whole take‐up speed, while α‐crystalline form started to appear at high speeds in bicomponent fibers. TEM micrographs revealed that the clay platelets were individually and evenly dispersed in the nylon 6 matrix. The neat nylon 6 fibers had a smooth surface while striped pattern was observed on the surface of bicomponent fibers containing clay. This was speculated to be due to thermal shrinkage of the core part after solidification of the sheath part in the spin‐line. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2014 , 131, 39996.     

Direct synthesis of bi-modal porous structure MCM-41 and its application in CO2 capturing through amine-grafting

A bi-modal porous structure MCM-41 (BPS-MCM-41) was synthesized and functionalized by 3-[2-(2-Aminoethylamino)ethylamino]propyltrimethoxysilane (TRI); also, its performance in amine grafting and CO₂ capturing was compared with that of pore-expanded MCM-41 [1]. To create larger pores beside the mesoporous structure of MCM-41, carbon black nanoparticles were used as the solid template. Characterizing the BPS-MCM-41 using the BET and BJH techniques resulted in the surface reduction of 29.3 percent and volume increase of 68.46 percent. The pore size distribution showed two peaks: a narrow peak at 2.24 nm diameter, which belonged to micelles, and a wide one at about 50 nm due to the presence of used nanoparticles. The functionalization confirmed that BPS-MCM-41 is capable of accommodating a large quantity of amine groups. The CO₂ adsorption measurement indicated that internal volume of the adsorbent was a critical factor affecting the adsorption capacity of the amine grafted adsorbents.