Modeling of precipitation hardening in Mg-based alloys

This work deals with the development of Mg-based alloys with enhanced properties at elevated temperatures. This is achieved by precipitation of binary phases such as MgZn₂ and Mg₂Sn during the aging of these alloys. The aim of the present work is to develop and calibrate a model for precipitation hardening in Mg-based alloys, as different types of precipitates form simultaneously. The modified Langer-Schwartz approach, while taking into account nucleation, growth and coarsening of the new phase precipitations, was used for the analysis of precipitates’ evolution and precipitation hardening during aging of Mg-based alloys. Two strengthening mechanisms associated with particle-dislocation interaction (shearing and bypassing) were considered to be operating simultaneously due to particle size-distribution. Parameters of the model, R _N i and k _{σ i} , were found by fitting of calculated densities and average sizes of precipitates with ones estimated from experiments. The effective diffusion coefficients of phase formation processes, which determine the strengthening kinetics, were estimated from the hardness maximum positions on the aging curves.     

Robot robust path tracking

A new discontinuous robust control law for a rigid manipulator with bounded parameter uncertainties to track a desired trajectory, is presented. Global exponential stability is proved by the use of a natural Lyapunov function based on a transformation of the manipulator's differential equation due to Slotine and Li [2]. Convergence is to a sliding mode along which the tracking error is reduced at an arbitrary exponential rate. It is also shown how adaptation of bounds on uncertainties, and parameter adaptation, can be incorporated. For a continuous approximation of the discontinuous control law,practical stability (essentially, global uniform ultimate boundedness) of the tracking error is proved. Simulation results for the continuous control law exhibit excellent robust tracking.     

The controlling effect of 0.05% hydrogen sulfide gaseous atmosphere on the accelerated fatigue failure of coated MM-002 nickel-base superalloy at 650 °C

A systematic study was carried out aimed at evaluating the environmental effects of H₂S containing environment on the creep-fatigue failure of coated undirectionally solidified MM-002 nickel-base superalloy at high temperature. The cyclic loading conditions were constant and consisted of creep tension and plastic compression following the CP-mode of the strain range partitioning method. The results obtained have shown that although the pack cementation coating used showed adequate resistance under the combination of cyclic loading and oxidizing environments, this resistance was not evident under the H₂S containing atmosphere. In fact, it was found that even an amount as little as 0.05% H₂S had an extremely detrimental effect on the creep-fatigue life of the coated superalloy at 650 °C. The crack initiation and propagation in the H₂S environment was controlled by an aggressive sulphidation attack ahead of the crack tip. This was demonstrated by the formation of low melting eutectic sulfides at the plastic zone ahead of the crack tip, causing an accelerated transdendritic cracking and premature failure.     

Corrosion fatigue of extruded magnesium alloys

Corrosion fatigue tests were carried out on extruded AZ31 (3% Al, 1% Zn, 0.3% Mn, Mg—the rest), AM50 (5% Al, 0.4% Mn, Mg—the rest) and ZK60 (5% Zn, 0.5% Zr, Mg—the rest) Mg alloys in air, NaCl-based and borate solutions. N_sol/N_air ratios (the relative fatigue life) were used for the analysis of the corrosion fatigue behavior of Mg alloys in various environments, where N_sol and N_air are the numbers of cycles to failure in the solution and in air, respectively. Extruded ZK60 alloy reveals very high fatigue and corrosion fatigue properties in comparison with other alloys. However, it has the lowest relative fatigue life (N_sol/N_air 10⁻³–10⁻²) or the highest sensitivity to the action of NaCl-based solutions in comparison with that of AM50 and AZ31 alloys (N_sol/N_air 10⁻²–10⁻¹). Under the same stress, the corrosion fatigue life of extruded alloys is significantly longer than that of die-cast alloys (N_sol for extruded AM50 in NaCl is two to three times longer than that of die-cast AM50).     

The effect of the methods of preparation on the Mössbauer spectrum of an Fe-Ge intermetallic compound

A comparative study was carried out on the effect of the methods of preparation on the Mössbauer spectrum of the -Fe₅Ge₃ phase. The disagreements between the various reported spectra for the -phase can be attributed to variations in the stochiometry of the final product. Sintering seems to be the best way to prepare the -phase, while melting of the iron-germanium powders resulted in evaporation and considerable loss of germanium. The various methods of preparation were subjected to chemical analysis and X-ray diffraction.