国产CN—31催化剂与ICI65—2催化剂工业应用的比较

国产轻油预转化催化剂与进口催化剂相比,具有性能相当、价格低廉、供应方便等优势。国产预转化催化剂需在较高的液空速、温度较低的条件下实现烃类转化反应,生成含甲烷60%以上的富气。采用国产催化剂能明显反映性能价格比。文章对两种催化剂进行了工业应用比较和分析。     

最佳相位设计的MBE声码器语音合成

提出了一种基于最佳相位设计的语音合成技术,能够有效降低MBE声码器合成语音信号由于波形失衡而导致的饱和失真的概率.此外,为了保证合成滤波器的稳定性,对线谱频率(LSF)系数提取进行了优化.实验结果显示,合成语音信号波形近似平衡地分布在零幅度值的上下,语音听起来没有不舒服的感觉.实验结果表明,基于最佳相位设计的语音合成技术能够有效改善合成语音质量.     

基于PI与 QPR双闭环控制的光伏并网系统控制策略∗

传统的比例积分(PI)控制器在光伏三相逆变器系统中存在无法实现无静差跟踪及谐振抑制效果较差的问题,为提高光伏三相逆变器系统谐振抑制效果及电流控制效果,提出一种基于PI与准比例谐振(QPR)双闭环控制的光伏三相逆变器系统控制策略.设计了基于PI与QPR双闭环控制的控制策略及控制框图,实现入网电流无静差跟踪,具有更好的入网电流波形及谐振抑制效果,提升了系统的稳定性.最后,通过在MATLAB/Simulink平台搭建仿真模型,验证了该控制策略的正确性和有效性.     

Studies on the semirigid chain polyamide—poly(1,4-phenyleneterephthalamide)

In this article, the polycondensation of terephthaloyl chloride and p-phenylenediamine was systematically studied, including the liquid–crystalline state of the solution and the spinning of poly(1,4-phenyleneterephthalamide) (PPTA). High-molecular-weight PPTA with ε_inh = 5–7 was prepared and the main factors influencing the solution polycondensation of 1,4-phenylenediamine with terephthaloyl chloride were studied in detail. Experimental results showed that the water content of the reaction system, reactant concentration, and volume ratio of mix solvents have a great influence on the inherent viscosity of the poly(1,4-phenyleneterephthalamide) obtained. The highest ε_inh was obtained at 0.3M/liter reactant concentration in a mixed solvent ratio HMPA/DMAC of 4/1 (by volume), at 0.35M/liter reactant concentration in a mixed solvent of HMPA/NMP = 7/3, and at 0.5M/liter of reactant concentration in a mixed solvent of HMPA/THF = 9/1. The water content must be controlled to less than 100 ppm in the polymerization system. In the early stage of the polycondensation process, the ε_inh of the polymer obtained increased rapidly with time. The system gelled within 2 or 3 min, while the monomer conversion reached about 100%. However, the reaction of polycondensation continued after gelation and the ε_inh of the polymer increased appreciably. We have studied the viscosity behavior at 20–155°C for the anisotropic solution of PPTA in 100% sulfuric acid (ε_inh of PPTA 2.5–4.9). Experimental results showed that, at low concentrations the viscosity of isotropic solution increases with the increase of polymer concentration to reach a maxium near the critical polymer concentration, beyond which the solution changes to an anisotropic liquid–crystalline solution. The appropriate spinning region was obtained as shown in the phase diagram determined by viscosity, degree of depolarization anisotropy, and region of thermal depolymerization. Fibers of PPTA with high modulus and high tenacity were obtained by dry-jet wet spinning. The fibers obtained have a tenacity of ～22 g/denier, a modulus of ～600 g/denier, and elongation at break ～3.5%.     

一种改进的无锁相环单相谐波电流检测方法

针对目前单相谐波电流检测方法存在的问题,对无锁相环谐波电流检测法进行了详细分析,提出了一种改进的无锁相环单相谐波电流检测方法.采用低通滤波器和均值滤波器串联的形式对原有低通滤波器进行优化,以提高检测精度和动态响应速度;采用基波电流反馈形式,以进一步提高动态响应速度.Matlab/Simulink下的仿真结果表明:所提方法确实可行,大大提高了检测精度和动态响应速度.     

模块化独立光伏储能系统及其控制策略

文中提出的模块化独立光伏系统中各独立的光伏电池基于Boost变换器运行在最大功率输出状态。所有Boost变换器的输出端共直流母线,直流母线作为高频隔离全桥DC-DC并联充电系统的输入端。直流母线的能量通过全桥DC-DC并联充电系统储存于超级电容。为使整个系统运行良好需要满足以下2个条件:其一,每个独立的Boost变换器实现最大功率跟踪控制(MPPT);其二,每个全桥DC-DC均匀分担超级电容的充电电流。由Matlab/Simulink电路仿真结果表明所采用的控制策略很好地实现了光伏电池MPPT控制,以及光伏电池产生的能量能够平稳地传递到超级电容。     

基于有源谐波电导法的光伏逆变器集群谐振抑制策略

为抑制光伏逆变器集群并入电网引起的谐振,提出一种基于有源谐波电导法的光伏逆变器集群谐振抑制策略.首先,基于PI控制器下电容电流内环,电网电流外环的双闭环控制,分析双闭环控制下单台逆变器谐振抑制效果.其次,在保持控制系统不变的情况下,针对多台逆变器谐振问题,在光伏并网系统中加入有源滤波电导,不仅有效抑制逆变器低频谐波电流...     

A fast bit-loading algorithm for high speed power line communications

Adaptive bit-loading is a key technology in high speed power line communications with the Orthogonal Frequency Division Multiplexing (OFDM) modulation technology. According to the real situation of the transmitting power spectrum limited in high speed power line communications, this paper explored the adaptive bit loading algorithm to maximize transmission bit number when transmitting power spectral density and bit error rate are not exceed upper limit. With the characteristics of the power line channel, first of all, it obtains the optimal bit loading algorithm, and then provides the improved algorithm to reduce the computational complexity. Based on the analysis and simulation, it offers a non-iterative bit allocation algorithm, and finally the simulation shows that this new algorithm can greatly reduce the computational complexity, and the actual bit allocation results close to optimal.     

分体式全自冷变压器温升的一种计算方法

分析了变压器的发热和散热机理，介绍了分体式自冷变压器温升的一种计算方法，并给出了计算实例。     

Three‐Component Reactions of 2‐Alkynylbenzaldoximes and α,β‐Unsaturated Carbonyl Compounds with Bromine or Iodine Monochloride

The three‐component reaction of 2‐alkynylbenzaldoximes and α,β‐unsaturated carbonyl compounds with bromine or iodine monochloride is described, which generates the unexpected 2‐(4‐haloisoquinolin‐1‐yl)ethanol derivatives in good to excellent yields.