Effects of Different Retention Parameter Estimation Methods on the Prediction of Surface Runoff Using the SCS Curve Number Method

Quantifying different hydrological components is an initial step for sustainable water resources planning and management. One rising concern is the conflict between the environment, hydropower and agriculture mainly in lowland areas where a large share of the base flows need to be abstracted. The Soil and Water Assessment Tool (SWAT) model was used to understand the hydrological processes of the Upper Awash River Basin with the emphasis on analyzing the different options for surface runoff generation using the Soil Conservation Service (SCS) Curve Number (CN) method. In this study, SWAT was applied incorporating two methods for estimating the retention parameter (S) for the SCS-CN method. The first allowed S to vary with soil profile moisture content (SM method) and the second allowed S to vary with accumulated plant evapotranspiration (PT method). Hydrograph comparison indicated that the PT method was better in simulating peak flows while the SM method was better in simulating the low flows. While the predicted stream flow hydrographs showed an agreement between the two methods, the simulated annual water balance indicated a disagreement in quantifying the different hydrological components. After evapotranspiration, base flow was the dominant component simulated in the SM method whereas surface runoff was the foremost in the PT method simulation. The analysis indicated that care must be taken when selecting an appropriate tool for quantifying hydrologic system to be used for decision making especially for un-gauged catchments where validation of model results is not possible.     

A New Donor–Acceptor–Donor Polyfluorene Copolymer with Balanced Electron and Hole Mobility

A new alternating polyfluorene copolymer poly[2,7‐(9,9‐dioctylfluoren)‐alt‐5,5‐(5′,8′‐di‐2‐thienyl‐(2′,3′‐bis‐(3′′‐octyloxyphenyl)‐quinoxaline))] (APFO‐15), which has electron donor–acceptor–donor units in between the fluorene units, is synthesized and characterized. This polymer has a strong absorption and emission in the visible range of the solar spectrum. Its electroluminescence and photoluminescence emissions extend from about 560 to 900 nm. Moreover, solar cells with efficiencies in excess of 3.5 % have been realized from blends of APFO‐15 and an electron acceptor molecule, a methanofullerene [6,6]‐phenyl‐C₆₁‐butyric acid methyl ester (PCBM). It has also been observed that electron and hole transport is balanced both in the pure polymer phase and in polymer/PCBM bulk heterojunction films, which makes this material quite attractive for applications in opto‐electronic devices.     

New low band gap alternating polyfluorene copolymer-based photovoltaic cells

New low band gap alternating polyfluorene copolymers were synthesized for use in plastic solar cells and their optical, electrochemical, and photovoltaic characteristics were determined. These polymers incorporated fluorene units alternating with groups including electron-withdrawing (A) and electron-donating (D) groups in donor–acceptor–donor (DAD) sequence to achieve the lowering of band gaps. The HOMO–LUMO values were estimated from electrochemical studies. By varying the donor and acceptor strength and position of the solubilizing substituents, similar HOMO values were obtained. These values were also found to correlate well with the open circuit voltage (V_OC) values determined from photovoltaic data of the polymers blended with the acceptor PCBM. Despite similar HOMO values, the absorption spectra of the polymers differ significantly. This prompted the preparation of photovoltaic devices consisting of blends of two polymers with complementary absorptions in combination with PCBM to harvest more photons in the polymer solar cells.     

Enhanced Photocurrent Spectral Response in Low‐Bandgap Polyfluorene and C70‐Derivative‐Based Solar Cells

Plastic solar cells have been fabricated using a low‐bandgap alternating copolymer of fluorene and a donor–acceptor–donor moiety (APFO‐Green1), blended with 3′‐(3,5‐bis‐trifluoromethylphenyl)‐1′‐(4‐nitrophenyl)pyrazolino[70]fullerene (BTPF70) as electron acceptor. The polymer shows optical absorption in two wavelength ranges, λ < 500 nm and 600 < λ < 1000 nm. The BTPF70 absorbs light at λ < 700 nm. A broad photocurrent spectral response in the wavelength range 300 < λ < 1000 nm is obtained in solar cells. A photocurrent density of 3.4 mA cm^–2, open‐circuit voltage of 0.58 V, and power‐conversion efficiency of 0.7 % are achieved under illumination of AM1.5 (1000 W m^–2) from a solar simulator. Synthesis of BTPF70 is presented. Photoluminescence quenching and electrochemical studies are used to discuss photoinduced charge transfer.     

Water Balance Study and Irrigation Strategies for Sustainable Management of a Tropical Ethiopian Lake: A Case Study of Lake Alemaya

Lake Alemaya in the Ethiopian Highlands has historically provided the surrounding area with water for domestic use, irrigation, and livestock and has served as a local fishery tank. Increasing irrigation and domestic water use, change in the local climate and changes in the surrounding land cover are believed to be the causes of Lake Alemaya’s demise. Expansion of major irrigated crops in particular chat (Catha Edulis), potato and vegetables and non-judicious use of irrigation water in the Lake Alemaya watershed led to presumption that irrigation is partly responsible for the withdrawal of large quantity of water from the lake. Thus, water balance study of Lake Alemaya was carried out under presumed scenarios in order to study the possible trends and fluctuations of the lake water level in response to proposed scenarios. Further, it is essential to study the irrigation performance for developing optimal irrigation schedules in the study area to make the best use of available water for long term sustainability of the water resources of Lake Alemaya. It was identified that expansion of the irrigated area in general and chat cultivation in particular in the study area have been the key to sustainable management of lake water, hence its expansion during the past 37 years (1965–2002) was studied through interpretation of satellite data. Subsequently, performance evaluation of the small-scale irrigation practices for major irrigated crops was carried out. Optimal irrigation schedules for different crop seasons were also developed for these irrigated crops using CROPWAT software. It was found that chat area increased from 190 ha in 1996 to nearly 330 ha in 2002. Further, it was observed that 43% surface area of the lake has reduced within a span of 37 years. Overall, maximum irrigation intensity of chat, potato and vegetables is observed during the first irrigation season of the crop calendar. Particularly, in case of chat, irrigation performance indicators such as Relative Water Supply (RWS), Relative Irrigation Supply (RIS), Depleted Fraction (DF) and Overall Consumed Ratio (OCR) values indicated poor performance of irrigation practices. From the analysis, it was found that the application of a fixed irrigation depth and fixed irrigation interval combinations of (25 mm—25 day), (20 mm—20 day), or (20 mm—25 day) are recommended for chat in the study area. Optimal irrigation schedules were decided on the basis of combination of irrigation interval and depth that results in low loss of irrigation water with reasonable yield reduction. Thus, determination of appropriate water management strategy can ensure proper utilization of the available water resources and improve the water application efficiency of the small-scale irrigation practices around Lake Alemaya, Ethiopia.     

Influence of natural and controlled fermentations on α-galactosides, antinutrients and protein digestibility of beans (Phaseolus vulgaris L.)

The influence of natural fermentation (NF) and controlled fermentation (CF) in diminishing the content of antinutrients, α‐galactosides and increments in in vitro protein digestibility was investigated. The dry bean (Phaseolus vulgaris) flour was the substrate used in this research study. A decrease in raffinose oligosaccharide, antinutritional components and pH was observed in both types of fermentation. The natural lactic fermentation of ground beans produced significant increase (P < 0.05) in protein digestibility. For all varieties of beans, raffinose concentration reduced significantly to an undetectable level after 96 h of NF. CF did not have any significant effect on the reduction of the α‐galactosides content of the flours during fermentation. NF is an inexpensive method by which consumers can obtain good‐quality protein. Both types of fermentation diminish antinutrients and improve the nutritional value of the bean flour, and indicate the potential to use bean flour as an ingredient for fabricated foods.     

Selection and characterisation of the predominant Lactobacillus species as a starter culture in the preparation of kocho,fermented food from enset

Food Science and Biotechnology - Enset (Ensete ventricosum (Welw.) Cheesman) (false banana) plant is a multipurpose traditional crop widely cultivated in the south and southwestern Ethiopia. A...     

25th Anniversary Article: Organic Photovoltaic Modules and Biopolymer Supercapacitors for Supply of Renewable Electricity: A Perspective from Africa

The role of materials in civilization is well demonstrated over the centuries and millennia, as materials have come to serve as the classifier of stages of civilization. With the advent of materials science, this relation has become even more pronounced. The pivotal role of advanced materials in industrial economies has not yet been matched by the influence of advanced materials during the transition from agricultural to modern societies. The role of advanced materials in poverty eradication can be very large, in particular if new trajectories of social and economic development become possible. This is the topic of this essay, different in format from the traditional scientific review, as we try to encompass not only two infant technologies of solar energy conversion and storage by means of organic materials, but also the social conditions for introduction of the technologies. The development of organic‐based photovoltaic energy conversion has been rapid, and promises to deliver new alternatives to well‐established silicon photovoltaics. Our recent development of organic biopolymer composite electrodes opens avenues towards the use of renewable materials in the construction of wooden batteries or supercapacitors for charge storage. Combining these new elements may give different conditions for introduction of energy technology in areas now lacking electrical grids, but having sufficient solar energy inputs. These areas are found close to the equator, and include some of the poorest regions on earth.     

Electrochromic, magnetotransport and AC transport properties of vapor phase polymerized PEDOT (VPP PEDOT)

Poly(3,4-ethylenedioxy)thiophene (PEDOT) doped with tosylate ion (PEDOT–tosylate or VPP PEDOT) was synthesized by vapor phase polymerization (VPP) technique on glass as well as on glass/ITO and the electrochromic properties were investigated. Compared with that of PEDOT–PSS spin-coated on glass/ITO, the studies showed that VPP PEDOT has a lower work function and better electrochromic properties. The magneto and AC transport properties studies were done on VPP PEDOT coated on glass substrate. The system shows 2-dimensional variable range hopping and wave function shrinkage of charge carriers.