Photocatalytic degradation of methyl tert‐butyl ether (MTBE) in contaminated water by ZnO nanoparticles

BACKGROUND: Over the past several decades methyl tert‐butyl ether (MTBE) as additive to gasoline, intended to either boost ratings of fuel or to reduce air pollution, has been accepted worldwide. Since MTBE has high water solubility, the occurrence of fuel spills or leaks from underground storage tanks or transferring pipeline has led to the contamination of natural waters. In this study the degradation of aqueous MTBE at relatively high concentrations was investigated by a UV‐visible/ZnO/H₂O₂ photocatalytic process. The effects of important operational parameters such as pH, amount of H₂O₂, catalyst loading and irradiation time were also investigated. Concentration of MTBE and intermediates such as tert‐butyl formate and tert‐butyl alcohol were measured. RESULTS: Time required for complete degradation increased from 20 to 150 min when the initial concentration was increased from 10 to 500 mg L^?1. The first‐order rate constants for degradation of MTBE were estimated to be 0.183–0.022 min^?1 as the concentration increased from 10 to 500 mg L^?1. Study of the overall mineralization monitored by total organic carbon analysis showed that at an initial concentration of 100 mg L^?1 MTBE complete mineralization was obtained after 100 min under UV‐visible/ZnO/H₂O₂ photocatalysis. CONCLUSION: The data presented in this paper clearly indicated that UV‐visible/ZnO/O₂ as an advanced oxidation process provides an efficient treatment alternative for the remediation of MTBE‐contaminated waters. Copyright © 2008 Society of Chemical Industry     

Multi-criteria Decision-making Approach for Environmental Impact Assessment to Reduce the Adverse Effects Of Dams

Water Resources Management - Environmental Impact Assessments (EIAs) of development projects are necessary to minimize negative impacts and maximize benefits. The objective of this paper is to...     

Polynomial-Time Approximation Schemes for Subset-Connectivity Problems in Bounded-Genus Graphs

We present the first polynomial-time approximation schemes (PTASes) for the following subset-connectivity problems in edge-weighted graphs of bounded-genus: Steiner tree, low-connectivity survivable-network design, and subset TSP. The schemes run in $\mathcal{O}(n \log n)$ time for graphs embedded on both orientable and nonorientable surfaces. This work generalizes the PTAS framework from planar graphs to bounded-genus graphs: any problem that is shown to be approximable by the planar PTAS framework of Borradaile et al. (ACM Trans. Algorithms 5(3), 2009) will also be approximable in bounded-genus graphs by our extension.     

The Shape Boltzmann Machine: A Strong Model of Object Shape

A good model of object shape is essential in applications such as segmentation, detection, inpainting and graphics. For example, when performing segmentation, local constraints on the shapes can help where object boundaries are noisy or unclear, and global constraints can resolve ambiguities where background clutter looks similar to parts of the objects. In general, the stronger the model of shape, the more performance is improved. In this paper, we use a type of deep Boltzmann machine (Salakhutdinov and Hinton, International Conference on Artificial Intelligence and Statistics, 2009) that we call a Shape Boltzmann Machine (SBM) for the task of modeling foreground/background (binary) and parts-based (categorical) shape images. We show that the SBM characterizes a strong model of shape, in that samples from the model look realistic and it can generalize to generate samples that differ from training examples. We find that the SBM learns distributions that are qualitatively and quantitatively better than existing models for this task.     

Geometry and topology optimization of geodesic domes using charged system search

Dome structures provide cost-effective solutions for covering large areas without intermediate supports. In this article, simple procedures are developed to reach the configuration of the geodesic domes. A new definition of dome optimization problems is given which consists of finding optimal sections for elements (size optimization), optimal height for the crown (geometry optimization) and the optimum number of elements (topology optimization) under determined loading conditions. In order to find the optimum design, the recently developed meta-heuristic algorithm, known as the Charged System Search (CSS), is applied to the optimum design of geodesic domes. The CSS takes into account the nonlinear response of the domes. Using CSS, the optimum design of the geodesic domes is efficiently performed.     

A new homotopy perturbation method for solving systems of partial differential equations

In this paper, a new homotopy perturbation method (NHPM) is introduced for obtaining solutions of systems of non-linear partial differential equations. Theoretical considerations are discussed. To illustrate the capability and reliability of the method three examples are provided. Comparison of the results of applying NHPM with those of applying HPM reveal the effectiveness and convenience of the new technique.     

Effect of galvanic contact on the flotability of galena in the presence and absence of a collector

In this paper, the effect of various electrochemical environments in the galena flotation is investigated. The electrochemical environments consisted of a ball mill for grinding of galena ore and a Denver flotation cell for flotation of galena in the laboratory scale. In order to achieve the maximum recovery with sodium hyposulfite, the concentrations of 0.06 and 0.12 M of air and nitrogen gases have been used to control the pulp potential in the Denver flotation cell. The galena sample was from the “Era mine” which is located in the Kiyasar area, north of Iran. This mine contains: Galena (PbS) at least 22%, Fluorite (CaF₂) 73.37%, Quartz (SiO₂) 2.54% and other minerals such as Cerussite (PbCO₃) and Kaolinite (Al₂Si₂O₅(OH)₄). Flotation of Galena was conducted in a 0.12 M of sodium hyposulfite solution. It was found that the amount of recovery by this process was 85% and 63% in the presence and absence of potassium amyl xanthate (KAX) and at an estimated potential of 280 to 350 mV respectively while the recovery was 70% and 52% at an approximate potential of 175 to 210 mV in water in the presence and absence of collector (KAX).     

Heat transfer in a turbulent jet impinging on a moving plate considering high plate-to-jet velocity ratios

In this paper, heat transfer characteristics of a turbulent slot jet impinging orthogonally on an isothermal moving hot plate is studied numerically. The governing equations were discretized using the finite volume method and the υ ² — f turbulence model was employed for turbulence modeling. The effect of the jet Reynolds number and the plate-to-jet velocity ratio (R) on the Nusselt were investigated. Despite of most previous studies, which have been restricted to R≤2, in the present research higher values of R, also were considered (0≤R≤6). Range of studied jet Reynolds number was between 3000 and 60000. The results indicate that at a fixed plate-to-jet velocity ratio increment of the Reynolds number leads to the enhancement of the average Nusselt number. For each Reynolds number, the average Nusselt number reduces with increasing the plate-to-jet velocity ratio until it becomes minimum at R = 1.25. For R>1.25 trend changes so that these parameters increase. In addition, it was found that only for R>2.5 the average Nusselt number is improved due to the plate motion in comparison with the stationary jet. The results are validated against available experimental data, showing good agreement.     

An Analytical Equation of State for Alkaline Earth Metals

In this work, an analytical equation of state based on statistical mechanical perturbation theory, which was initially developed for normal fluids and can be applied to predict the P–V–T data for saturated liquid alkaline earth metals, is presented. The equation of state is that of Ihm, Song, and Mason, and the temperature-dependent parameters of the equation of state are calculated from a corresponding-states correlation as functions of the reduced temperature. Two scaling constants are sufficient for this purpose, the surface tension and the liquid density at the melting point. The equation of state is used to predict the saturated liquid density of molten alkaline earth metals from the melting point up to 2000 K, for which experimental data exist, within an accuracy of 5%.