Biohydrogen Production from Organic Waste – A Review

Hydrogen fuel is a promising alternative to fossil fuels because of its energy content, clean nature, and fuel efficiency. However, it is not readily available. Most current producion processes are very energy intensive and emit carbon dioxide. Therefore, this article reviews technological options for hydrogen production that are eco-friendly and generate clean hydrogen fuel. Biological methods, such different fermentation processes and photolysis are discussed together with the required substrates and the process efficiency.     

Electrocatalytic Reduction of CO2 to Ethylene by Molecular Cu‐Complex Immobilized on Graphitized Mesoporous Carbon

The electrochemical reduction of carbon dioxide (CO₂) to hydrocarbons is a challenging task because of the issues in controlling the efficiency and selectivity of the products. Among the various transition metals, copper has attracted attention as it yields more reduced and C2 products even while using mononuclear copper center as catalysts. In addition, it is found that reversible formation of copper nanoparticle acts as the real catalytically active site for the conversion of CO₂ to reduced products. Here, it is demonstrated that the dinuclear molecular copper complex immobilized over graphitized mesoporous carbon can act as catalysts for the conversion of CO₂ to hydrocarbons (methane and ethylene) up to 60%. Interestingly, high selectivity toward C2 product (40% faradaic efficiency) is achieved by a molecular complex based hybrid material from CO₂ in 0.1 m KCl. In addition, the role of local pH, porous structure, and carbon support in limiting the mass transport to achieve the highly reduced products is demonstrated. Although the spectroscopic analysis of the catalysts exhibits molecular nature of the complex after 2 h bulk electrolysis, morphological study reveals that the newly generated copper cluster is the real active site during the catalytic reactions.     

Microstructural developments in Mg-Ti-PSZ systems

The microstructure of titania-added Mg-partially-stabilized zirconia (PSZ) is dramatically influenced by thermal treatments. Effects of various sintering, heat-treatment and thermal shock cycling parameters on the microstructure of the Mg-Ti-PSZ system are described. Conditions favourable for the growth of needle-like Ti-rich reinforcements in highly thermalshock-resistant Mg-Ti-PSZ ceramics are identified. TiO₂ seems to play a catalytic role in the formation of Zr-rich networks during high-temperature (1700°C) sintering of the Mg-Ti-PSZ system, quite similar to those found in Mg-PSZ, heat-treated above 1300 °C.     

Photo-Chemically-Deposited and Industrial Cu/ZnO/Al2O3 Catalyst Material Surface Structures During CO2 Hydrogenation to Methanol: EXAFS,XANES and XPS Analyses of Phases After Oxidation,Reduction, and Reaction

Catalysis Letters - Industrial Cu/ZnO/Al2O3 or novel rate catalysts, prepared with a photochemical deposition method, were studied under functional CH3OH synthesis conditions at the set temperature...     

Curcumin Prevents Cerebellar Hypoplasia and Restores the Behavior in Hyperbilirubinemic Gunn Rat by a Pleiotropic Effect on the Molecular Effectors of Brain Damage

Bilirubin toxicity to the central nervous system (CNS) is responsible for severe and permanent neurologic damage, resulting in hearing loss, cognitive, and movement impairment. Timely and effective management of severe neonatal hyperbilirubinemia by phototherapy or exchange transfusion is crucial for avoiding permanent neurological consequences, but these therapies are not always possible, particularly in low-income countries. To explore alternative options, we investigated a pharmaceutical approach focused on protecting the CNS from pigment toxicity, independently from serum bilirubin level. To this goal, we tested the ability of curcumin, a nutraceutical already used with relevant results in animal models as well as in clinics in other diseases, in the Gunn rat, the spontaneous model of neonatal hyperbilirubinemia. Curcumin treatment fully abolished the landmark cerebellar hypoplasia of Gunn rat, restoring the histological features, and reverting the behavioral abnormalities present in the hyperbilirubinemic rat. The protection was mediated by a multi-target action on the main bilirubin-induced pathological mechanism ongoing CNS damage (inflammation, redox imbalance, and glutamate neurotoxicity). If confirmed by independent studies, the result suggests the potential of curcumin as an alternative/complementary approach to bilirubin-induced brain damage in the clinical scenario.     

Influence of Montmorillonite Clay Content on Thermal,Mechanical, Water Absorption and Biodegradability Properties of Treated Kenaf Fiber/ PLA-Hybrid Biocomposites

Silicon - Nowadays, the starring attentions of the polylactic acid based composites are improved due to environmental awareness and diminution of petroleum oil. The bio-plastics were restricted to...     

Membrane degumming of crude rice bran oil: Pilot plant study

The procedure for the classical chemical refining of vegetable oils consists of degumming, alkali neutralization, bleaching, and deodorization. Conventional refining of rice bran oil using alkali gives oil of acceptable quality, but the refining losses are very high. A critical work has been carried out to study the application of membrane technology in the pretreatment of crude rice bran oil. Oils intended for physical refining should have a low phosphorus content, and this is not readily achievable by the conventional acid/water degumming process. The application of membrane technology for the pretreatment of rice bran oil has been investigated. The process has already been successfully applied to other vegetable oils. Ceramic membranes, which are important from the commercial point of view, were examined for this purpose. The results showed that the membrane‐filtered oils met the requirements of physical refining, with a substantial reduction in color. It was observed that most of the waxy material was also rejected. Experiments were carried out to establish the relationship between permeate flux and rejection with membrane pore size, trans‐membrane pressure and micellar solute concentration.     

A reduced reaction model for carbon CVD/CVI processes

Carbon-carbon composites are produced by chemical vapor deposition/chemical vapor infiltration (CVD/CVI) processes. Models of carbon-carbon composite production processes will help reduce production costs. Reliable process models must, however, include details of the gas phase kinetics in order to identify optimal conditions. We have combined detailed gas phase kinetics, surface kinetics, and a pore closure model to predict pore geometry changes with respect to time. To determine the dominant gas phase kinetics, we reduced a large set of reactions to a minimal set using a sensitivity, rate, and dimensional analysis approach. These robust and relatively fast techniques can be used under a variety of conditions, including those within the pores of the composite. The process model shows that the deposition profile depends on the kinetic model chosen. Using the more realistic reaction model, conditions for uniform, or inside-out, densification can be suggested.     

Correlating the 3D melt electrospun polycaprolactone fiber diameter and process parameters using neural networks

In the present work, we developed an artificial neural networks (ANN) model to predict and analyze the polycaprolactone fiber diameter as a function of 3D melt electrospinning process parameters. A total of 35 datasets having various combinations of electrospinning writing process variables (collector speed, tip to nozzle distance, applied pressure, and voltage) and resultant fiber diameter were considered for model development. The designed stand-alone ANN software extracts relationships between the process variables and fiber diameter in a 3D melt electrospinning system. The developed model could predict the fiber diameter with reasonable accuracy for both train (28) and test (7) datasets. The relative index of importance revealed the significance of process variables on the fiber diameter. Virtual melt spinning system with the mean values of the process variables identifies the quantitative relationship between the fiber diameter and process variables.     

Memory leak detection in Plumbr

Platforms with automatic memory management, such as the JVM, are usually considered free of memory leaks. However, memory leaks can happen in such environments, as the garbage collector cannot free objects, which are not used by the application anymore, but are still referenced. Such unused objects can eventually fill up the heap and crash the application. Although this problem has been studied extensively, nevertheless, there are still many rooms for improvement in this area. This paper describes the statistical approach for memory leak detection, as an alternative, along with a commercial tool, Plumbr, which is based on the method. The tool is later analyzed with three case studies of real applications and in the process also analyzes strengths and weaknesses of the statistical approach for memory leak detection. Copyright © 2014 John Wiley & Sons, Ltd.