High char‐yielding poly[acrylonitrile‐co‐(itaconic acid)‐co‐(methyl acrylate)]: synthesis and properties

Polyacrylonitrile terpolymers of various compositions consisting of acrylonitrile (AN), itaconic acid (IA) and methyl acrylate (MA) were synthesized by solution polymerization in dimethylsulfoxide. Increase in concentration of either IA or MA retarded the overall polymerization rate and the polymer molecular weight. The system consisting of AN + MA and varying IA concentration was more prone to retardation in comparison with the system composed of AN + IA with variable MA concentration. The retardation factors were quantified. Minor quantities of MA boost the reactivity of IA in the terpolymer system. The terpolymer was richer in MA vis‐à‐vis the feed. The thermal characteristics of the terpolymer were examined as a function of its composition. In contrast to the copolymer of AN and IA requiring 1–1.5 mol% IA, the terpolymer required an IA content of approximately 2.5 mol% for optimum thermal stability. The polymer with 90 mol% AN, 2.5 mol% IA and 7.5 mol% MA exhibited reasonably good char‐forming characteristics and thermal stability. The overall crystallinity and crystallite size of the polymers were found to decrease on incorporation of the comonomers. The ‘aromatization index’ of the copolymer increased with the temperature of pyrolysis through re‐organization of the tetrahydropyridine ladder structure. Copyright © 2005 Society of Chemical Industry     

Residual aluminium in water defluoridated using activated alumina adsorption - Modeling and simulation studies

The removal of fluoride from drinking water by the method of adsorption on activated alumina is found superior than other defluoridation techniques mostly due to the strong affinity between aluminium and fluoride. Dissolution of aluminium from the alumina surfaces into its free and hydroxide ions in the aqueous medium is reported to be very low, but the presence of high fluoride concentrations may increase its solubility due to the formation of monomeric aluminium fluoride and aluminium hydroxyl fluoride complexes. An Activated Alumina Defluoridation Model Simulator (AAD) has been developed to represent fluoride adsorption on the basis of the surface complexation theory incorporating aspects of aluminium solubility in presence of high fluoride concentrations and pH variations. Model validations were carried out for residual aluminium concentrations in alumina treated water, by conducting a series of batch fluoride adsorption experiments using activated alumina (grade FB101) treating fluoride concentrations of 1-10 mg/L, at varying pH conditions. The total residual aluminium in the defluoridated water is due to presence of both dissolved and precipitated Al-F complexed forms. The Freundlich adsorption isotherm was found fit for fluoride adsorption capacity versus residual fluoride concentrations for pH = 7.5, and the relationship is given by the linearised equation log (x/m) = log k + (1/n) log C_e with values of k = 0.15 mg/g and 1/n = 0.45 indicating favorable adsorption. The relationship is linear in the region of low fluoride concentrations, but as concentrations of fluoride increased, the formation of the dissolved AlF₃⁰ complexes was favored than adsorption on alumina, and hence makes the isotherm nonlinear. The AAD simulations can predict for operating fluoride uptake capacity in order to keep the residual aluminium within permissible limits in the alumina treated water.     

Photocatalytic degradation of pesticide contaminants in water

Photocatalysis has been proved to be an effective and inexpensive tool for the removal of organic and inorganic pollutants from water. Of particular interest in this context, in recent years, has been the complete photocatalytic mineralisation of a variety of pesticides into harmless products. The technique is now reaching the pre-industrial level, with several pilot plants and prototypes being operational in various countries. This paper reviews the major developments in the area, with special reference to the mechanism of the process involved, nature of the reactive intermediates and final products.     

Surface energy and separation mechanics of droplet interface phospholipid bilayers

Droplet interface bilayers are a convenient model system to study the physio-chemical properties of phospholipid bilayers, the major component of the cell membrane. The mechanical response of these bilayers to various external mechanical stimuli is an active area of research because of its implications for cellular viability and the development of artificial cells. In this article, we characterize the separation mechanics of droplet interface bilayers under step strain using a combination of experiments and numerical modelling. Initially, we show that the bilayer surface energy can be obtained using principles of energy conservation. Subsequently, we subject the system to a step strain by separating the drops in a step-wise manner, and track the evolution of the bilayer contact angle and radius. The relaxation time of the bilayer contact angle and radius along with the decay magnitude of the bilayer radius were observed to increase with each separation step. By analysing the forces acting on the bilayer and the rate of separation, we show that the bilayer separates primarily through the peeling process with the dominant resistance to separation coming from viscous dissipation associated with corner flows. Finally, we explain the intrinsic features of the observed bilayer separation by means of a mathematical model comprising the Young–Laplace equation and an evolution equation. We believe that the reported experimental and numerical results extend the scientific understanding of lipid bilayer mechanics, and that the developed experimental and numerical tools offer a convenient platform to study the mechanics of other types of bilayers.     

Liquid phase benzoylation of arenes over iron promoted sulphated zirconia

The present work undertakes the preparation and physico-chemical characterisation of iron promoted sulphated zirconia (SZ) with different amounts of iron loading and their application to Friedel–Crafts benzoylation of benzene, toluene and xylene under different experimental conditions. XRD and laser Raman techniques reveal the stabilisation of the tetragonal phase of zirconia and the existence of iron in highly dispersed form as Fe₂O₃ on the catalyst surface. The surface acidic properties were determined by ammonia temperature programmed desorption (TPD) and perylene adsorption. The results were supported by the TGA studies after adsorption of pyridine and 2,6-dimethylpyridine (2,6-DMP). Strong Lewis acid sites on the surface, which are evident from TPD and perylene adsorption studies, explain the high catalytic activity of the systems towards benzoylation. The experimental results provide evidence for the truly heterogeneous nature of the reaction. The studies also establish the resistance to deactivation in the metal incorporated sulphated systems.     

Solar photocatalytic decolorization of synthetic dye solution using pilot scale slurry type falling film reactor

Ag deposited TiO₂ was prepared by simple chemical reduction method and its photocatalytic efficiency was evaluated for the decolorization of methylene blue dye using pilot scale slurry type falling film reactors (FFR) under sunlight. The characterization of the prepared catalysts by XRD, TEM, EDAX, DRS and PL confirmed that silver, which acts as electron trap, was deposited over the TiO₂ surface. The operational parameters, such as catalyst loading, concentration of the dye solution, pH of the slurry, addition of oxidizing agents and effect of different substrates, were optimized. The photocatalytic efficiency of Ag deposited TiO₂ increased two-fold times than pure TiO₂ and the maximum decolorization of dye was observed under acidic conditions. The reaction rate significantly increased with the addition of oxidizing agent H₂O₂. The ceramic tile as well as double skin reactor have higher photocatalytic efficiency than glass as substrate. In addition, Ag-deposited TiO₂ photocatalyst could be easily recovered by simple sedimentation process and reused for repeated experimental cycles with more than 95% decolorization efficiency.     

In vitro evaluation of bioactive strontium-based ceramic with rabbit adipose-derived stem cells for bone tissue regeneration

The development of bone replacement materials is an important objective in the field of orthopaedic surgery. Due to the drawbacks of treating bone defects with autografts, synthetic bone graft materials have become optional. So in this work, a bone tissue engineering approach with radiopaque bioactive strontium incorporated calcium phosphate was proposed for the preliminary cytocompatibility studies for bone substitutes. Accumulating evidence indicates that strontium containing biomaterials promote enhanced bone repair and radiopacity for easy imaging. Hence, strontium calcium phosphate (SrCaPO₄) and hydroxyapatite scaffolds have been investigated for its ability to support and sustain the growth of rabbit adipose-derived mesenchymal stem cells (RADMSCs) in vitro. They were characterized via Micro-CT for pore size distribution. Cells used were isolated from New Zealand White rabbit adipose tissue, characterized by FACS and via differentiation into the osteogenic lineage by alkaline phosphatase, Masson’s trichome, Alizarin Red and von Kossa staining on day 28. Material-cell interaction was observed by SEM imaging of cell morphology on contact with material. Live–Dead analysis was done by confocal laser scanning microscopy and cell cluster analysis via μCT. The in vitro biodegradation, elution and nucleation of apatite formation of the material was evaluated using simulated body fluid and phosphate buffered saline in static regime up to 28 days at 37 °C. These results demonstrated that SrCaPO₄ is a good candidate for bone tissue engineering applications and with osteogenically-induced RADMSCs, they may serve as potential implants for the repair of critical-sized bone defects.     

Geometric Representation of Graphs in Low Dimension Using Axis Parallel Boxes

An axis-parallel k-dimensional box is a Cartesian product R ₁×R ₂×???×R _k where R _i (for 1≤i≤k) is a closed interval of the form [a _i ,b _i ] on the real line. For a graph G, its boxicity box?(G) is the minimum dimension k, such that G is representable as the intersection graph of (axis-parallel) boxes in k-dimensional space. The concept of boxicity finds applications in various areas such as ecology, operations research etc. A number of NP-hard problems are either polynomial time solvable or have much better approximation ratio on low boxicity graphs. For example, the max-clique problem is polynomial time solvable on bounded boxicity graphs and the maximum independent set problem for boxicity d graphs, given a box representation, has a $\lfloor 1+\frac{1}{c}\log n\rfloor^{d-1}An axis-parallel k-dimensional box is a Cartesian product R ₁×R ₂×⋅⋅⋅×R _k where R _i (for 1≤i≤k) is a closed interval of the form [a _i ,b _i ] on the real line. For a graph G, its boxicity box (G) is the minimum dimension k, such that G is representable as the intersection graph of (axis-parallel) boxes in k-dimensional space. The concept of boxicity finds applications in various areas such as ecology, operations research etc. A number of NP-hard problems are either polynomial time solvable or have much better approximation ratio on low boxicity graphs. For example, the max-clique problem is polynomial time solvable on bounded boxicity graphs and the maximum independent set problem for boxicity d graphs, given a box representation, has a ?1+\frac1clogn?^d-1\lfloor 1+\frac{1}{c}\log n\rfloor^{d-1} approximation ratio for any constant c≥1 when d≥2. In most cases, the first step usually is computing a low dimensional box representation of the given graph. Deciding whether the boxicity of a graph is at most 2 itself is NP-hard.