Densification and Properties of α-Silicon Carbide

Densification of a-Sic powders with no premixed sintering aids (type 1) and with premixed B and C (type 2) was investigated by sintering them at 2150° to 2200°C for 30 min. Flexure strengths, Weibull moduli, and fracture flaws were characterized for type 2 α-SiC only. The results were compared with those for a state-of-the-art sintered a-Sic material.     

Studies on the synthesis of SAPO-5

Silicoaluminophosphate (SAPO-5) molecular sieves have been synthesised from reaction mixtures having a molar composition of: 0.7–1.0 Al₂O₃:0.7–1.0 P₂O₅:0.01–2.0 SiO₂:xR:40 H₂O (where R = (C₂H₃)₃N or (C₂H₃)₄NOH and x = 1.5–2.5 for (C₂H₅)⁵N and 0.5 for (C₂H₅)₄NOH, at 473 K using various sources of alumina and silica. The effects of (i) varying the crystallinity of the alumina source (boehmite) and (ii) the use of different silica sources such as freshly prepared silica either from sodium silicate or paddy husk extract, silica gel from commercial water-glass, and tetraethyl orthosilicate have been studied. The crystallinity of boehmite has been found to have a strong effect on its reactivity towards the formation of SAPO-5. The activity of boehmite for SAPO-5 formation increased with a decrease in its crystallinity (or with increase in its moisture content). Any silica source devoid of sodium ions could be employed for the synthesis of SAPO-5. The process of crystallisation started as early as within 1.5 h of reaction and incorporation of silicon into the AlPO₄ framework has been noted at this stage. Formation of some tridymite phase as impurity has been observed under conditions such as (i) SiO₂ concentration > 1.7 mole and (ii) x > 2.0 when R = (C²H₅)₃N.     

A comparative study of short nylon fiber—Natural rubber composites prepared from dry rubber and latex masterbatch

A novel method for the preparation of short nylon fiber–natural rubber composites was developed in which short fibers chopped to approximately 6 mm were incorporated in the latex stage and processed into sheet form. By this method, mixing cycle time was reduced without compromising the fiber dispersion. Fiber breakage during mixing was reduced. The new composites when compounded with a dry bonding system based on hexamethylenetetramine, resorcinol and hydrated silica (HRH) showed improved modulus, tensile strength and abrasion resistance compared to conventional composites. Tear strength, resilience, and compression set were similar to the conventional composites. SEM analysis indicated better interaction between matrix and fibers in the case of latex master batch. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008     

Polyamide-6,6/in situ silica hybrid nanocomposites by sol-gel technique: synthesis, characterization and properties

The organic-inorganic hybrid nanocomposites comprising of poly(iminohexamethyleneiminoadipoyl), better known as Polyamide-6,6 (abbreviated henceforth as PA66), and silica (SiO₂) were synthesized through sol-gel technique at ambient temperature. The inorganic phase was generated in situ by hydrolysis-condensation of tetraethoxysilane (TEOS) in different concentrations, under acid catalysis, in presence of the organic phase, PA66, dissolved in formic acid. Infrared (IR) spectroscopy was used to monitor the microstructural evolution of the silica phase in the PA66 matrix. Wide angle X-ray scattering (WAXS) studies showed that the crystallinity in PA66 phase decreased with increasing silica content. Atomic force microscopy (AFM) of the nanocomposite films revealed the dispersion of SiO₂ particle with dimensions of <100 nm in the form of network as well as linear structure. X-ray silicon mapping further confirmed the homogeneous dispersion of the silica phase in the bulk of the organic phase. The melting peak temperatures slightly decreased compared to neat PA66, while an improvement in thermal stability by about 20 °C was achieved with hybrid nanocomposite films, as indicated by thermogravimetric analysis (TGA). Dynamic mechanical analysis (DMA) exhibited significant improvement in storage modulus (E′) for the hybrid nanocomposites over the control specimen. An increase in Young's modulus and tensile strength of the hybrid films was also observed with an increase in silica content, indicating significant reinforcement of the matrix in the presence of nanoparticles. Some properties of the in situ prepared PA66-silica nanocomposites were compared with those of conventional composites prepared using precipitated silica as the filler by solution casting from formic acid.     

A Comparative Investigation of Optical and Structural Properties of Cu-Doped CdO-Derived Nanostructures

In this report, we studied various structural and optical properties of pure and copper-doped cadmium oxide (CdO) thin films. Nanostructured Cu-doped CdO films were deposited using sol–gel spin-coating technique. The structural and morphological changes have been observed by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and atomic force microscopy (AFM) studies. The optical and electrical properties of the pure and Cu-doped CdO thin films were studied by UV–vis spectroscopy and four-point probe method, respectively. The XRD peaks show the formation of nanocrystalline CdO with cubic face-centered crystal structure. The band gaps of the as deposited films were found in the range of 2.32–2.73 eV, while after doping, it decreases due to structural deformation. The electrical resitivity was found to decrease approximately ～10 in Cu-doped CdO thin films.     

Asymmetrically loaded annular ring antenna

A numerical model for resonant frequency using asymmetric loading is presented using cavity model. In asymmetric loaded antenna, the posts are not equispaced on annular ring antenna and resonant frequency is independent of the angular location of posts. The posts are located away from the centre of patch. The diameter of post is thin as compared to the diameter of annular ring antenna. The first few dominant modes calculated for asymmetric loading are compared to symmetric loading where the posts are to be located at specific angular locations. The theoretical model is compared to the simulated results of IE3D based on Method of Moments. The numerical model developed can also be verified further by the full wave analysis.     

Impact of Variable Packet Length on the Performance of Heterogeneous Multimedia Wireless Sensor Networks

Wireless Personal Communications - Performance valuation of wireless sensor network (WSN) routing protocols calls for realistic data traffic models because of their application specific nature....     

SHELF-LIFE MODELING OF SWEETENED CONDENSED MILK BASED ON KINETICS OF MAILLARD BROWNING

Nonenzymatic browning and related changes were monitored in commercial sweetened condensed milk stored at 7, 15, 30, 45 and 55C. Darkening of the color measured in terms of absorbance (100 - reflectance percent) followed zero-order kinetics, the apparent activation energy (E_a) being 45.2 kJ/mol at 7–30C and 139.9 kJ/mol at > 30–55C. Hydroxy-methyl-furfural (HMF) showed a first-order increase, the associated E_a values being smaller than those for absorbance. The pH exhibited a linear decline after a small initial rise at 30C and below. As browning progressed, the coffee whitening ability of the product decreased along zero-order kinetics. The Q₁₀ values for these variables ranged from 1.21 to 1.84 for temperatures up to 30C and were nearly 2–3 times higher above 30C. The sensory color score was negatively correlated with absorbance. The linear regression of color score on absorbance and the temperature dependence of the latter as expressed by Arrhenius relationship were combined into a mathematical model which could be useful in predicting the product's shelf-life.     

Mobile information services enabled by mobile publishing (MIS-MP)

Mobile users and devices want to discover and share a growing range of information as the processing and storage capabilities of mobile devices grow. For example, users want to discover nearby networks, and location-based or time-sensitive user information contents. A mobile device may want to discover neighboring networks and the parameters required to access these networks so that it can intelligently decide which networks to use next, and use its existing network connection to authenticate with selected neighboring networks before it moves into the coverage areas of the selected networks. This can significantly reduce handoff delays. Existing service discovery frameworks are not effective for such neighboring network discovery or for discovering dynamic, location- or time-sensitive user information contents. This paper describes and evaluates a new approach—Mobile Information Services enabled by Mobile Publishing (MIS-MP)—for real time collection, discovery, and sharing of network and user information. With MIS-MP, mobiles take full advantage of the wealth of information they can accumulate during their routine mobility and use of networks to help each other to discover the information they want when and where they want it. This is accomplished by mobiles publishing the information they collect about the networks they visited, and the user information contents they learned or used, to make the information available to other mobiles. This paper presents analytical models and simulation results to evaluate the feasibility and performance of MIS-MP. It also describes a testbed implementation of MIS-MP and some of the lessons we learned. Tao Zhang is Director of Mobile Networking Research Group at Telcordia Technologies, Piscataway, New Jersey, USA. He develops and directs research and advanced development programs in mobile networking and applications, including mobility and applications across heterogeneous radio networks, mobile information services, vehicular networking, mobile peer-to-peer applications, sensor networking and applications, and collaborative networking .Dr. Zhang’s work has led to several new commercial products. He co-authored the book “IP-Based Next Generation Wireless Networks” published by John Wiley & Sons in 2004. He initiated the International Conference on Collaborative Computing: Networking, Applications, and Worksharing (CollaborateCom), and has been serving in various roles for it. Dr. Zhang holds 4 U.S. patents, with over 25 more pending. He received the 2000 Telcordia CEO Award (for most exceptional teams and individuals who have achieved a significant business success) and 2002 SAIC’s Executive Science and Technology Council Publication Prize. Eric van den Berg received his Ph.D. in Applied Mathematics from Cornell University in 1999. After obtaining his degree, he joined Telcordia Technologies, where he is a Research Scientist in Applied Research Department. His research interests include traffic modeling and performance analysis of IP- and wireless networks. He received the 2000 Telcordia CEO Award (for most exceptional individuals and teams who have achieved a significant business success) and the 2002 SAIC Executive Science and Technology Council Publication Prize. Sunil Madhani is a Distinguished MTS with Motorola where he manages the IP Realization team in Mobile Device Technology Office. He aims at working on unconventional and disruptive IP technologies. His current research focus is on convergent networks, dynamic mobility management and fast handoff in secured/seamless wireless LAN/WAN roaming. His past research includes registration/configuration protocols in wireless environment, application layer mobility management, secured Mobile IP, managed DOS attack sensor and TCP/IP boosters. Sunil Madhani holds MS (2002) in Engineering Management & System from Columbia University and MS (1997) in Computer Science from State University of New York.