Oxidation of some aliphatic polyols on anodically deposited MnO2

Galvanostatic steady state current potential measurements were carried out for oxidation of a series of aliphatic alcohols having varying number of hydroxyl groups. The anodically deposited layer of MnO₂ on platinum was used as the electrode material. The deposit was characterised by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX) and electrode potential measurements. The catalytic role of MnO₂ in the electro-oxidation of alcohols was indicated by the chronopotentiograms and the cyclic voltammograms. An analysis of the electrochemical data indicated a catalytic EC mechanism in which Mn (V) is generated electrochemically and consumed chemically in succession. Based on this and the hydrogen bonding interaction between alcoholic hydroxyl groups and MnO₂ layer, a mechanism was proposed which accounts for the variation in the observed electrochemical reaction orders. Tafel behaviour was found to be followed only approximately. Current efficiency of the electrochemical oxidation of polyols was studied. Replacement of platinum by carbon as current collector was found to leave the electrocatalytic activity of the MnO₂ deposit practically unaltered.     

Unified modeling technique for high-viscosity,melt-phase,condensation polymer reactors

Mathematical models for chemical reaction and mass transfer occurring in the manufacture of high-viscosity condensation polymers are considered. A preliminary study indicates that several diverse models can be represented using a single formula based upon an effectiveness factor. The effectiveness factor is shown to depend upon a ratio of time scales of mixing and reaction. The formula giving the effectiveness factor in terms of the time scales ratio is shown to depend upon mixing assumptions only. Starting with a mixing-cell model, a new modeling framework is developed and shown to include the previous models as special cases. The framework is free of inherent mixing assumptions and can be applied to a wide variety of situations once the mixing characteristics are specified. © 1993 John Wiley & Sons, Inc.     

Terahertz Interferometer That Senses Vibrations Behind Barriers

A terahertz sensor that measures vibrations behind optically opaque barriers (cardboard, plastic, wool, cotton) is described and demonstrated. Using interferometric techniques, submicrometer displacements can be resolved. Measured spectral response agrees with commercial vibrometer     

Attribute Allocation and Retrieval Scheme for Large-Scale Sensor Networks

Wireless sensor network is an emerging technology that enables remote monitoring of large geographical regions. In this paper, we address the problem of distributing attributes over such a large-scale sensor network so that the cost of data retrieval is minimized. The proposed scheme is a data-centric storage scheme where the attributes are distributed over the network depending on the correlations between them. The problem addressed here is similar to the Allocation Problem of distributed databases. In this paper, we have defined the Allocation Problem in the context of sensor networks and have proposed a scheme for finding a good distribution of attributes to the sensor network. We also propose an architecture for query processing given such a distribution of attributes. We analytically determine the conditions under which the proposed architecture is beneficial and present simulation results to demonstrate the same. To the best of our knowledge, this is the first attempt to determine an allocation of attributes over a sensor network based on the correlations between attributes.     

A Grey Wolf Optimization Based Algorithm for Optimum Camera Placement

Wireless Personal Communications - Camera placement is very important for surveillance applications. Proposed work presents a new method of optimum placement of visual sensors for maximum coverage...     

Device performance of transistors with high-/spl kappa/ dielectrics using cross-wafer-scaled interface-layer thickness

A technique has been developed to fabricate transistors using a continuously scaled 0-2.5-nm SiO/sub 2/ interface layer between a silicon substrate and high-/spl kappa/ dielectric, on a single wafer. The transistor results are promising with good mobility values and drive current. The slant-etching process has no detrimental effect on the electrical characteristics of the Si/SiO/sub 2/ interface. This technique provides a powerful tool in examining the effect of the process variations on device performance.     

Emerging Soft Conductors for Bioelectronic Interfaces

Bidirectional interfacing between electrodes and biological systems has enabled diagnostics and therapeutics in modern medicine; however, the inherent dissimilarity between the soft, ion‐rich, dynamic biological tissues and the rigid, dry, static electronic systems hinders the establishment of effective and reliable bioelectronic interfaces. In the past decade, the scope of flexible/stretchable electronics has been broadened into bioelectronics owing to the need of implementation of various biocompatible soft conductors. Herein, the basic requirements for the construction of both epidermal and implantable bioelectronic interfaces utilizing soft materials are discussed, the most recent progress in the development of soft conductors, which are customized to interface with skin and other tissues, are summarized. An outlook into the remaining obstacles is provided and possible strategies to facilitate technological advances in bioelectronics are also outlined.     

Generation of square and triangular wave with independently controllable frequency and amplitude using OTAs only and its application in PWM

This paper presents a self-generating square/triangular wave generator using only the CMOS Operational Transconductance Amplifiers (OTAs) and a grounded capacitor. The output frequency and amplitude of the proposed circuit can be independently and electronically adjusted. The proposed circuit validates its advantage by consuming less amount of power, which is about 71.3 µW. The theoretical aspects are authentically showcased using the PSPICE simulation results. The performance of the proposed circuit is also verified through pre layout and post layout simulation results using the 90 nm GPDK CMOS parameters. A prototype of this circuit has been made using commercially available IC CA3080 for experimental verification. Experimentation also gives the similar output as per the theoretical proposition. The designed circuit is also made applicable to perform pulse width modulation (PWM).