Flammenpyrolytische Silikatbeschichtung bei Normaldruck als Alternative zu Vakuumverfahren. Combustion CVD of silica as an alternative method to vakuum treatment

In advancement of Pyrosil®‐technology a new kind of precursor delivery was developed, build and tested on real substrates. A Lab‐demonstrator was build to demonstrate the resources of the technology.     

Leben, Arbeit, Kommunikation — Harmonie im Dreiklang

An enterprise is not just a tall shiny building or a collection of facilities. Rather, it is the sum of individuals collectively engaged in a common pursuit. From an information and communications perspective, this realization changes everything. By looking at the enterprise as a boundary-less collection of individuals who sometimes work in an office, sometimes at home, and sometimes on the road, we need new communications concepts designed to work with and enhance our complex home and work lives.     

Determination of mechanical properties of thin films: a theoretical feasibility study

The aim of this work was to determine the principal mechanical parameters of a thin film on a substrate, i.e. Young's modulus, Poisson's ratio, intrinsic stress, and coefficient of linear thermal expansion. First, standard experiments possibly suitable for this purpose were investigated theoretically. The margin of error of the mechanical parameters determined was estimated as dependent on the geometrical conditions, substrate properties, and error in the respective measurements. In addition, the homogeneity and stability of the parameters were taken into account, for instance inhomogeneity of the film thickness and possible modification of substrate parameters during film growth. To obtain meaningful results, the accuracy of the measurements as well as the homogeneity and stability of several geometrical and physical parameters in general must be extremely high. However, the experimental conditions were found to fulfill these requirements.     

Reverse short channel effects in high-k gated nMOSFETs

Anomalous threshold voltage roll-up behavior, commonly referred as reverse short channel effect (RSCE), has been observed in high-k (HfO₂ on SiON buffer, Al₂O₃ on SiON buffer) gated submicron nMOSFETs, while the SiO₂ or SiON control samples show normal short channel effect (SCE) behavior. The possible causes such as inhomogeneous channel doping profile and gate oxide thickness variation near S/D ends have been ruled out. The results indicate that interface trap density that dependents on channel length is the main cause of the RSCE observed here. In addition, oxide charge also plays a role.     

On-line corrosion monitoring in geothermal district heating systems. II. Localized corrosion

Corrosion monitoring in district heating systems has traditionally been performed by using off-line methods, such as weight loss. The disadvantage is that the method is very slow, especially in low-corrosive environments, and that it only provides information about the past corrosion (accumulated over period of time). The purpose of the work is to test on-line monitoring methods in geothermal hot water in the district heating system in Reykjavik, Iceland. Geothermal water poses certain problems with regards to corrosion monitoring due to low conductivity, high pH and the presence of sulphide. These conditions make the geothermal environment low corrosive. However, a quality control is needed, especially since the sulphide causes the steel pipes to be more vulnerable towards localized corrosion. The methods used in this study were: linear polarization resistance (LPR), harmonic analysis (HA), electrochemical noise (EN) and zero resistance ammetry (ZRA). The Pitting Factor was measured with EN and showed promising results for measuring-localized corrosion on-line. A crevice corrosion cell also gave good results but had a low lifetime. However, the results of a galvanic corrosion cell (Fe/Cu) proved more difficult to interpret since they were dependent both on the dissolved oxygen and the sulphide level.     

Zur Nitratreaktion bei Milchprodukten

Zusammenfassung Wir haben die für die Abfüllung von Milchprodukten benützten Kartonpapiersorten auf ihren Nitratgehalt untersucht. Die untersuchten Kartonsorten zeigten schwankenden, aber unbedeutenden Nitratgehalt, der in erster Linie von den verschieden hohen Nitratgehalten der Fabrikationswässer abhängig ist. In den untersuchten Fällen wurde die Aufnahme von Nitraten durch Sauerrahm aus solchen paraffinierten Kartonbechern nachgewiesen. Die Herkunft dieser weit über den ursprünglichen Nitratgehalt der Kartons hinausgehenden Nitratmenge lag in dem zur Herstellung der Becher benützten, stark nitrathaltigen Stärkekleister. In solchen Fällen fallen somit die an die Nitratreaktion geknüpften Folgerungen (Wässerung, Verschmutzung) weg. Daher ist bei der Beurteilung der Milchprodukte auf Grund der Nitratreaktion auf diesen Umstand acht zu geben.Da solche Kartonbehälter auch zur Abfüllung anderer Lebensmittel verwendet werden (Honig, Senf, Marmelade usw.), behalten wir uns vor, unsere Untersuchungen auch auf dieses Gebiet auszudehnen.