Effect of cellulose acetate/cellulose triacetate ratio on reverse osmosis blend membrane performance

Surface functionalization and modification including the grafting process are effective approaches to improve and enhance the reverse osmosis (RO) membrane performance. This work is aimed to synthesize grafted/crosslinked cellulose acetate (CA)/cellulose triacetate (CTA) blend RO membranes using N-isopropylacrylamide (N-IPAAm) as a monomer and N,N-methylene bisacrylamide (MBAAm) as a crosslinker. The morphology of these membranes was analyzed by scanning electron microscopy and their surface roughness was characterized by atomic force microscopy. The performance of these membranes was evaluated through measuring two major parameters of salt rejection and water flux using RO unit at variable operating pressures. It was noted that the surface average roughness obviously decreased from 148 nm for the pure CA/CTA blend membrane with 2.5% CTA to 110 nm and 87 nm for the grafted N-IPAAm and grafted/crosslinked N-IPAAM/MBAAm/CA/CTA-RO membranes, respectively. Moreover, the contact angle decreased from 51.98° to 47.6° and 43.8° after the grafting and crosslinking process. The salt rejection of the grafted CA/CTA-RO membrane by 0.1% N-IPAAm produced the highest value of 98.12% and the water flux was 3.29 L/m²h at 10 bar.     

Flexible poly(styrene-ethylene-butadiene-styrene) hybrid nanofibers for bioengineering and water filtration applications

Among the thermoplastic elastomers that play important roles in the polymer industry due to their superior properties, styrene-based species and polyurethane block copolymers are of great interest. Poly(styrene-ethylene-butadiene-styrene) (SEBS) as a triblock copolymer seems to have the potential to meet many demands in different applications due to various industrial requirements where durability, biocompatibility, breaking elongation, and interfacial adhesion are important. In this study, the SEBS triblock copolymer was functionalized with natural (Satureja hortensis, SH) and synthetic (nanopowder, TiO₂) agents to obtain composite nanofibers by electrospinning and electrospraying methods for use in biomedical and water filtration applications. The results were compared with thermoplastic polyurethane (TPU) composite nanofibers, which are commonly used in these fields. Here, functionalized SEBS nanofibers exhibited antibacterial effect while at the same time improving cell viability. In addition, because of successful water filtration by using the SEBS composite nanofibers, the material may have a good potential to be used comparably to TPU for the application.     

Effect of fortification with asparagus powder on the qualitative properties of processed cheese

The qualitative properties of processed cheese (PC) fortified with different levels of asparagus powder (AP) (0.5%, 1% and 1.5% wt/wt) were evaluated during storage. AP decreased the pH and lipolysis indexes and increased the phenolic content, antioxidant activity and proteolysis of the processed cheeses. AP made the structure of the cheese more elastic, increased the rigidity and decreased the spreadability compared with the control sample, which corresponded to the results obtained using dynamic oscillatory rheometry. The results showed that AP as a rich source of bioactive components could be used for the fortification of processed cheeses.     

A Novel Approach to Analyzing the Occupancy of the Geo/Geo/∞ Queueing System

Discrete time queueing systems have been successfully used to model packet queues in computer and digital communications systems. In this article we introduce a novel approach to analyzing the Geo^X/Geo^Y/∞ queueing system, which is suitable for modelling high speed computer and communications systems. The approach is based on characterizing the system by a functional equation which is then solved recursively to give identical results to those obtained using other approaches.     

Pheromone Disruption of Argentine Ant Trail Integrity

Disruption of Argentine ant trail following and reduced ability to forage (measured by bait location success) was achieved after presentation of an oversupply of trail pheromone, (Z)-9-hexadecenal. Experiments tested single pheromone point sources and dispersion of a formulation in small field plots. Ant walking behavior was recorded and digitized by using video tracking, before and after presentation of trail pheromone. Ants showed changes in three parameters within seconds of treatment: (1) Ants on trails normally showed a unimodal frequency distribution of walking track angles, but this pattern disappeared after presentation of the trail pheromone; (2) ants showed initial high trail integrity on a range of untreated substrates from painted walls to wooden or concrete floors, but this was significantly reduced following presentation of a point source of pheromone; (3) the number of ants in the pheromone-treated area increased over time, as recruitment apparently exceeded departures. To test trail disruption in small outdoor plots, the trail pheromone was formulated with carnuba wax-coated quartz laboratory sand (1 g quartz sand/0.2 g wax/1 mg pheromone). The pheromone formulation, with a half-life of 30 h, was applied by rotary spreader at four rates (0, 2.5, 7.5, and 25 mg pheromone/m²) to 1- and 4-m² plots in Volcanoes National Park, Hawaii. Ant counts at bait cards in treated plots were significantly reduced compared to controls on the day of treatment, and there was a significant reduction in ant foraging for 2 days. These results show that trail pheromone disruption of Argentine ants is possible, but a much more durable formulation is needed before nest-level impacts can be expected. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Postintegration methods for numerical integration of non-linear dynamic equations of motion

The paper presents a family of methods with postintegration, for numerical integration of non-linear dynamic equations of motion of discrete systems. Both explicit and implicit algorithms of these methods are conditionally stable, but can give solutions of accuracy of a few orders higher than the known methods with preintegration, corresponding to them. A general analysis of stability and accuracy of single-step methods is carried out. The postintegration methods have been tested on a single-degree-of-freedom non-linear system.     

A quick neural network for computer vision of gray images

This paper presents a comparison between the traditional image processing method and the area vector concept as well as the new technique of artificial neural networks. Freeman chain coding is considered in the study, and the principle of segmentation may be based and implemented for further investigations resulting from the proposed work. The pattern recognition concept is analyzed and defined through the sigmoid function and the determination of the threshold of a gray image for an object. The block schemes for the given protocols are summarized in a single scheme for illustration and comparison purposes. The synthetic pictures are generated and investigated regarding the dependence of computer vision on the contents of the artificial neural network. The normalization technique is included to eliminate noise and zooming problems. The minimum computational time for image processing with the generated pictures is also determined. The rate of deflection in the computational time is recommended for sensing the minimum computational time according to the variation of the number of hidden units in the hidden layer. A three-layer neural network has been used. The study of gray binary imaging for color pictures is illustrated to save computational time and effort.     

Comparison of two different approaches for making design sensitivity analysis an integrated part of finite element analysis

This paper presents a comparison of two approaches for incorporating design sensitivity calculations into finite element analysis. The formulations depend on the implicit differentiation method and require few additional calculations to obtain the design sensitivity derivatives. The first approach by-passes the direct calculation of the stiffness matrix derivatives by calculating the sensitivity derivatives at the stress recovery stage of the analysis. The second approach depends on the direct calculation of the derivatives of the stiffness matrix, which are stored for re-use in multiple load case analyses, and subsequent matrix multiplications to evaluate the design sensitivities. The two approaches are developed and implemented to calculate the design sensitivities for continuum and structural isoparametric elements. In addition, a criterion is developed to aid in deciding which approach is better for a given number of load cases. To demonstrate the validity of the developed criterion and to evaluate the relative merits of each approach, some sensitivity calculation test problems are solved with different numbers of load cases.