电动汽车锂离子电池荷电状态估算方法研究综述

锂离子电池具有循环寿命长、能量密度高、自放电率低、环境污染小等优点,在电动汽车产业中得到广泛应用.电动汽车中的电池管理系统(BMS)可以维护和监测电池状态,确保电池的安全性和可靠性.电池荷电状态(SoC)表示电池中剩余的电量,是BMS的重要参数之一,实时精确的SoC估算可以延长电池寿命,保障行驶安全.然而锂离子电池是一个高度复杂的非线性时变系统,电池寿命、环境温度、电池自放电等许多未知因素均会对估算精度造成影响,使估算难度大大增加.为了满足不同条件下对锂离子电池SoC精确、快速、实时估算的要求,需要对SoC估计算法进行进一步研究与改进.近年来已有相关文献对锂离子电池SoC的估算方法进行了综述,然而已有相关综述对估算方法的总结不够全面且缺少流程表达.该文首先介绍了锂离子电池的工作原理,阐述了影响电池SoC估算的因素;其次,通过总结最新的研究成果对电池SoC估算方法进行了归纳分析,根据各类算法的不同特性将其分为查表法、安时积分法、基于模型的方法、数据驱动的方法以及混合方法五大类,说明了各类估算方法的主要特征并对模型或算法的优缺点进行综合的比较和讨论;最后,对电动汽车中锂离子电池SoC估算方法的未来发展方向做出展望.     

Electrochemical stripping features of graphite and its products characterization

A stable dispersion in mixed solvent of water and N,N-dimethyl formamide (DMF) of graphene was synthesized by one-step electrochemical approach. Here we demonstrate about electrochemical stripping graphite to prepare graphene influence by different electrolytes. The physical and chemical properties of the stripping product had been characterized by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), UV-Vis spectrophotometer (UV-Vis), Scanning electron microscopy (SEM), Transmission Electron Microscope (TEM) . The characteristic results of XRD showed that it could improve the efficiency of graphite stripping when H₂SO₄ was used as electrolyte mother liquid and amount of HNO₃ was doped in electrolyte; XPS and FTIR results indicate that the electrochemical stripping products preserve the intrinsic structure of graphene. The results of SEM and TEM shown that the surface morphology of the as-prepared graphene was folded lamellar structure and have good transparency;its thickness varies from 0.8 nm to a few nanometers.     

石墨烯/纳米TiO_2复合材料的制备及光催化还原性能

为探索超声辅助下利用紫外光及耦合热还原工艺制备RGO/纳米TiO_2复合材料的方法,并对其在缺氧水体中的光催化还原特性进行研究,首先,以鳞片石墨为原料,采用改进的Hummers法制备了氧化石墨烯(GO),进而通过超声/紫外光还原工艺制备了还原氧化石墨烯(RGO);然后,以钛酸丁脂和RGO为前驱物,采用溶胶-凝胶法并在氮气保护下高温加热制备了RGO/纳米TiO_2复合光催化材料;接着,利用FTIR、XRD、BET及紫外-可见光谱等对RGO/纳米TiO_2复合材料进行了结构性能表征;最后,以2,4-二氯苯氧乙酸(2,4-D)为探针物,研究了RGO/纳米TiO_2在缺氧水体中的光催化特性与2,4-D降解机制。结果表明:采用低温氧化Hummers法制备的GO六碳环上生成的活性基团较少,采用超声/紫外光还原工艺及耦合高温热还原工艺可使环状结构得到良好的修复;所制备的RGO/纳米TiO_2复合材料具有良好的2,4-D降解能力,在缺氧状态下,2,4-D主要发生光催化还原反应,脱除苯环上的氯,产生氯酚、邻苯三酚及间苯三酚等中间产物,部分2,4-D被氧化降解生成CO_2和H_2O。制备的RGO/纳米TiO_2复合材料具有良好的光催化还原性能。     

商业CAD系统中的协作设计

商业ＣＡＤ系统是一个支持多个设计者并行设计、协作完成同一设计任务的ＣＡＤ系统。文中提出了基于客户／服务器结构、支持同步和异步设计的协作设计模型,并具体介绍了协作管理中的角色管理、任务管理、群体感知管理和数据管理的实现技术和技巧。     

基于GIS的道路事故黑点聚类应用研究

由于地理信息系统中数据的多样性和空间复杂性,在GIS数据空间挖掘时原有的挖掘算法会遇到一些新问题。本文针对城市道路网中交通事故黑点发掘问题,对基于密度的DBSCAN算法进行改进,使改进后的算法能够确保聚类仅在连通空间内进行。最后以某市交通事故数据为例对该方法进行验证,实验结果表明此方法是有效的。     

Enhanced piezoelectric properties and temperature stability of Bi4Ti3O12-based Aurivillius ceramics via W/Nb substitution

Bi₄Ti₃O₁₂ (BIT), a typical Aurivillius ceramics with high Curie temperature (T_c ? 675 °C), has great potential for high temperature applications. This work provides an effective method of inducing structure distortion, relieving the tetragonal strain of the TiO₆ octahedron and decreasing the concentration of oxygen vacancies to improve the piezoelectricity and temperature stability of BIT ceramics. Bi₄Ti_2.98W_0.01Nb_0.01O₁₂ possesses an optimum piezoelectric coefficient (d₃₃) of 32 pC/N, a high T_c of 655 °C and a large resistivity of 3 × 10⁶ Ω·cm at 500 °C. The maximum d₃₃ reported here is approximately quadruple than that of pure BIT (?7 pC/N). Moreover, the d₃₃ of W/Nb co-doped BIT and the in-situ temperature stability of the compression-mode sensor present a highly stable characteristic in the range of 25–600 °C. These results imply that W/Nb-modified BIT ceramics is a promising candidate for application at high temperatures of up to 600 °C.     

Microstructure and mechanical properties of Mg-5Li-1Al sheets prepared by accumulative roll bonding

Ultrafine-grain and high-strength Mg-5Li-1Al sheets were prepared by accumulative roll bonding (ARB) process. Evolution of microstructure and mechanical properties of ARB-processed Mg-5Li-1Al sheets was investigated.Results show that, during ARB process, the evolution of deformation mechanism of t Mg-5Li-1Al alloy is as follows: twinning deformation, shear deformation, forming macro shear zone, and finally dynamic recrystallization (DRX). The grain refining mechanism changes from twin DRX to rotation DRX. With the increase in ARB cycles, strength of the Mg-5Li-1Al sheets is enhanced, whilst elongation varies slightly. With the increase in rolling cycles, anisotropy of mechanical properties decreases. It is conclusive that strain hardening and grain refinement dominate the strengthening mechanism of Mg-5Li-1Al alloy.     

三维GIS建模方法的研究与实现

三维GIS建模是发展新一代GIS系统的关键技术。提出了一种基于面向对象思想的建模方法——聚合派生法。其基本思想是：将模型分为基础模型和应用模型两大部分,其中基础模型由点、线和三角形三类原型及由其通过循环聚合而成的聚合实体构成,它可以适用干不同的场合;应用模型则是由基础模型通过一些附加条件派生而成。建模方法的特点是避免了数据冗余、拓扑关系清晰且具有较强的通用性.     

一个Bernstein型插值算子的逼近阶

本文给出了一个以第一类Chebyshev多项式的零点为插值结点组Bernsten型插值算子的逼近阶,并给出了这个算子的饱和阶和饱和类。     

关于共轭三角多项式的范数的渐近展开

设T_n(x)是阶数不超过刀的三角多项式,■(x)是了T_n(x)的共轭,本文给出了量■当■时的完全渐近展开式.