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排序方式: 共有240条查询结果,搜索用时 796 毫秒
1.
Taro Shimonosono Yoshihiro Hirata Mubin Changgan Syohei Kamei Rina Tokaiya Soichiro Sameshima Toshifumi Yoshidome Katsuhiko Yamaji 《Ceramics International》2018,44(8):8904-8912
This paper reports the performance of porous Gd-doped ceria (GDC) electrochemical cells with Co metal in both electrodes (cell No. 1) and with Ni metal in the cathode and Co metal in the anode (cell No. 2) for CO2 decomposition, CH4 decomposition, and the dry reforming reaction of a biogas with CO2 gas (CH4 + CO2 → 2H2 + 2CO) or with O2 gas in air (3CH4 +?1.875CO2 +?1.314O2 → 6H2 +?4.875CO +?0.7515O2). GDC cell No. 1 produced H2 gas at formation rates of 0.055 and 0.33?mL-H2/(min?m2-electrode) per 1?mL-supplied gas/(min?m2-electrode) at 600?°C and 800?°C, respectively, by the reforming of the biogas with CO2 gas. Similarly, cell No. 2 produced H2 gas at formation rates of 0.40?mL-H2/(min?m2) per 1?mL-supplied gas/(min?m2) at 800?°C from a mixture of biogas and CO2 gas. The dry reforming of a real biogas with CO2 or O2 gas at 800?°C proceeded thermodynamically over the Co or Ni metal catalyst in the cathode of the porous GDC cell. Faraday's law controlled the dry reforming rate of the biogas at 600?°C in cell No. 2. This paper also clarifies the influence of carbon deposition, which originates from CH4 pyrolysis (CH4 → C + 2H2) and disproportionation of CO gas (2CO → C + CO2), on the cell performance during dry reforming. The dry reforming of a biogas with O2 molecules from air exhibits high durability because of the oxidation of the deposited carbon by supplied air. 相似文献
2.
Atsushi Narumi Kosei Kawasaki Harumi Kaga Toshifumi Satoh Naoya Sugimoto Toyoji Kakuchi 《Polymer Bulletin》2003,49(6):405-410
Summary
The potato phosphorylase-catalyzed polymerization of α-D-glucose-1-phosphate (G-1-P) onto poly[styrene-block-(4-vinylbenzyl maltohexaoside)] (1) was performed at the molar ratios of [G-l-P]0 and [maltohexaose]0 of 35, 80, and 250. The product was found to be soluble in dimethyl sulfoxide, which was a good solvent for amylose, and
showed the complex-formation with iodine, indicating that the product was assignable to poly[styrene-block-(styrene-graft-amylose)] (2). The quantitative analysis of the liberated phosphoric acid gave the average degree of polymerization o f the glucose unit
(n) as 27, 5 1, and 180 for 2-I, 2-II, and 2-III, respectively.
Received: 29 November 2002/Accepted: 22 December 2002
Correspondence to Toyoji Kakuchi 相似文献
3.
This paper presents a method to compensate voltage sags with minimum energy injection for a series‐connected voltage restorer using a micro‐SMES. A circuit for extracting the fundamental symmetrical components from sag voltages and a minimum energy injection algorithm is described. Simulations of voltage sag compensation have been carried out using PSCAD/EMTDC for various faults. The simulation results confirm the validity of the proposed method and show the possibility of reducing the size of energy storage devices. © 2002 Wiley Periodicals, Inc. Electr Eng Jpn, 141(3): 70–80, 2002; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/eej.10047 相似文献
4.
Toshifumi Saigusa
Sakae Shimizu
《Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment》1989,280(2-3):195-197The expectation of LET∞ (unrestricted linear energy transfer) for a tritium beta particle around its parent nucleus in water has been calculated by the use of the energy-range relation of electrons. The amount of energy deposited by a beta particle with a certain initial energy over the interval of one micron at a definite position is obtained from the relation by the calculus of difference, and the probability that the event takes place per decay of tritium is estimated from the energy spectrum of tritium beta particles. The calculated values of expectations of LET∞ are higher at positions close to the parent nucleus. 相似文献
5.
Masahide Hojo Yasunori Mitani Toshifumi Ise Kiichiro Tsuji 《Electrical Engineering in Japan》2002,138(3):43-51
The advancement of power electronics technologies has significantly developed the power system stabilizing controllers. Quantitative as well as qualitative evaluation of their effectiveness in power systems is a matter of great importance for the feasibility investigation of these apparatus. In this paper, the possible control region of FACTS controllers with series and/or shunt configuration in a single machine to infinite bus system is formulated in the powerangle curve with a set of algebraic equations. The effectiveness of TCPST (Thyristor‐Controlled Phase Shifting Transformer), SSSC (Static Synchronous Series Compensator), and TCSC (Thyristor‐Controlled Series Compensator) for the improvement of the transient stability is evaluated quantitatively as a numerical example. The correctness of the proposed method has been confirmed by analysis based on the electromagnetic transients simulation with a detailed system model. © 2001 Scripta Technica, Electr Eng Jpn, 138(3): 43–51, 2002 相似文献
6.
When water-soluble polyacrylic acid (PAA) macromolecules are introduced into zinc phosphating liquids, significant improvements in the yield of conventional zinc phosphate conversion films deposited on carbon steel surfaces are obtained. The improvements include controllability of crystal dimensions, degree of crystallinity, and coating weight. The conversion layer formed is a composite microstructure consisting of a bulk PAA polymer and complexed PAA continuously overlaying a uniform array of fine dense zinc phosphate crystals. Interfacial studies of the composite layer using infrared spectroscopy, energy-dispersive X-ray spectrometry associated with scanning electron microscopy, and X-ray photoelectron spectroscopy indicated that the functional carboxylic acid groups in the PAA molecules were strongly chemisorbed by the Zn atoms at the outermost surface sites of the crystal layers. The intermolecular bridging action of the surface Zn atoms which connect the PAA and the zinc phosphate crystal layers results in good adhesion at the PAA–crystal interfaces. In addition, the plasticized complex formation plays an essential role in increasing the stiffness and the ductility of the normally conventional crystal films. The flexibility of the complex coating surface and the thickness and surface roughness of the thin PAA overlayer all affect the adhesive force at the interface between the organic polymer topcoat and the complexed coating. 相似文献
7.
The nature of the interfacial interactions between functional levulinic-acid-modified furan resin coatings and crystalline zinc phosphate hydrate films deposited on carbon steel surfaces has been systematically investigated. The typical surface topography of the highly crystallized zinc phosphate films was found to be characterized by the presence of a dendritic microstructure array of interlocking triclinic crystals. This structure acts significantly to develop mechanical interlocking bonds with the functional blend polymer which penetrates into the open surface structure of the films. Both the thickness of deposition film and the polar H2O molecules of hydrate at the outermost film surface sites play essential roles in wetting by the functional liquid resin. When the polarized furan polymers spread on the oxide film surfaces, the carboxylate groups derived from the levulinic ester and acid molecules react to form strong hydrogen bonds with the crystallized H2O molecules on the hopeite film. This formation of hydrogen bonding was shown to be a major factor affecting the chemical intermolecular attractions. A formulation consisting of 95 parts furan to 5 parts levulinic acid was found to yield the optimum protective coating. More than 5 parts levulinic acid resulted in the transformation of the characteristics of the polymer film from hydrophobic to hydrophilic. 相似文献
8.
Yoga Sugama Salim Norsyazlin Abd Rashid Suhaila Idayu Abdul Halim Chin Han Chan Chong Hup Ong Mohamad Kamal Harun 《Polymer Engineering and Science》2021,61(11):2757-2770
Standardization of Fourier transform infrared (FTIR) fingerprint region for paints and assessment on the reproducibility using different spectrophotometers were investigated. While selective fingerprint regions may be confusing for technicians/analysts who are non-chemists, we attempt to generalize these regions (e.g., 1300–1000 cm−1 for Epoxy part A and 1400–1000 cm−1 for Epoxy part B) by choosing a universal region (2000–900 cm−1) that works for different paints. Comparison result using a paired student t-test shows that the degree of similarity (r) values from the studied regions are not statistically different. The paint fails the screening analysis occasionally on-site when analyzed using handheld FTIR due to the higher level of noise that gives low r values (r < 0.900 ± 0.002). The same samples were analyzed using a benchtop FTIR and the r values are above 0.900 ± 0.002. While the screening may lead to a false rejection of the sample on-site, there could be occurrence of false acceptance. The on-site screening of EPZ part A with different formulations, for instance, shows that the r values over the entire IR spectrum are above 0.900 ± 0.002 when analyzed using handheld FTIR. After the samples were analyzed using the benchtop, the r values fall below 0.900 ± 0.002. 相似文献
9.
Yoshiaki Ukita Toshifumi Asano Kuniyo Fujiwara Katsuhiro Matsui Masahiro Takeo Seiji Negoro Yuichi Utsumi 《Microsystem Technologies》2008,14(9-11):1573-1579
The advantages of vertical microreactor stack with three-dimensional (3D) structure for immunoassay are discussed. The vertical microreactor stack uses vertical fluid flow operation with multifunctional fluid filters. The multi function of fluid filter is very effective for micromixing and passive valve operation. The mechanism of micromixing is discussed by using computational fluid dynamics (CFD), and we know that the mixing mechanism based on Coanda effect. To evaluate the micromixing performance of fluid filter, we demonstrated enzyme reaction with unique repeat mixing operation. As the results, we proved that the fluid filter has very effective mixing performance. The detection limit, which demonstrated by competition enzyme-linked immunosorvent assay (ELISA), is comparable with recommended detection limit, which suggested by Japanese ministry for the environment. 相似文献
10.
Hideaki Adachi Toshifumi Satoh Masahiro Sakai Koichi Mizuno Kentaro Setsune 《Journal of Superconductivity》1994,7(4):737-741
Epitaxial multilayer thin films of infinite-layer (Sr, Ca)CuO2 and perovskite (Sr, Ca)RuO3 have been prepared on (100) SrTiO3 substrates by multitarget rf magnetron sputtering. X-ray diffraction analyses revealed that the multilayer structure of (Sr, Ca)CuO3/(Sr, Ca)RuO3 was successfully fabricated with a minimum layer thickness of 20 Å. Transmission electron microscopy measurements of the multilayers indicated that there was no dislocation which normally exists in single-layer films with an infinite-layer structure. Resistivities of multilayer films at room temperature ranged from 1 to 10 m cm and showed semiconductor-like dependence against the temperature. 相似文献