Fabrication of oriented ZnO nanopillar self-assemblies and their application for photovoltaic devices

Organic photovoltaic devices based on a blend of poly(3-hexylthiophene) and a fullerene have been studied by inserting oriented zinc oxide nanopillars which were fabricated by a new method at low temperature (343?K). The dependence of the photovoltaic performance on the zinc oxide morphology was investigated, and it is concluded that the oriented zinc oxide nanopillar array plays an important role in collecting photogenerated electrons and acts as a conducting path to the electrode. Insertion of the oriented zinc oxide nanopillars in the photovoltaic cells produced enhanced performance with a power conversion efficiency of 1.22% under AM1.5 illumination.     

Study on the bulk junction type organic solar cells with double zinc oxide layer

The optical and photovoltaic properties of a photovoltaic cell with a structure of indium–tin oxide (ITO)/double ZnO/poly(3-hexylthiophene) (PAT6):PCBM/Ag have been investigated. The double layer ZnO was a composite of a sputtered ZnO layer and oriented zinc oxide nanopillars layer which was fabricated by a new method at low temperature (343 K). It is concluded that the double layer ZnO plays an important role in collecting photogenerated electrons and acts as a conducting path to the electrode. Insertion of the double layer ZnO in the photovoltaic cells produced enhanced performance with the power conversion efficiency of 1.42% under AM1.5 illumination.     

Fabrication of organic photovoltaic cells with double-layer ZnO structure

The fabrication process of a photovoltaic cell with a structure of indium-tin-oxide (ITO)/double ZnO/C₆₀/poly(3-hexylthiophene) (PAT6)/Ag has been investigated. The C₆₀/PAT6 heterojunction of this cell was fabricated by spin-coating a chloroform solution of PAT6 onto the C₆₀ thin film formed on double-layer ZnO-coated ITO. The fabrication of this double-layer ZnO was a new method, which was a composite of a sputtered ZnO layer and oriented zinc oxide nanograins layer fabricated at low temperature (343 K). Insertion of the double-layer ZnO in the photovoltaic cells produced enhanced performance with the power conversion efficiency of 1.31% under AM1.5 illumination.     

High‐performance white OLEDs with high color‐rendering index for next‐generation solid‐state lighting

Abstract— Several white‐OLED structures with a high color‐rendering index (CRI) were investigated for lighting applications. A two‐unit fluorescent/phosphorescent hybrid white OLED achieved an excellent CRI of 95, high luminous efficacy of 37 lm/W, and long lifetime of over 40,000 hours at 1000 cd/m². White‐OLED lighting panels of 8 × 8 cm for high‐luminance operation were fabricated, and a stable emission at 3000 cd/m² was confirmed. Quite a small variation in chromaticity in a different directions was achieved by using an optimized optical device structure. With a light‐outcoupling substrate, a higher efficacy of 56 lm/W, high CRI of 91, and longer half‐decay lifetime of over 150,000 hours at 1000 cd/m² was achieved. All‐phosphorescent white OLEDs placed on the light‐outcoupling substrate show a high CRI of 85 and higher efficacy of 65 lm/W with a fairly good half‐decay lifetime of over 30,000 hours. With a further voltage reduction and a high‐index spherical extractor, 128 lm/W at 1000 cd/m² has been achieved.     

Highly efficient white organic light‐emitting diodes with over 100 lm/W for next‐generation solid‐state lighting

High‐performance two‐unit all‐phosphorescent white devices on a built‐up light extraction substrate that comprised high‐index materials were studied. As a result of suitable optical and electrical design, the device showed an extremely high efficacy of 114 lm/W at 1000 cd/m². The device also showed 102 lm/W with long lifetime (LT70) of over 10,000 h at 3000 cd/m². Outstanding external quantum efficiency of almost 50% was also achieved in a flat panel with an emissive area of 25 cm². Color coordinates of the panel met the Energy Star ® criteria of solid‐state lighting with CIE (Commission Internationale de l'Éclairage) 1931 (x, y) = (0.477, 0.423), and the color rendering index was 81.     

Realization of high efficacy white organic light emitting diode by controlling internal light absorption and angular distribution

We investigated highly efficient organic light emitting diode (OLED) with advanced optical designs of organic layers to convert evanescent mode (internal absorption) into guided light and micro structure to extract the specifically distributed guided light dominated by wide angular substrate mode. White OLED device based on these optical designs realized high efficacy of 133 lm/W and external quantum efficiency of 56 % at 1000 cd/m².     

Effect of solvent vapor treatment on photovoltaic properties of conducting polymer/C60 interpenetrating heterojunction structured organic solar cell

The effect of solvent vapor treatment on the characteristics of a photovoltaic cell with a structure of indium–tin–oxide (ITO)/C₆₀/poly (3-hexylthiophene) (PAT6)/Au was studied. Interpenetrating film of C₆₀ and PAT6 fabricated by using chloroform (CF) as a solvent was exposed to vaporized CF atmosphere at different concentrations, temperatures and time periods before an evaporation of metal electrode. Solvent vapor treatment caused an increase in the open-circuit voltage, the fill factor and the external quantum efficiency; these were discussed by taking the surface morphology and crystallinity of the PAT6 layer which underwent a change after it was treated by this method.     

MoO3 buffer layer effect on photovoltaic properties of interpenetrating heterojunction type organic solar cells

Photovoltaic cells, with a conducting polymer/fullerene (C₆₀) interpenetrating heterojunction structure fabricated by spin-coating a conducting polymer onto a C₆₀ thin film, have been investigated and demonstrated a high efficiency as solar cells based on organic materials. The photovoltaic properties of the solar cells with a structure of indium-tin-oxide (ITO)/C₆₀/poly(3-hexylthiophene) (PAT6)/Au have been improved by the insertion of a molybdenum trioxide (VI) (MoO₃) layer as a cathode buffer layer. In the solar cells with the structure of ITO/C₆₀/PAT6/MoO₃/Au, the energy conversion efficiency has been improved to 1.15% under AM1.5 (100 mW/cm²) illumination.