Adjustable Robust Optimisation approach to optimise discounts for multi-period supply chain coordination under demand uncertainty

In this research, a problem of supply chain coordination with discounts under demand uncertainty is studied. To solve the problem, an Affinely Adjustable Robust Optimisation model is developed. At the time when decisions about order periods, ordering quantities and discounts to offer are made, only a forecasted value of demand is available to a decision-maker. The proposed model produces a discount schedule, which is robust against the demand uncertainty. The model is also able to utilise the information about the realised demand from the previous periods in order to make decisions for future stages in an adjustable way. We consider both box and budget uncertainty sets. Computational results show the necessity of accounting for uncertainty, as the total costs of the nominal solution increase significantly even when only a small percentage of uncertainty is in place. It is testified that the affinely adjustable model produces solutions, which perform significantly better than the nominal solutions, not only on average, but also in the worst case. The trade-off between reduction of the conservatism of the model and the uncertainty protection is investigated as well.     

Striated 2D Lattice with Sub‐nm 1D Etch Channels by Controlled Thermally Induced Phase Transformations of PdSe2

2D crystals are typically uniform and periodic in‐plane with stacked sheet‐like structure in the out‐of‐plane direction. Breaking the in‐plane 2D symmetry by creating unique lattice structures offers anisotropic electronic and optical responses that have potential in nanoelectronics. However, creating nanoscale‐modulated anisotropic 2D lattices is challenging and is mostly done using top‐down lithographic methods with ≈10 nm resolution. A phase transformation mechanism for creating 2D striated lattice systems is revealed, where controlled thermal annealing induces Se loss in few‐layered PdSe₂ and leads to 1D sub‐nm etched channels in Pd₂Se₃ bilayers. These striated 2D crystals cannot be described by a typical unit cells of 1–2 Å for crystals, but rather long range nanoscale periodicity in each three directions. The 1D channels give rise to localized conduction states, which have no bulk layered counterpart or monolayer form. These results show how the known family of 2D crystals can be extended beyond those that exist as bulk layered van der Waals crystals by exploiting phase transformations by elemental depletion in binary systems.     

Beneficial effects of three brown seaweed polysaccharides on gut microbiota and their structural characteristics: An overview

The gut microbiota appears critical in the metabolic health and anti-disease activity. In this review, we discuss three brown seaweed polysaccharides (alginate, laminarin, fucoidan) for their structural information, the digestive behaviour and the effects on gut microbiota. Bioactivities are associated with various physicochemical properties, like solubility, viscosity, hydration properties, molecular weight, monosaccharide composition, and so on. Brown seaweed polysaccharides can be completely utilised by microbes in the large bowel, and they can regulate the gut microbiota. The ultimate metabolite of these polysaccharides is mainly short-chain fatty acids, which are able to regulate the ecology of the gut microbiota by increasing the growth of beneficial bacteria and inhibiting the growth of some harmful bacteria. In addition, this article also discusses the relationship between the structure and activity of modulating the gut microbiota. Results show that polysaccharides with low molecular weight are more conductive to modulate gut microbiota.     

Controlling Defects in Continuous 2D GaS Films for High-Performance Wavelength-Tunable UV-Discriminating Photodetectors

A chemical vapor deposition method is developed for thickness-controlled (one to four layers), uniform, and continuous films of both defective gallium(II) sulfide (GaS): GaS_0.87 and stoichiometric GaS. The unique degradation mechanism of GaS_0.87 with X-ray photoelectron spectroscopy and annular dark-field scanning transmission electron microscopy is studied, and it is found that the poor stability and weak optical signal from GaS are strongly related to photo-induced oxidation at defects. An enhanced stability of the stoichiometric GaS is demonstrated under laser and strong UV light, and by controlling defects in GaS, the photoresponse range can be changed from vis-to-UV to UV-discriminating. The stoichiometric GaS is suitable for large-scale, UV-sensitive, high-performance photodetector arrays for information encoding under large vis-light noise, with short response time (<66 ms), excellent UV photoresponsivity (4.7 A W^–1 for trilayer GaS), and 26-times increase of signal-to-noise ratio compared with small-bandgap 2D semiconductors. By comprehensive characterizations from atomic-scale structures to large-scale device performances in 2D semiconductors, the study provides insights into the role of defects, the importance of neglected material-quality control, and how to enhance device performance, and both layer-controlled defective GaS_0.87 and stoichiometric GaS prove to be promising platforms for study of novel phenomena and new applications.