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以丙烯腈和苯甲醇为原料,浓硫酸作催化剂,合成了N-苄基丙烯酰胺(N-BAA)。考察了反应温度、反应时间和催化剂用量等因素对产物收率的影响,得出了最佳反应条件:n(丙烯腈):n(苯甲醇):n(浓硫酸)=3:1:1.2,反应时间3h,反应温度60℃。在最佳条件下,N-BAA的收率可达92%。每100g粗产物用10%氢氧化钠溶液提纯,精制产物纯度可达99.80%,熔点为64~65℃。通过红外光谱对产物结构进行了表征。 相似文献
3.
Microstructure and mechanical behaviour of 3Y-TZP/Mo nanocomposites possessing a novel interpenetrated intragranular microstructure 总被引:2,自引:0,他引:2
Yttria stabilized tetragonal zirconia polycrystal (Y-TZP)/0-100 vol % molybdenum (Mo) composites were fabricated by hot-pressing a mixture of Y-TZP powder containing 3 mol % yttria (Y2O3) and a fine Mo powder in vacuum. This composite system possessed a novel microstructural feature composed of an interpenetrated intragranular nanostructure, in which either nanometer sized Mo particles or equivalent sized zirconia (ZrO2) particles located within the ZrO2 grains or Mo grains, respectively. The strength and toughness were both greatly enhanced with increasing Mo content for the 3Y-TZP/Mo composites thus breaking through the strength-toughness tradeoff relation in transformation toughened ZrO2 and its composite materials. They exhibited a maximum strength of 2100 MPa and a toughness of 11.4 MPa·m1/2 for the composite containing 70 vol % Mo. These simultaneous improvements in strength and toughness were determined to be the result of a decrease in flaw size associated with the interpenetrated intragranular nanostructure, and a stress shielding effect created in the crack tip by the elongated Mo polycrystals bridging the crack tip in addition to the stress induced phase transformation. 相似文献
4.
Hayashi Y. Takizawa H. Inoue M. Niihara K. Suganuma K. 《Electronics Packaging Manufacturing, IEEE Transactions on》2005,28(4):338-343
Ecodesigns for nano-sized noble metal particles were investigated by a new liquid-solid (metal oxide-alcohol) system. We have reduced noble metal oxides as low-emission starting materials by ultrasound and tried to fabricate various noble metal nanoparticles (Ag, Au, Pt, Pd) at room temperature, Noble metal oxides were investigated during decomposition. These reductions are ecologically clean, because many noble metal oxides are not toxic, and during decomposition, O/sub 2/ is evolved. By choosing suitable conditions, it is reasonable to expect that this simple sonochemical process can be extended to obtain nano-sized metal particles. 相似文献
5.
彩色PDP用玻璃基板 总被引:4,自引:0,他引:4
本文讨论了彩色PDP现用钠钙玻璃的热稳定性,指出由于这种玻璃在热处理过程中易变形和收缩,因而不适合作大面积彩色PDP基板材料,介绍了彩色PDP基板玻璃的制造方法和特点。最后介绍了日本旭硝子公司和美国康宁公司各自为彩色PDP新开发的玻璃基板材料PD200和CS25。 相似文献
6.
高效铣环在胜科1井事故处理中的应用 总被引:1,自引:0,他引:1
胜科1井是中国石化的一口重点科学探井,在钻至井深5001m时因井眼缩径发生了卡钻事故。由于井底存在直翼扩大器、PDC钻头等含有硬质合金的落鱼,普通铣鞋无法完成套铣打捞作业,为此,专门设计了一种高效铣环。该铣环的切削元件选用了一种硬度达93.2 HRA的钛合金,经铣槽镶焊在本体上;本体选用了40CrNiMo厚壁管材,并进行了调质处理;连接螺纹选用了双级梯形同步螺纹。在胜科1井的应用表明:切削元件的强度满足了切削扩大器切削翼和PDC钻头胎体的需要,其齿形、布齿方向和出刃高度设计合理,提高了切削速度;本体性能高,切削元件焊接性能较好;双级梯形同步螺纹有效增加了连接部位的强度,具有较高的上扣扭矩,承受冲击载荷能力强。高效铣环在该井的成功应用,为今后同类型井的事故处理提供了借鉴。 相似文献
7.
En-Hai Sun Yong-Ho Choa Tohru Sekino Tomohiko Adachi Koichi Niihara 《Materials Research Innovations》2002,6(3):105-111
Cordierite/ZrO2 composites with 5 to 25 wt% ZrO2 were fabricated by conventional powder mixing and pressureless sintering method. Their densification behavior, microstructure,
mechanical and thermal properties were studied. By dispersing 25 wt% (9.57 vol%) ZrO2, densified cordierite/ZrO2 composite with a relative density of 98.5% was obtained at an optimum sintering condition of 1440 °C and 2 h. ZrO2 particles were homogenously dispersed within matrix grains and at the grain boundaries. The intragranular particles were
finer than 100 nm and the intergranular particles were coarser. Both fracture strength and toughness could be enhanced more
than two times higher, compare to those of monolithic cordierite, by dispersing 25 wt% ZrO2 into the cordierite matrix. The toughening mechanism in the present composites was mainly attributed to martensitic transformation
due to ZrO2 dispersion.
Electronic Publication 相似文献
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Weihua Jiang Zinsmeyer K. Less M. Schoenbach K.H. Kristiansen M. 《Electron Devices, IEEE Transactions on》1994,41(4):582-586
Results of electron-beam controlled switching experiments with switch samples of quartz crystal and polycrystalline zinc selenide (ZnSe) are presented. For switch samples of both materials, drastic reductions of the switch resistance were induced by the electron beam. The quartz sample showed very fast temporal response (less than 1 ns) with potential applicability for current control. The ZnSe samples, on the other hand, showed longer current transients (on the order of 10 ns) with exponential development of the switch resistance after the electron beam pulse 相似文献
10.
An experimental study for the pathologic changes of the canine tracheal mucosa under YAG:Nd laser ablation was performed in order to master the appropriate parameters for the clinical treatment of YAG:Nd laser. 6 male and female Mongolia dogs weighing 13-18 kg were received 20W YAG:Nd laser treatment and their pathologic changes were examined instantly and 3, 7, 14 and 28 days after ablation. 相似文献