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1.
Deformation behavior of stoichiometric blends made from poly(styrene-co-styrenesulfonic acid) (SPS) and poly(styrene-co-4-vinylpyridine) (SVP) was investigated by TEM observation of strained thin films. An FTIR investigation revealed that ionic cross-links were formed between the component polymers upon blending due to intermolecular ion-ion interactions, which arose from proton transfer from sulfonic acid groups to pyridine groups. TEM observations indicate that the deformation mode of the blends changed from crazing only to crazing plus shear deformation, with the shear contribution becoming larger, as the ion content in the blends increased. Such changes in deformation mode can be understood as arising from an increase in the ‘effective’ strand density due to the formation of ionic cross-links upon blending. It was also found that the ionic cross-links via pyridinium cation/sulfonate anion ion pairs were more effective in inducing the transition of deformation mode than ionic cross-links via -SO3−/Na+ or -SO3−/Ca2+ ion pairs. 相似文献
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Shiqi He Qianchu Liu Yiu-Wing Mai Roland Bryant 《Journal of materials science. Materials in medicine》1996,7(10):611-616
Abrasive wear is a major problem in the application of dental composite resins. In this study the friction and wear behaviours of two types of dental composites: one containing relatively coarse filler particles and some microfillers (Estilux) and another containing only microfiller particles (Durafill), have been investigated by using a scratch testing machine. Experimental results show that the coefficients of friction in both composites are essentially constant for applied loads up to 20 N. The wear resistance of Durafill is better than Estilux. Under the same testing conditions, the size, shape and distribution of the filler particles are more important variables than applied load and sliding speed in controlling the wear mechanism. It is shown that for Estilux, plastic ploughing by the diamond indenter is the predominant mechanism. For Durafill, however, the formation and propagation of tensile cracks on the worn surface is the main wear mechanism. The effects of two different indenters, diamond and enamel, on the basic wear mechanisms are also discussed. 相似文献
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人力资源管理中的人才资源管理是现代企业面临的一个重大挑战。国企中的人才资源管理需要不断进行观念创新,正确认识人才的流动,人才的识别选拔、人才的能上能下、人才的文化物质需求、人才的培育评价、人才的使用储备。 相似文献
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彩色半柔性混合料是一种在开级配沥青混合料中填充水泥胶浆而形成的兼具沥青路面与水泥混凝土路面优点的彩色复合路面。利用车辙试验来评价彩色半柔性混合料的高温稳定性,用残留稳定度和冻融劈裂试验评价半柔性混合料的水稳定性。结果表明,半柔性混合料具有优良的高温稳定性和疲劳性能,水稳定性较好。 相似文献
6.
The effects of particulate reinforcement on the fatigue behaviour and fatigue mechanisms of two 6061 aluminium-based metal-matrix composites (MMCs) in three different heattreatment conditions were studied in situ with a scanning electron microscope and compared to the unreinforced alloy in the as-received condition. It was observed that the fatigue properties of the MMCs were influenced by the ceramic particles in two ways: firstly the particles increased the fatigue stress intensity threshold mainly by crack-deflection and crack-closure mechanisms, and secondly, the particles raised the fatigue crack growth rates in the Paris region by providing an easy crack path. The effect of ageing was small on the fatigue stress intensity threshold of MMCs, but for the peak-aged MMCs the fatigue crack growth rates in the Paris region were faster. The mechanism of fatigue crack growth was largely associated with the matrix/particle interface and the linkage with subcracks initiated ahead of the main crack at high applied stress intensity factors. 相似文献
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Theoretical analyses for the single fibre pull-out and push-out models under monotonic loading are given which are based on a shear-lag analysis in a fracture mechanics approach considering non-constant friction at the debonded interface as a result of fibre Poisson contraction (or expansion). The solutions allow the determination of typical fibre/matrix interfacial properties such as the interfacial fracture toughness, Gic, the coefficient of friction, μ, and the residual clamping stress, q0. Under cyclic loading the interfacial properties are expected to degrade as a result of repetitive abrasion, and a power law function is assumed between μ and the number of elapsed cycles, N. However, Gic is assumed to be unaffected and a fracture mechanics based debond criterion is derived for the relationship between the external applied stress, the debond length and the reduced friction coefficient for both fibre pull-out and fibre push-out. In addition, the relative displacements between the free fibre end and the matrix top are obtained for cyclic fatigue when the fibre is loaded and unloaded. A relationship obtained for the protrusion (or intrusion) length in fibre pull-out (or push-out) experiments allows the severity of the interface frictional degradation to be evaluated and characterised. Similarities and differences in the frictional degradation behaviour between fibre pull-out and push-out are also identified. 相似文献
9.
Mai Lu Paul J. Leonard Duo-Wang Fan Fu-Yong Xu 《Journal of Infrared, Millimeter and Terahertz Waves》2004,25(10):1469-1479
In this paper, the cutoff characteristic of rectangular-shaped microshield transmission line has been analysed by edge element method. Dependence of cutoff wavelengths on the thickness of metallic signal strip, dielectric constant of dielectric substrate and the width of the rectangular-shaped ground conductor are presented in tabular form. Numerical results in this paper have important values in design of rectangular-shaped microshield lines in microwave and millimeter wave integrated circuits. 相似文献
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