A New Variable Diffusion Drying Model for the Second Falling Rate Period of Paddy Dried in a Rapid Bin Dryer

The objectives of this article is to propose a new drying model for the second falling rate period known as the variable diffusion controlled period that follows after the first falling rate period and to propose a new method to determine the second critical moisture content that separates these two periods. Experimental work on paddy drying at minimum fluidization velocity was carried out in a rapid bin dryer. The effects of operating temperatures (60-120°C) and bed depths (2-6 cm) on the paddy drying characteristics were investigated. It was found that the normalized drying rate of paddy was proportional to the normalized moisture content in the first falling rate period but in the second falling rate period, the normalized drying rate of the material varies exponentially with the normalized moisture content. The different relationship between the normalized drying rate and the normalized moisture content in the first and second falling rate periods indicate that two different mechanism of moisture transport are at work. The new exponential model of the second falling rate period and the linear model of the first falling rate period were found to fit the experimental data very well. Derivation from variable diffusion equation shows that the linear model is the result of constant diffusion coefficient whereas the new exponential model is the result of linear diffusion coefficient. This also implies that the first falling rate period is a constant diffusion controlled period and the second falling rate period is a variable diffusion controlled period. In addition, drying kinetics data of a drying process that fits the exponential model over a very slow drying period will show that the drying process is under the effect of a linear diffusion coefficient. It was also found that the proposed new method to determine the second critical moisture content that distinguishes between the first and second falling rate periods by using a sudden change in the value of the drying rate gradient to a much lower value at that point is more rigorous and yet simpler than the method of determining the specific location of the receding drying boundary since it is based on the behavior of the actual drying kinetic data.     

Drying with Chemical Reaction in Cocoa Beans

Desirable flavor qualities of cocoa are dependent on how the cocoa beans are fermented, dried, and roasted. During fermentation and drying, polyphenols such as leucocyanidin and apecatechin are oxidized by polyphenols oxidase to form o-quinone, which later react nonenzymatically with a hydroquinone in a condensation reaction to form browning products and moisture. The objective of this article is to model the cocoa beans drying together with the browning reaction. A Luikov drying model for the moisture and a simple Fick's law diffusion model combined with first-order reactions for both the enzymatic oxidation and nonenzymatic condensation reactions were constructed. Both models were used to identify moisture diffusivity coefficient and total polyphenols diffusivity in cocoa beans from experimental drying and polyphenols degradation data and published kinetic data of the reactions. The theoretical drying model fitted the experimental cocoa bean drying curves with low mean square of residuals. The polyphenols diffusion and reaction model also fitted the experimental polyphenols degradation curves with minimum mean residual squares. The rate of polyphenols degradation in the cocoa beans increases at higher temperature and higher relative humidity. This is because the increasing reaction rate of polyphenols oxidation reaction as well as higher moisture diffusion at higher relative humidity and temperature. The effective moisture diffusivity in cocoa beans is estimated to be between 8.194 × 10^-9 and 8.542 × 10^-9 m²·s^-1, which is of the same order of magnitude as published data. The effective total polyphenols diffusivity is estimated to be between 8.333 × 10^-12 to 1.000 × 10^-11 m²·s^-1 with minimum mean residual squares. It is three orders of magnitude less than the estimated moisture diffusivity because of the larger polyphenols molecules. The estimated polyphenols diffusivity is very close to those published in the literature for sorption and ultrafiltration processes.     

Temperature-dependent diffusion coefficient of soluble substances during ethanol extraction of clove

The temperature dependence of the diffusion coefficient of ethanol-soluble substances from ground cloves (particle size 250 μm) during extraction was estimated by fitting batch extraction data at several temperatures (27.8, 40, 50, and 60°C) to a previously developed mass transfer model. The model was based on spherical geometry of particles. Nonlinear regression analysis was used to develop an equation that describes the diffusivity as a function of temperature. The temperature dependence ofD _A was of the Arrhenius type.     

Calendering of non-newtonian fluids

The calendering of non-Newtonian fluids by two rotating cylinders to produce thin films of fluids finds wide application in polymer sheet-making and food-drying industries. Theoretical work has previouly been devoted to the symmetrical case where the cylinders are of equal diameters rotating at the same speed. The present work proposes a new one-film theory of calendering of power law fluids for unequal radii and surface velocities of the calendering cylinders. The relationship between the dimensionless thickness of the calendered fluid, Δ_e^* and that of the incoming fluid, Δ_i^* is shown to be a function of the ratio of the surface velocities of the cylinders and the power law index. The result further shows that Δ_e^* tends to asymptote after the second decade of Δ_i^*     

Sulphur dioxide loadings over megacity Lahore (Pakistan) and adjoining region of Indo-Gangetic Basin

This article presents spatial and temporal variations of planetary boundary layer (PBL) sulphur dioxide (SO₂) over megacity Lahore and adjoining region, a typical representative area in the Indo-Gangetic Basin (IGB) largely influenced by transported volcanic SO₂ from Africa, Middle East, and southern Europe, by using data retrieved from satellite-based Ozone Monitoring Instrument (OMI) during October 2004–September 2015. We find a positive trend of 2.4% per year (slope 0.01 ± 0.005 with y-intercept 0.35 ± 0.03 Dobson Unit (DU), correlation coefficient r = 0.55 and 2-tailed p-value at 0.1) of OMI-SO₂ column with the average value of 0.4 ± 0.05 DU. Strong seasonality of OMI-SO₂ column is observed over the region linked with local meteorology, patterns of anthropogenic emissions, crop residue burning, and vegetation cover. There exists a seasonal high value in winter 0.56 ± 0.24 DU with a peak in December 0.67 ± 0.26 DU. The seasonal lowest value is observed to be 0.29 ± 0.11 DU in wet summer with minimum value in July 0.25 ± 0.06 DU. High growth rates of OMI-SO₂ column over the study region have been observed in January, June, October, and December ranging from 5.7% to 11.6% per year. Satellite data show elevated OMI-SO₂ columns in 2007, 2008, 2011, and 2012 largely contributed by trans-boundary volcanic SO₂. A detailed analysis of volcanic SO₂ transported from Africa and Middle East (Jabal Al-Tair, Dalaffilla, and Nabro volcanoes) over the study area is presented. Air mass trajectories suggest the presence of long-range transported volcanic SO₂ at high altitude levels over Lahore and IGB region during the volcanic episodes. The SO₂ enhancements in PBL during winter season are generally due to significant vertical downdraft of high-altitude volcanic SO₂. For the first time, we present significant influence of volcanic SO₂ from southern Europe (Mt. Etna volcano) reaching over the study area. Daily mean OMI-SO₂ levels up to 21.4, 10.0, 5.6, and 2.4 DU have been noticed due to the eruptions from Dalaffilla, Mt. Etna, Nabro, and Jabal Al-Tair volcanoes, respectively.     

Influence of nitrogen doping on carbon nanotubes towards the structure,composition and oxygen reduction reaction

Nitrogen-doped carbon nanotubes (NCNTs) as noble-metal free catalysts were synthesised via chemical vapour deposition using iron (II) phthalocyanine as a metal catalyst for growth of the nanotubes. The synthesis process was performed in one step in a tube furnace using different chemical precursors (aniline, diethylamine and ethylenediamine) as nitrogen sources. The NCNT samples were physically characterised using scanning electron microscopy, transmission electronic microscopy and X-ray photoelectron spectroscopy. Cyclic voltammetry measurements were conducted to investigate the oxygen reduction reaction (ORR), and they showed that the electrocatalytic activities depend on the structural and morphological changes in the NCNTs. The results showed that NCNTs synthesised from ethylenediamine precursors exhibit an ORR scheme proceed via indirect four electron transfer process in acidic media, which implies that these NCNTs are a candidate for serving as the cathodic catalyst in PEMFCs. The highly active NCNTs possess unique characteristics, including a high concentration of surface defects with high pyridinic-N and pyridinic-N-oxides configurations that serve as active sites for ORR activity in acidic media.     

Microbial fuel cell-based sensor for Enterobacter sp. KBH6958 activity monitoring during hydrogen production: the effects of pH and glucose concentration

Journal of Applied Electrochemistry - A microbial fuel cell (MFC) is an electricity-generating device utilising electrochemically active microorganisms as biocatalysts. Using MFC as a biosensor to...     

Extraction equilibrium conditions of beryllium and aluminium from a beryl ore for optimal industrial beryllium compound production

This study examines the extraction of beryllium and aluminium from a Nigerian beryl ore using Cyanex®272 in kerosene from an aqueous sulphate pregnant solution. Parameters such as extractant concentration and equilibrium pH that dictates the extraction yield were studied. Under the following conditions: temperature 27?±?2°C, phase ratio 1?1, about 45.50 and 46.76% of beryllium and aluminium were extracted by 0.15?mol?L^?1 Cyanex®272 concentration within 30?min. However, the extraction yield of beryllium and aluminium was increased to 91.68% and 97.89% at equilibrium pH of 3 and 4, respectively, for beryllium and aluminium at 27?±?2°C. A 0.05?mol?L^?1 H₂SO₄ solution was found to be adequate for the stripping of about 99.00% Be and 95.40% Al from the loaded organic phase. The pure solutions containing metal ions were accordingly beneficiated to obtain beryllium and aluminium compounds of industrial values.     

Drying Kinetics,Texture, Color,and Determination of Effective Diffusivities During Sun Drying of Chempedak

Sun drying of chempedak (Artocarpus integer) was carried out on different sample sizes to investigate the effects on product quality. Fick's second law model was used to determine the effective diffusivities of sun–dried chempedak slabs based on the drying rate versus moisture content plots. In addition, texture degradation and total color changes were investigated. The texture and color changes of dried chempedak were relatively significant (p < 0.05) compared to fresh chempedak. There was an increase in dried fruit hardness and chewiness but a decrease in springiness and cohesiveness during drying.