ESTIMATION OF DAILY INTAKE OF FOUR KINDS OF TRIHALOMETHANE BY JAPANESE HOUSEWIVES

Duplicate portions of the daily meals consumed by 30 housewives were collected for 3 consecutive days in the cities of Nagoya and Yokohama in Japan.
Meals were analyzed for chloroform, bromodichloromethane (BDCM), chlorodibromomethane (CDBM) and bromoform by using a purge-trap procedure. The average concentration (and the range) of these four kinds of trihalomethane in each of the 24 h duplicate meals were, chloroform 19.6±18.1 ppb(n.d.-106.8 ppb), BDCM 0.3±0.3 ppb(n.d.-1.7 ppb), CDBM 0.1±0.2 ppb(n.d.-0.6 ppb) and bromoform 0.5±1.3 ppb(n.d.-8.1 ppb).
The mean daily dietary intake of the four kinds of trihalomethane by housewives were, chloroform 40.0±25.4 μg, BDCM 0.6±0.5 μg, CDBM 0.3±0.3 μg and bromoform 0.9±1.3 μg.     

ADDUCT FORMATION OF β-DIKETONATO LANTHANOIDS(III) WITH CARBOXYLIC ACIDS HAVING HYDROXYL AND METHOXYL GROUPS

Adduct formation of 2-thenoyltrifluoroacetonato(tta) lantha-num(III), europium(III), and ytterbium(I II) with α-pheny 1 1 actic, α-methoxy phenyl acetic, salicylic, and o-methoxy benzoic acids in chloroform has been studied by solvent extraction technique. It has been found that 1anthanoid(111) chelates form more stable adducts with these carboxylic acids in the sequence: Yb(tta)₃ < Eu(tta) ₃ < La(tta) ₃. The adduct formation constants as well as the separation factors obtained as the ratio of the constants between a pair of metals are the largest for α-phenyl lactic acid among these acids. The characteristics with α-phenyl 1actic acid would be caused by the action as bidentate unlike benzoic acid derivatives which work as monodentates owing to the internal complexa-tion through hydrogen bonding.     

α-HYDROXYCARBOXYLIC ACID AS ADDUCT FORMING LIGAND FOR EXTRACTION OF LANTHANIDE(III)

Lanthanide(lII) chelates with 1,1,1 -trif luoro-5,5-dimethyl-2,4-hexanedione form adducts with benzilic acid, an a-hydroxycar-boxylic acid, in chloroform. The order of. the adduct formation constants in magnitude is: La^m> Eu^m> Yb^m although it is known that the stability constant of lanthanide(III) complexes with α-hydroxycarboxylic acids in aqueous solutions increases with increasing atomic number.     

Limonoids in Pummelos [Citrus grandis (L.) Osbeck]

Juice and seeds from 16 cultivars of mature pummelo fruits were analyzed for limonoid content. Pummelo juice contained an average of 18 ppm limonin and 29 ppm total limonoid glucosides. Compared to other juices, ptmnnelo contained very high concentrations of limonin and very low concentrations of limonoid glucosides. Limonin, nomilin, obacunone and trace amounts of deacetyhromilin were found in pummelo seeds. The 17–β-D-glucopyranoside derivatives (glucosides) of nomilin, nomilinic acid and obacunone were also present. Total limonoid aglycone concentration in the seeds ranged from 773 ppm to 9,900 ppm and total limonoid glucosides ranged from 130 ppm to 1,912 ppm.     

某轻混凝土γ屏蔽积累因子的计算

使用蒙特卡罗程序EGS4计算了光子能量范围0.015~15MeV、屏蔽厚度达40个平均自由程的某核电厂中使用的轻混凝土的γ照射量积累因子,程序计算中考虑了轫致辐射、荧光效应和相干（瑞利）散射对积累因子的影响。使用G-P近似拟合公式对γ屏蔽积累因子计算结果进行拟合计算,给出了相应的积累因子G-P拟合公式的拟合参数。利用此方法可得到此种轻混凝土的任意光子能量和屏蔽厚度的γ屏蔽积累因子。     

Non-inductive start up of QUEST plasma by RF power

Both start-up and sustainment of plasma were successfully achieved by fully non-inductive current drive using microwave with a frequency of 8.2 GHz. Plasmas current of 15 kA was implemented for 1 s. Magnetic surface reconstruction exhibited a plasma shape with an aspect ratio of below 1.5. The plasma current was dependent significantly on the launchen microwave power and vertical magnetic field, whiile not affected by the mode of launched wave and the toroidal refractive index. Hard X-ray (HXR) emitted from energetic electrons accelerated by the microwave was observed, and the discharge with a plasma current over 4 kA followed the same trend as the number of photons of 10 to 12 keV. This suggests that the plasma current may be driven by energetic electrons. Based on the experimental conditions, alternative explanations of how the plasma current could be driven are discussed.     

北京养老服务机构入住理由及位置选择的初探——关于合理布局建设养老服务机构

通过对北京市养老服务机构的入住老人进行问卷调研,解析老人的入住理由。老人在机构选择意向中重视"离子女居住地近"的要素,并在实际选择入住时,呈现选择离子女居住地较近机构的趋势。根据该倾向,研究通过整理各功能区特征,为解决北京市养老服务机构入住率分布不均衡的现状,提出各功能区养老机构的规划建设见解。     

Mechanism of inactivation of heat-tolerant spores of Bacillus stearothermophilus IFO 12550 by Rapid Decompression

The effect of three rapid decompression methods to clear the mechanism of inactivation of heat tolerant spores of Bacillus stearothermophilus IFO 12550 was investigated. Pressurization of the spores at 200 MPa and 75°C for 60 min caused a kill of 10⁴ CFU/mL by the link-motion system but the nonrotational rod valve and E.G. seal methods gave a kill of about 10³ CFU/mL. Sterilization was due to the physical breakdown of spore coat, and was induced by its physical permeability of water at high pressure and temperature. Rapid decompression by the link-motion system at 200 MPa decreased the D-value of the spores from 3000 min (100°C, one atmosphere) to 6 min, 11 min, and 17 min at 95, 85, and 75°C, respectively.     

Formation Reaction of ZrO2 Scatterers in ZrF4-Based Fluoride Fibers

This paper clarifies the formation reaction of ZrO₂ crystals which appear as extrinsic scatterers in fluoride fibers. EPMA analysis indicates that BaO exists at grain boundaries of BaF₂ purified by sublimation. BaO reacts with ZrF₄ to form ZrO₂ at 600°C during a glass-melting process. The ZrO₂ formation reaction is influenced by H₂O. Ba(OH)₂, which is formed by the reaction between BaO and water vapor, melts at 370° to 420°C and reacts with ZrF₄ to form ZrO₂ at 450° to 520°C. When low-oxide-content BaF₂ is used for fiber preparation, scatterers significantly decrease.     

Nomilin Acetyl-Lyase, a Bacterial Enzyme for Nomilin Debittering of Citrus Juices

Nomilin acetyl-lyase, an enzyme responsible for the conversion of bitter nomilin to nonbitter obacunone was purified from cell-free extracts of Corynebacterium fuscians by (NH₄)₂SO₄ precipitation, followed by HPLC gel filtration and ion exchange chromatography. The electrophoretically pure preparation represented a 1050-fold increase in specific activity with a recovery of 38%. The enzyme, (MW 90,000) required sulfhydryl groups for its catalysis, had a pH optimum of 8.5, a K_m of 38.1 PM, and a V_max of 4.83 μmoles/min. Obacunone A-ring lactone hydrolase, which catalyzes the conversion of obacunone to obacunoate, was also purified from the extract by HPLC gel filtration.