铁磁偶合的Gd（Ⅲ）Cu（Ⅱ）配合物──组装分子基铁磁体的一种重要元件

铁磁偶合的Ｇｄ（Ⅲ）Ｃｕ（Ⅱ）配合物──组装分子基铁磁体的一种重要元件缪明明，廖代正，王耕霖（南开大学化学系天津３０００７１）摘要分子基磁体的设计是自然界向化学家挑战的一个热点课题。铁磁偶合的Ｇｄ（Ⅲ）Ｃｕ（Ⅱ）配合物是组装分子基磁体的一种重要元件。...     

袖珍计算机放射性总量测量系统

本文介绍以PC-1500(A)型袖珍计算机为主体的地面放射性总量数据采集及处理系统的方案、硬件、软件及应用。     

Electrodeposition of catalytically active nickel for the oxygen evolution reaction — effects of anionic composition

Nickel electrodes were prepared by electrodeposition in electrolytes of various anionic compositions. The deposition conditions and bath types were evaluated with special emphasis on the electrocatalytic properties for the oxygen evolution reaction (OER). Electrochemical characterizations in a 5 mol/L KOH solution at 25°C showed that the electrode deposited from the chloride bath, having a low Tafel slope of 50 mV/dec and an overpotential of 396 mV at 100 mA/cm², is the most catalytically active among electrodes prepared in electrolytes of various anionic compositions. The electrode activity for the OER is related to the real surface areas, which depend on the anion compositions in the deposition bath and the deposition conditions.     

Electrodeposition of Ni-transition alloys for the oxygen evolution reaction

The oxygen evolution reaction (OER) is the anodic reaction in several industrial electrolytic processes. The objective of this work was to develop a new electrocatalytic material for long-lasting and economical high performance electrodes. New electrodes were prepared by electrodeposition of nickel, nickel-ruthenium and nickel-iridium alloys. They were then activated by anodic polarization at 100 mA cm^–2 to form an oxide layer. The electrocatalytic activity was characterized for the OER in 5M KOH solution. The results show that nickel-iridium alloys provide greater electrocatalytic activity for the OER and better corrosion resistance than nickel-ruthenium in alkaline solution. The effects of transition elements on improving the performance of the nickel electrode are then discussed.Notation b Tafel slope - i _ex exchange current density - i _dp electrodeposition current density - i _OER oxygen evolution reaction current density - C _dl double-layer capacity - o₂ oxygen overpotential     

Solvent free oxidation of alcohols catalyzed by KMnO4 adsorbed on Kieselguhr

Efficient and selective oxidation of primary and secondary alcohols to the corresponding aldehydes and ketones catalyzed by potassium permanganate supported on Kieselguhr reagent under solvent free conditions are reported.     

新型城镇化下欠发达地区传统文化保护研究——以张家口市段家堡村为例

新型城镇化背景下欠发达地区传统文化保护的关键取决于其能否在保护文化资本和环境资本的基础上,实现经济资本的提升、文化价值观念及生活方式的转变.通过对张家口市下花园区段家堡村传统文化的调查研究,提出转变观念,主动保护、挖掘和丰富欠发达地区传统文化特色,提升旅游开发优势,带动地区经济发展,实现新型城镇化的同时更好地保护传统文化.     

中英规范有关建筑物防雷接地做法的比较

结合国家标准GB 50057-2010《建筑物防雷设计规范》和BS规范BS EN 62305-2006《Protection against lightning》,介绍了两本规范中建筑物防雷装置做法,简述了两种规范中有关建筑物外部防雷(接闪器、引下线、接地装置)、内部防雷以及防雷击电磁脉冲的有关规范条文规定和比较。     

环境经济系统工程的思考

环境问题与经济问题紧密相连,由于环境问题的综合性和复杂性,需要运用系统工程的方法和经济学原理,将环境问题置于整个经济系统中统筹考虑,建立相对完整的环境经济系统工程方法体系,将环境保护工作纳入经济社会发展中,使其成为决策中主要考虑的因素之一,并引起应有的重视。本研究从环境与经济承载力、环境投资的经济分析、环境与投资效率比较、环境资源的经济价值以及生态补偿与污染赔偿等方面构建环境经济系统工程的基本框架体系,并结合实际进行案例分析。研究表明,单纯的政府行政干预不如创造条件,如补偿、税收减免、投资、贴息等,使其具备在市场规则下.自动引导资源向环境保护与污染治理的投入,如排污指标的交易等。此外,自然资源是不可或缺的稀有资本,应该将保护生态系统及生物多样性纳入各级政府决策的主要方面。     

基于位承诺的数字证书敏感信息保护

目前数字证书缺少敏感信息保护机制,容易泄露用户的隐私信息.针对数字证书的敏感信息泄露问题,采用基于单向函数的位承诺协议实现数字证书中敏感信息的隐藏和选择性披露,详细讨论了基于位承诺的证书申请、证书颁发及证书查询验证过程,并分析了位承诺协议的安全性和效率.