Deposition of cerium contained conversion films on LC4 alloy with square wave pulse method

Cerium contained conversion films were deposited on LC4 aluminum alloy using square wave pulse (SWP) in aCeCl3 solution with KMnO4 as the oxidant. Energy dispersive spectroscopy (EDS) and scanning electron microscopy (SEM) were adopted to study the composition and the morphology of the film. It is found that the film is composed of Al, Zn, Cu,and small amount of cerium. The polarization curves of the specimens treated with SWP technique measured in 3.5% (mass fraction) NaCl solution reveal that the film thus formed inhibits both the anodic and cathodic process of the corrosion of the specimen. The immersion tests of treated specimens in 3.5% NaCl solution indicate that the corrosion resistance of the SWP treated specimen is better than that of the untreated and is equivalent to or even better than that of the traditionally electro-chemically treated specimens.     

ANALYSIS OF DEPOSITED PRODUCTS AND REANODIZED POROUS LUBRICATING FILM ON A1 AFTER(NH_4)_2MoS_4 SOLUTION TREATMENT

Observation was carried out of the structure of sulphuric,oxalic or phosphoricfilm on Al after treatment of reanodizing and electrolytic depositing lubricant in(NH_4)_2MoS_4 solution,as well as of the deposited products by means of EMPA,TEMand energy spectro-scopic analysis.The deposited products are mixture of compounds ofS and Mo rather than single MoS_2 and most of them dcposited near the surface layerof the film.Some regular long pores without barrier layer occurred in the film,but theregular fine channels without relation to the structural element parameters of originalanodized film were found in the thickened barrier layer of phosphoric film.Sulphur maybe remained as Mo sulphide in the film during heating under Ar protective environment.     

304不锈钢焊缝在室温酸性氯化物溶液中的应力腐蚀行为

本文用慢应变速率实验(SSRT)方法研究了奥氏体304不锈钢焊接接头在室温HCl+NaCl溶液中应力腐蚀开裂(SCC)敏感性H+浓度和Cl-浓度是影响该体系发生SCC的两个重要因素,H+浓度的改变可使材料的腐蚀形态发生变化,对SCC敏感的酸度范围为:5.0x10-4～30MH+,并给出体系“304不锈钢焊缝/HCl+NaCl”的应力腐蚀状态图([Cl-]-[H+]-SCC图)焊缝区是焊接接头的SCC敏感区,应力腐蚀裂纹是沿着被选择性溶解的奥氏体枝晶间的δ-铁素体扩展的,断口具有奥氏体枝晶骨架的形貌.该体系     

高温超导交流磁体气冷电流引线的优化设计和实验

通过研究交流超导磁体气冷电流引线两段式模型的优化设计,使得其向低温系统的漏热达到最小,并自行设计热测法实验装置进行了实验研究.结果表明在引线顶端温度为300 K、引线下端温度为77 K、引线传输电流为460 A的情况下,得到最佳引线直径为7.9 mm,与实验值8 mm符合.对交流电流引线的趋肤效应进行了分析和讨论.     

高温超导线材交流特性研究进展

本文简要概述了高温超导线材交流特性的研究进展，并对其实际应用和存在的技术问题进行了探讨。     

高温超导变压器关键技术

由于超导材料的无阻载流特性,其在超导电缆、超导限流器、超导变压器、超导储能、超导电机等超导电力装置中的应用引起人们极大兴趣。其中超导变压器具有体积小、重量轻、损耗低、无火灾隐患、无环境污染和低漏抗等特点。简要介绍了高温超导变压器基本结构,重点介绍了变压器研发过程中的关键技术问题,包括液氮和气氮低温绝缘特性、超导绕组损耗分析、电流引线设计、非金属低温容器设计等,为高温超导变压器的研发提供有用的参考。     

高温超导变压器研发进展综述

与传统常规变压器相比,超导变压器具有很多优势,如体积小、重量轻、损耗低、无污染火灾隐患等。近十几年来,随着高温超导线材取得重要的研究进展,国际上相继开展了高温超导变压器的研发,已有三台样机成功地完成了挂网试验。简要介绍了近年来国内外高温超导变压器（包括电力变压器和机车变压器）的研发情况以及近期几个基于第二代高温超导线材的高温超导变压器项目,并指出随着高温超导线材的技术发展,限流变压器的研究值得关注。     

316L不锈钢微动磨蚀过程力学化学交互作用研究

采用球－平面接触微动设备,对３１６Ｌ不锈钢在不同ＮａＣｌ溶液中微动过程力学化学交互作用进行了研究,并解析了材料微动损伤速率与溶液腐蚀特性之间的关系。结果表明,材料微动过程力学化学作用相互促进,力学损伤在微动损伤过程中占居主导作用。强碱性、强酸性及溶液富含Ｃｌ＾－的情况下,都可导致材料严重微动损伤,而在中性条件下,力学因素对化学损伤促进作用最为明显。     

SCC Susceptibility of Steel 16Mn in Nitrate Solution and Its Mechanism

The SCC(stress corrosion cracking )susceptibility of steel 16Mn in nitrate solution was studied.The results showed that applied potential polarization would accelerate (anodic polarization)or retard(cathodic polarization)the SCC process.The study on phase electrochemistry revealed that there was significant difference in electrochemical performacnce between ferrite and pearlite of steel 16Mn.Pearlite preferentially corroded under the action of galvanic cell.The observation on time and in situ showed that corrosion started first at the phase boundary between ferrite and pearlite,and the pearklite gradually corroded until disappared.and then corrosion corssed the phase boundary extending into the ferrite phase.According to this,an anodic dissolution mechanism of SCC was proposed ,on which pre-existing active path and phase electrochemistry(PEAP-PEC) jointly came into action (SCC mechanism of PEAP-PEC).     

带锈铸铁在含盐湿砂中的腐蚀行为研究

研究带锈铸铁在含盐湿砂中的腐蚀和电化学行为,研究表明,在含盐湿砂中生成较厚砂锈层的带锈铸铁的腐蚀速度和电化学行为与铸铁相差很大,较厚砂锈层不仅不能阻碍腐蚀过程继续发展,而且加速腐蚀。